A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly

Ya Jun Zhang; Cheng Chen; Li Xuan Cai; Xiao Dong Yang; Jie Zhang

doi:10.1021/acs.inorgchem.7b01497

A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly

Ya Jun Zhang
, Cheng Chen
, Li Xuan Cai
, Xiao Dong Yang
, Jie Zhang^*

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal-organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration-decoloration under alternating light and thermal stimuli.

源语言	英语
页（从-至）	10529-10534
页数	6
期刊	Inorganic Chemistry
卷	56
期	17
DOI	https://doi.org/10.1021/acs.inorgchem.7b01497
出版状态	已出版 - 5 9月 2017

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title = "A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly",

abstract = "Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal-organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration-decoloration under alternating light and thermal stimuli.",

author = "Zhang, \{Ya Jun\} and Cheng Chen and Cai, \{Li Xuan\} and Yang, \{Xiao Dong\} and Jie Zhang",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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AU - Chen, Cheng

AU - Cai, Li Xuan

AU - Yang, Xiao Dong

AU - Zhang, Jie

PY - 2017/9/5

Y1 - 2017/9/5

N2 - Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal-organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration-decoloration under alternating light and thermal stimuli.

AB - Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal-organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration-decoloration under alternating light and thermal stimuli.

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ER -

A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly

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