A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

Man Bo Zhang; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/anie.200461424

A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

Man Bo Zhang
, Jie Zhang
, Shou Tian Zheng
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

347 引用（Scopus）

摘要

Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln₁₄, (μ₆-O)(μ₃-OH)₂₀(H₂O) ₈]²⁰⁺ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.

源语言	英语
页（从-至）	1385-1388
页数	4
期刊	Angewandte Chemie - International Edition
卷	44
期	9
DOI	https://doi.org/10.1002/anie.200461424
出版状态	已出版 - 18 2月 2005
已对外发布	是

访问文件

10.1002/anie.200461424

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{3ec06bb480cc4a4c8901784e1a9dde86,

title = "A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands",

abstract = "Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.",

keywords = "Bridging ligands, Cluster compounds, Copper, Hydrothermal synthesis, Lanthanides",

author = "Zhang, \{Man Bo\} and Jie Zhang and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2005",

month = feb,

day = "18",

doi = "10.1002/anie.200461424",

language = "English",

volume = "44",

pages = "1385--1388",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "9",

}

TY - JOUR

T1 - A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

AU - Zhang, Man Bo

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2005/2/18

Y1 - 2005/2/18

N2 - Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.

AB - Lanthanide oxides as sources of lanthanides provided 3D coordination polymers under hydrothermal conditions in which distinct [Ln14, (μ6-O)(μ3-OH)20(H2O) 8]20+ (Ln = Y, Gd, Dy) clusters are linked to two different types of copper centers through isonicotinate ligands. The unprecedented 3D network topology of. these isostructural compounds is exemplified for Ln = Gd in the picture, which reveals the presence of 1D channels along the c axis.

KW - Bridging ligands

KW - Cluster compounds

KW - Copper

KW - Hydrothermal synthesis

KW - Lanthanides

UR - https://www.scopus.com/pages/publications/14844336823

U2 - 10.1002/anie.200461424

DO - 10.1002/anie.200461424

M3 - Article

AN - SCOPUS:14844336823

SN - 1433-7851

VL - 44

SP - 1385

EP - 1388

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands

摘要

访问文件

其它文件与链接

指纹

引用此