1,4-Benzene-bridged covalent hybrid of triarylamine and cyclometalated ruthenium: A new type of organic-inorganic mixed-valent system

Chang Jiang Yao; Ren Hui Zheng; Qiang Shi; Yu Wu Zhong; Jiannian Yao

doi:10.1039/c2cc32471g

1,4-Benzene-bridged covalent hybrid of triarylamine and cyclometalated ruthenium: A new type of organic-inorganic mixed-valent system

Chang Jiang Yao
, Ren Hui Zheng
, Qiang Shi
, Yu Wu Zhong^*
, Jiannian Yao

^*此作品的通讯作者

CAS - Institute of Chemistry
Nanjing University

科研成果: 期刊稿件 › 文章 › 同行评审

53 引用（Scopus）

摘要

A 1,4-benzene-bridged covalent hybrid of triarylamine and cyclometalated ruthenium 1²⁺ was isolated as a bench-stable open-shell substance. The free spin in this complex is mainly associated with the triarylamine unit, as indicated by EPR and DFT calculations and electrochemical analysis. It exhibits an intense intervalence-charge-transfer transition around 1050 nm that is not present in 1⁺ and 1³⁺.

源语言	英语
页（从-至）	5680-5682
页数	3
期刊	Chemical Communications
卷	48
期	45
DOI	https://doi.org/10.1039/c2cc32471g
出版状态	已出版 - 9 5月 2012
已对外发布	是

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abstract = "A 1,4-benzene-bridged covalent hybrid of triarylamine and cyclometalated ruthenium 12+ was isolated as a bench-stable open-shell substance. The free spin in this complex is mainly associated with the triarylamine unit, as indicated by EPR and DFT calculations and electrochemical analysis. It exhibits an intense intervalence-charge-transfer transition around 1050 nm that is not present in 1+ and 13+.",

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AU - Zheng, Ren Hui

AU - Shi, Qiang

AU - Zhong, Yu Wu

AU - Yao, Jiannian

PY - 2012/5/9

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AB - A 1,4-benzene-bridged covalent hybrid of triarylamine and cyclometalated ruthenium 12+ was isolated as a bench-stable open-shell substance. The free spin in this complex is mainly associated with the triarylamine unit, as indicated by EPR and DFT calculations and electrochemical analysis. It exhibits an intense intervalence-charge-transfer transition around 1050 nm that is not present in 1+ and 13+.

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1,4-Benzene-bridged covalent hybrid of triarylamine and cyclometalated ruthenium: A new type of organic-inorganic mixed-valent system

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