A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate)

Man Bo Zhang; Yong Mei Chen; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/ejic.200500883

A 3D manganese coordination polymer [Mn₃(IMDC) ₂(H₂O)₄] constructed from [Mn ₂(IMDC)₂(H₂O)₂] layers and [Mn(H₂O)₂] pillars (IMDC = 4,5-imidazoledicarboxylate)

Man Bo Zhang
, Yong Mei Chen
, Shou Tian Zheng
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter
Beijing University of Chemical Technology

科研成果: 期刊稿件 › 文章 › 同行评审

58 引用（Scopus）

摘要

A novel three-dimensional coordination polymer [Mn₃(IMDC) ₂(H₂O)₄] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn₂(IMDC)₂(H ₂O)₂] layers and [Mn(H₂O)₂] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the Mn^II ions of the dimeric units.

源语言	英语
页（从-至）	1423-1428
页数	6
期刊	European Journal of Inorganic Chemistry
期	7
DOI	https://doi.org/10.1002/ejic.200500883
出版状态	已出版 - 3 4月 2006
已对外发布	是

访问文件

10.1002/ejic.200500883

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{bb2def95da28420c9a2d2bf8e83a8505,

title = "A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate)",

abstract = "A novel three-dimensional coordination polymer [Mn3(IMDC) 2(H2O)4] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn2(IMDC)2(H 2O)2] layers and [Mn(H2O)2] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the MnII ions of the dimeric units.",

keywords = "Carboxylate ligands, Coordination polymers, Hydrothermal synthesis, Manganese",

author = "Zhang, \{Man Bo\} and Chen, \{Yong Mei\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2006",

month = apr,

day = "3",

doi = "10.1002/ejic.200500883",

language = "English",

pages = "1423--1428",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "7",

}

TY - JOUR

T1 - A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate)

AU - Zhang, Man Bo

AU - Chen, Yong Mei

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2006/4/3

Y1 - 2006/4/3

N2 - A novel three-dimensional coordination polymer [Mn3(IMDC) 2(H2O)4] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn2(IMDC)2(H 2O)2] layers and [Mn(H2O)2] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the MnII ions of the dimeric units.

AB - A novel three-dimensional coordination polymer [Mn3(IMDC) 2(H2O)4] (1) (IMDC = 4,5- imidazoledicarboxylate), consisting of [Mn2(IMDC)2(H 2O)2] layers and [Mn(H2O)2] pillars, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, TGA, and magnetic measurements. It is the first example of a 3D framework containing 4,5-imidazoledicarboxylate in the family of manganese complexes. Variable-temperature magnetic susceptibility measurements show a weak antiferromagnetic coupling interaction between the MnII ions of the dimeric units.

KW - Carboxylate ligands

KW - Coordination polymers

KW - Hydrothermal synthesis

KW - Manganese

UR - https://www.scopus.com/pages/publications/33645783917

U2 - 10.1002/ejic.200500883

DO - 10.1002/ejic.200500883

M3 - Article

AN - SCOPUS:33645783917

SN - 1434-1948

SP - 1423

EP - 1428

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 7

ER -

A 3D manganese coordination polymer [Mn3(IMDC) 2(H2O)4] constructed from [Mn 2(IMDC)2(H2O)2] layers and [Mn(H2O)2] pillars (IMDC = 4,5-imidazoledicarboxylate)

摘要

访问文件

其它文件与链接

指纹

引用此

A 3D manganese coordination polymer [Mn₃(IMDC) ₂(H₂O)₄] constructed from [Mn ₂(IMDC)₂(H₂O)₂] layers and [Mn(H₂O)₂] pillars (IMDC = 4,5-imidazoledicarboxylate)