[Zn(H2O)4][B6O10]: An open-framework borate with acentric structure

Rui Pan; Bai Feng Yang; Guo Ming Wang; Guo Yu Yang

doi:10.1016/j.inoche.2016.11.017

[Zn(H₂O)₄][B₆O₁₀]: An open-framework borate with acentric structure

Rui Pan
, Bai Feng Yang
, Guo Ming Wang^*
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

An open-framework borate [Zn(H₂O)₄][B₆O₁₀] with acentric structure, has been successfully obtained for the first time under solvothermal conditions. It has been characterized by powder and single crystal X-ray diffraction, IR spectroscopy, diffuse-reflectance spectroscopy and thermogravimetric (TG) analyses, respectively. It crystallizes in the orthorhombic system, space group Pna2₁, a = 11.3140(6) Å, b = 11.8995(7) Å, c = 8.6140(5) Å and Z = 4. In the structure, the alternative connections between [B₃O₇] units give rise to an unprecedented 3D borate framework with 11- and 10-MR channels, in which the [Zn(H₂O)₄]²⁺ complexes are located. It has a cut-off edge below 200 nm and exhibits second harmonic generation (SHG) efficiency approximately 0.4 times that of KH₂PO₄ (KDP).

Original language	English
Pages (from-to)	15-17
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	76
DOIs	https://doi.org/10.1016/j.inoche.2016.11.017
Publication status	Published - 1 Feb 2017

Keywords

Crystal structure
Nonlinear optical
Open-framework
Oxoboron cluster
Solvothermal condition

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10.1016/j.inoche.2016.11.017

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@article{74cb0b1e24a0411b80118c5c849458d9,

title = "[Zn(H2O)4][B6O10]: An open-framework borate with acentric structure",

abstract = "An open-framework borate [Zn(H2O)4][B6O10] with acentric structure, has been successfully obtained for the first time under solvothermal conditions. It has been characterized by powder and single crystal X-ray diffraction, IR spectroscopy, diffuse-reflectance spectroscopy and thermogravimetric (TG) analyses, respectively. It crystallizes in the orthorhombic system, space group Pna21, a = 11.3140(6) {\AA}, b = 11.8995(7) {\AA}, c = 8.6140(5) {\AA} and Z = 4. In the structure, the alternative connections between [B3O7] units give rise to an unprecedented 3D borate framework with 11- and 10-MR channels, in which the [Zn(H2O)4]2+ complexes are located. It has a cut-off edge below 200 nm and exhibits second harmonic generation (SHG) efficiency approximately 0.4 times that of KH2PO4 (KDP).",

keywords = "Crystal structure, Nonlinear optical, Open-framework, Oxoboron cluster, Solvothermal condition",

author = "Rui Pan and Yang, \{Bai Feng\} and Wang, \{Guo Ming\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = feb,

day = "1",

doi = "10.1016/j.inoche.2016.11.017",

language = "English",

volume = "76",

pages = "15--17",

journal = "Inorganic Chemistry Communications",

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TY - JOUR

T1 - [Zn(H2O)4][B6O10]

T2 - An open-framework borate with acentric structure

AU - Pan, Rui

AU - Yang, Bai Feng

AU - Wang, Guo Ming

AU - Yang, Guo Yu

PY - 2017/2/1

Y1 - 2017/2/1

N2 - An open-framework borate [Zn(H2O)4][B6O10] with acentric structure, has been successfully obtained for the first time under solvothermal conditions. It has been characterized by powder and single crystal X-ray diffraction, IR spectroscopy, diffuse-reflectance spectroscopy and thermogravimetric (TG) analyses, respectively. It crystallizes in the orthorhombic system, space group Pna21, a = 11.3140(6) Å, b = 11.8995(7) Å, c = 8.6140(5) Å and Z = 4. In the structure, the alternative connections between [B3O7] units give rise to an unprecedented 3D borate framework with 11- and 10-MR channels, in which the [Zn(H2O)4]2+ complexes are located. It has a cut-off edge below 200 nm and exhibits second harmonic generation (SHG) efficiency approximately 0.4 times that of KH2PO4 (KDP).

AB - An open-framework borate [Zn(H2O)4][B6O10] with acentric structure, has been successfully obtained for the first time under solvothermal conditions. It has been characterized by powder and single crystal X-ray diffraction, IR spectroscopy, diffuse-reflectance spectroscopy and thermogravimetric (TG) analyses, respectively. It crystallizes in the orthorhombic system, space group Pna21, a = 11.3140(6) Å, b = 11.8995(7) Å, c = 8.6140(5) Å and Z = 4. In the structure, the alternative connections between [B3O7] units give rise to an unprecedented 3D borate framework with 11- and 10-MR channels, in which the [Zn(H2O)4]2+ complexes are located. It has a cut-off edge below 200 nm and exhibits second harmonic generation (SHG) efficiency approximately 0.4 times that of KH2PO4 (KDP).

KW - Crystal structure

KW - Nonlinear optical

KW - Open-framework

KW - Oxoboron cluster

KW - Solvothermal condition

UR - https://www.scopus.com/pages/publications/85008146721

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DO - 10.1016/j.inoche.2016.11.017

M3 - Article

AN - SCOPUS:85008146721

SN - 1387-7003

VL - 76

SP - 15

EP - 17

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

[Zn(H₂O)₄][B₆O₁₀]: An open-framework borate with acentric structure

Abstract

Keywords

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