A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

Wenjin Liu; Xiaoyong Lu; Zihui Meng; Lyle Isaacs

doi:10.1039/c8ob01575a

A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

Wenjin Liu
, Xiaoyong Lu
, Zihui Meng^*
, Lyle Isaacs

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology
University of Maryland, College Park

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of ¹H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.

源语言	英语
页（从-至）	6499-6506
页数	8
期刊	Organic and Biomolecular Chemistry
卷	16
期	35
DOI	https://doi.org/10.1039/c8ob01575a
出版状态	已出版 - 2018

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abstract = "The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of 1H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.",

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AU - Meng, Zihui

AU - Isaacs, Lyle

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AB - The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of 1H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.

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A glycoluril dimer-triptycene hybrid receptor: Synthesis and molecular recognition properties

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