A cationic water-soluble pillar[5]arene: Synthesis and host-guest complexation with long linear acids

Gui Yuan Wu; Bing Bing Shi; Qi Lin; Hui Li; You Ming Zhang; Hong Yao; Tai Bao Wei

doi:10.1039/c4ra08592b

A cationic water-soluble pillar[5]arene: Synthesis and host-guest complexation with long linear acids

Gui Yuan Wu
, Bing Bing Shi
, Qi Lin
, Hui Li
, You Ming Zhang
, Hong Yao
, Tai Bao Wei^*

^*此作品的通讯作者

Northwest Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

A cationic water-soluble pillar[5]arene has been synthesized and revealed to encapsulate linear acids in neutral, alkaline, and acidic conditions, driven by the hydrophobic and hydrogen bond interactions. A higher guest hydrophobicity contributes to a higher host affinity. Methanoic acid (A1) and acetic acid (A2) do not show any affinity for the host at all, because they are too hydrophilic for the host to compete with water.

源语言	英语
页（从-至）	4958-4963
页数	6
期刊	RSC Advances
卷	5
期	7
DOI	https://doi.org/10.1039/c4ra08592b
出版状态	已出版 - 2015
已对外发布	是

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title = "A cationic water-soluble pillar[5]arene: Synthesis and host-guest complexation with long linear acids",

abstract = "A cationic water-soluble pillar[5]arene has been synthesized and revealed to encapsulate linear acids in neutral, alkaline, and acidic conditions, driven by the hydrophobic and hydrogen bond interactions. A higher guest hydrophobicity contributes to a higher host affinity. Methanoic acid (A1) and acetic acid (A2) do not show any affinity for the host at all, because they are too hydrophilic for the host to compete with water.",

author = "Wu, \{Gui Yuan\} and Shi, \{Bing Bing\} and Qi Lin and Hui Li and Zhang, \{You Ming\} and Hong Yao and Wei, \{Tai Bao\}",

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AU - Shi, Bing Bing

AU - Lin, Qi

AU - Li, Hui

AU - Zhang, You Ming

AU - Yao, Hong

AU - Wei, Tai Bao

PY - 2015

Y1 - 2015

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AB - A cationic water-soluble pillar[5]arene has been synthesized and revealed to encapsulate linear acids in neutral, alkaline, and acidic conditions, driven by the hydrophobic and hydrogen bond interactions. A higher guest hydrophobicity contributes to a higher host affinity. Methanoic acid (A1) and acetic acid (A2) do not show any affinity for the host at all, because they are too hydrophilic for the host to compete with water.

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A cationic water-soluble pillar[5]arene: Synthesis and host-guest complexation with long linear acids

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