[Zn(dap)3][Zn(dap)B5O8(OH)2]2: A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B5O8(OH)2]3− Clusters and [Zn(dap)]2+ Linkers

Hang Jiang; Bai Feng Yang; Guo Ming Wang; Guo Yu Yang

doi:10.1007/s10876-016-1149-x

[Zn(dap)₃][Zn(dap)B₅O₈(OH)₂]₂: A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B₅O₈(OH)₂]³⁻ Clusters and [Zn(dap)]²⁺ Linkers

Hang Jiang
, Bai Feng Yang
, Guo Ming Wang
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A new organic–inorganic hybrid chain-like zincoborate [Zn(dap)₃][Zn(dap)B₅O₈(OH)₂]₂ (1, dap = 1,2-diaminopropane) has been made under solvothermal conditions. The structure was determined by single crystal X-ray diffraction and further characterized by elemental analysis, FT-IR, thermogravimetric analysis and photo-luminescence spectroscopy. Crystal data for 1: orthorhombic, Pca2₁ (No. 29), a = 12.5696(4) Å, b = 12.9506(6) Å, c = 25.2370(10) Å, Z = 4. The structure of 1 features one-dimensional (1-D) inorganic–organic hybrid zincoborate helical chain, which was constructed from the assembly of [B₅O₈(OH)₂]³⁻ clusters and Zn(dap) linkers. Adjacent zincoborate chains are further linked by [Zn(dap)₃] complexes through extensive hydrogen-bonds to generate 3-D supramolecular network. Two distinct coordination-modes of zinc centers are simultaneously observed in the structure, and they play different roles in the formation of the resultant framework. In addition, 1 exhibits extensive luminescence and moderate second-harmonic generation efficiency.

Original language	English
Pages (from-to)	1421-1429
Number of pages	9
Journal	Journal of Cluster Science
Volume	28
Issue number	3
DOIs	https://doi.org/10.1007/s10876-016-1149-x
Publication status	Published - 1 May 2017

Keywords

Borate cluster
Crystal structure
Hybrid structure
Transition-metal complexes
Zincoborate

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10.1007/s10876-016-1149-x

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@article{21cbb4eb03a6461ea6a8446707e6056d,

title = "[Zn(dap)3][Zn(dap)B5O8(OH)2]2: A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B5O8(OH)2]3− Clusters and [Zn(dap)]2+ Linkers",

abstract = "A new organic–inorganic hybrid chain-like zincoborate [Zn(dap)3][Zn(dap)B5O8(OH)2]2 (1, dap = 1,2-diaminopropane) has been made under solvothermal conditions. The structure was determined by single crystal X-ray diffraction and further characterized by elemental analysis, FT-IR, thermogravimetric analysis and photo-luminescence spectroscopy. Crystal data for 1: orthorhombic, Pca21 (No. 29), a = 12.5696(4) {\AA}, b = 12.9506(6) {\AA}, c = 25.2370(10) {\AA}, Z = 4. The structure of 1 features one-dimensional (1-D) inorganic–organic hybrid zincoborate helical chain, which was constructed from the assembly of [B5O8(OH)2]3− clusters and Zn(dap) linkers. Adjacent zincoborate chains are further linked by [Zn(dap)3] complexes through extensive hydrogen-bonds to generate 3-D supramolecular network. Two distinct coordination-modes of zinc centers are simultaneously observed in the structure, and they play different roles in the formation of the resultant framework. In addition, 1 exhibits extensive luminescence and moderate second-harmonic generation efficiency.",

keywords = "Borate cluster, Crystal structure, Hybrid structure, Transition-metal complexes, Zincoborate",

author = "Hang Jiang and Yang, \{Bai Feng\} and Wang, \{Guo Ming\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2016, Springer Science+Business Media New York.",

year = "2017",

month = may,

day = "1",

doi = "10.1007/s10876-016-1149-x",

language = "English",

volume = "28",

pages = "1421--1429",

journal = "Journal of Cluster Science",

issn = "1040-7278",

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number = "3",

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T1 - [Zn(dap)3][Zn(dap)B5O8(OH)2]2

T2 - A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B5O8(OH)2]3− Clusters and [Zn(dap)]2+ Linkers

AU - Jiang, Hang

AU - Yang, Bai Feng

AU - Wang, Guo Ming

AU - Yang, Guo Yu

PY - 2017/5/1

Y1 - 2017/5/1

N2 - A new organic–inorganic hybrid chain-like zincoborate [Zn(dap)3][Zn(dap)B5O8(OH)2]2 (1, dap = 1,2-diaminopropane) has been made under solvothermal conditions. The structure was determined by single crystal X-ray diffraction and further characterized by elemental analysis, FT-IR, thermogravimetric analysis and photo-luminescence spectroscopy. Crystal data for 1: orthorhombic, Pca21 (No. 29), a = 12.5696(4) Å, b = 12.9506(6) Å, c = 25.2370(10) Å, Z = 4. The structure of 1 features one-dimensional (1-D) inorganic–organic hybrid zincoborate helical chain, which was constructed from the assembly of [B5O8(OH)2]3− clusters and Zn(dap) linkers. Adjacent zincoborate chains are further linked by [Zn(dap)3] complexes through extensive hydrogen-bonds to generate 3-D supramolecular network. Two distinct coordination-modes of zinc centers are simultaneously observed in the structure, and they play different roles in the formation of the resultant framework. In addition, 1 exhibits extensive luminescence and moderate second-harmonic generation efficiency.

AB - A new organic–inorganic hybrid chain-like zincoborate [Zn(dap)3][Zn(dap)B5O8(OH)2]2 (1, dap = 1,2-diaminopropane) has been made under solvothermal conditions. The structure was determined by single crystal X-ray diffraction and further characterized by elemental analysis, FT-IR, thermogravimetric analysis and photo-luminescence spectroscopy. Crystal data for 1: orthorhombic, Pca21 (No. 29), a = 12.5696(4) Å, b = 12.9506(6) Å, c = 25.2370(10) Å, Z = 4. The structure of 1 features one-dimensional (1-D) inorganic–organic hybrid zincoborate helical chain, which was constructed from the assembly of [B5O8(OH)2]3− clusters and Zn(dap) linkers. Adjacent zincoborate chains are further linked by [Zn(dap)3] complexes through extensive hydrogen-bonds to generate 3-D supramolecular network. Two distinct coordination-modes of zinc centers are simultaneously observed in the structure, and they play different roles in the formation of the resultant framework. In addition, 1 exhibits extensive luminescence and moderate second-harmonic generation efficiency.

KW - Borate cluster

KW - Crystal structure

KW - Hybrid structure

KW - Transition-metal complexes

KW - Zincoborate

UR - https://www.scopus.com/pages/publications/85007452818

U2 - 10.1007/s10876-016-1149-x

DO - 10.1007/s10876-016-1149-x

M3 - Article

AN - SCOPUS:85007452818

SN - 1040-7278

VL - 28

SP - 1421

EP - 1429

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 3

ER -

[Zn(dap)₃][Zn(dap)B₅O₈(OH)₂]₂: A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B₅O₈(OH)₂]³⁻ Clusters and [Zn(dap)]²⁺ Linkers

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