摘要
A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g−1 of CO2, 9.9 mg g−1 of H2, and 11.5 mg g−1 of CH4, at 273 K and 1 bar, with high selectivity towards CO2 over N2 and CH4.
| 源语言 | 英语 |
|---|---|
| 页(从-至) | 13825-13828 |
| 页数 | 4 |
| 期刊 | Chemical Communications |
| 卷 | 50 |
| 期 | 89 |
| DOI | |
| 出版状态 | 已出版 - 14 10月 2014 |
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