TY - JOUR
T1 - A 3D heteropolynuclear network with 4,6-connected (44 · 62)(48 · 66 · 8) topology
T2 - Synthesis, structure, thermal and magnetic properties
AU - Chen, Pang Kuan
AU - Che, Yun Xia
AU - Zheng, Ji Min
PY - 2007/2
Y1 - 2007/2
N2 - This paper describes a novel heteropolynuclear coordination polymer [Cd4Co2(m-BDC)6(HIm)4]n (1) (m-H2BDC = 1,3-benzenedicarboxylic acid, Him = imidazole), which has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR, ICP, XRPD, TGA, DSC, and element analysis. The overall architecture is constructed from alternate Co(II) and Cd layers arranged in ABAB mode, and affords a three-dimensional (3D) 4,6-conneccted (44 · 62)(48 · 66 · 8) topological network. Furthermore, magnetic property of 1 has also been studied in the temperature range of 5-300 K.
AB - This paper describes a novel heteropolynuclear coordination polymer [Cd4Co2(m-BDC)6(HIm)4]n (1) (m-H2BDC = 1,3-benzenedicarboxylic acid, Him = imidazole), which has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR, ICP, XRPD, TGA, DSC, and element analysis. The overall architecture is constructed from alternate Co(II) and Cd layers arranged in ABAB mode, and affords a three-dimensional (3D) 4,6-conneccted (44 · 62)(48 · 66 · 8) topological network. Furthermore, magnetic property of 1 has also been studied in the temperature range of 5-300 K.
KW - 4,6-Connected topology
KW - Alternate layer
KW - Heteropolynuclear
KW - Hydrothermal synthesis
KW - Magnetic property
KW - Thermal property
UR - https://www.scopus.com/pages/publications/33846200013
U2 - 10.1016/j.inoche.2006.10.015
DO - 10.1016/j.inoche.2006.10.015
M3 - Article
AN - SCOPUS:33846200013
SN - 1387-7003
VL - 10
SP - 187
EP - 190
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 2
ER -