[{{Zn(en)2}2As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)2 Complex Bridge

Shou Tian Zheng; Jie Zhang; Guo Yu Yang

doi:10.1246/cl.2003.810

[{{Zn(en)₂}₂As₆V₁₅O ₄₂(H₂O)}₂{Zn(en)₂}] ·2Hen·3H₂O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)₂ Complex Bridge

Shou Tian Zheng
, Jie Zhang
, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The hydrothermal reaction of VOSO₄, As₂O ₃, ZnCl₂, en (ethylenediamine), HCl, and H₂O produces [{{Zn(en)₂}₂-As₆V₁₅O ₄₂(H₂O)}₂{Zn(en)₂}] ·2Hen·3H₂O, which is the first dimeric As-V-O cluster linked by transition metal complex bridge. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, EPR, TGA, and IR spectrum.

Original language	English
Pages (from-to)	810-811
Number of pages	2
Journal	Chemistry Letters
Volume	32
Issue number	9
DOIs	https://doi.org/10.1246/cl.2003.810
Publication status	Published - 5 Sept 2003
Externally published	Yes

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title = "[\{\{Zn(en)2\}2As6V15O 42(H2O)\}2\{Zn(en)2\}] ·2Hen·3H2O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)2 Complex Bridge",

abstract = "The hydrothermal reaction of VOSO4, As2O 3, ZnCl2, en (ethylenediamine), HCl, and H2O produces [\{\{Zn(en)2\}2-As6V15O 42(H2O)\}2\{Zn(en)2\}] ·2Hen·3H2O, which is the first dimeric As-V-O cluster linked by transition metal complex bridge. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, EPR, TGA, and IR spectrum.",

author = "Zheng, \{Shou Tian\} and Jie Zhang and Yang, \{Guo Yu\}",

year = "2003",

month = sep,

day = "5",

doi = "10.1246/cl.2003.810",

language = "English",

volume = "32",

pages = "810--811",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

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T1 - [{{Zn(en)2}2As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)2 Complex Bridge

AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2003/9/5

Y1 - 2003/9/5

N2 - The hydrothermal reaction of VOSO4, As2O 3, ZnCl2, en (ethylenediamine), HCl, and H2O produces [{{Zn(en)2}2-As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O, which is the first dimeric As-V-O cluster linked by transition metal complex bridge. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, EPR, TGA, and IR spectrum.

AB - The hydrothermal reaction of VOSO4, As2O 3, ZnCl2, en (ethylenediamine), HCl, and H2O produces [{{Zn(en)2}2-As6V15O 42(H2O)}2{Zn(en)2}] ·2Hen·3H2O, which is the first dimeric As-V-O cluster linked by transition metal complex bridge. The structure of this compound was characterized by single crystal X-ray diffraction, elemental analysis, EPR, TGA, and IR spectrum.

UR - https://www.scopus.com/pages/publications/0347381332

U2 - 10.1246/cl.2003.810

DO - 10.1246/cl.2003.810

M3 - Article

AN - SCOPUS:0347381332

SN - 0366-7022

VL - 32

SP - 810

EP - 811

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

[{{Zn(en)₂}₂As₆V₁₅O ₄₂(H₂O)}₂{Zn(en)₂}] ·2Hen·3H₂O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)₂ Complex Bridge

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