[{Zn2(HPO4)4}{Co(dien) 2}]·H3O: A zinc phosphate with multidirectional intersecting helical channels

Yu Wang; Jihong Yu; Min Guo; Ruren Xu

doi:10.1002/anie.200351643

[{Zn₂(HPO₄)₄}{Co(dien) ₂}]·H₃O: A zinc phosphate with multidirectional intersecting helical channels

Yu Wang, Jihong Yu^*, Min Guo, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

194 Citations (Scopus)

Abstract

A twist in the tale: A racemic mixture of the chiral [Co(dien) ₂]Cl₃ complex has been used as a template in preparing an openframework zinc phosphate with multidirectional helical channels, consisting of alternate ZnO₄ and PO₄ tetrahedra. The framework contains 12-membered ring channels along the [100] direction, within which [Co(dien)₂]³⁺ ions are located. Each channel is enclosed by chiral interpenetrating double helices (see picture; dien=diethylenetriamine).

Original language	English
Pages (from-to)	4089-4092
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	34
DOIs	https://doi.org/10.1002/anie.200351643
Publication status	Published - 5 Sept 2003
Externally published	Yes

Keywords

Helical structures
Host-guest systems
Hydrothermal synthesis
Phosphates
Zinc

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10.1002/anie.200351643

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abstract = "A twist in the tale: A racemic mixture of the chiral [Co(dien) 2]Cl3 complex has been used as a template in preparing an openframework zinc phosphate with multidirectional helical channels, consisting of alternate ZnO4 and PO4 tetrahedra. The framework contains 12-membered ring channels along the [100] direction, within which [Co(dien)2]3+ ions are located. Each channel is enclosed by chiral interpenetrating double helices (see picture; dien=diethylenetriamine).",

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AU - Guo, Min

AU - Xu, Ruren

PY - 2003/9/5

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AB - A twist in the tale: A racemic mixture of the chiral [Co(dien) 2]Cl3 complex has been used as a template in preparing an openframework zinc phosphate with multidirectional helical channels, consisting of alternate ZnO4 and PO4 tetrahedra. The framework contains 12-membered ring channels along the [100] direction, within which [Co(dien)2]3+ ions are located. Each channel is enclosed by chiral interpenetrating double helices (see picture; dien=diethylenetriamine).

KW - Helical structures

KW - Host-guest systems

KW - Hydrothermal synthesis

KW - Phosphates

KW - Zinc

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[{Zn₂(HPO₄)₄}{Co(dien) ₂}]·H₃O: A zinc phosphate with multidirectional intersecting helical channels

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Keywords

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