Zn(2,2′-bipy)2/Co(2,2′-bipy)2 linked decaniobate [Nb10O28]6- clusters-zigzag neutral chains

Long Shen; Chun Hong Li; Ying Nan Chi; Chang Wen Hu

doi:10.1016/j.inoche.2008.05.015

Zn(2,2′-bipy)₂/Co(2,2′-bipy)₂ linked decaniobate [Nb₁₀O₂₈]^6- clusters-zigzag neutral chains

Long Shen, Chun Hong Li, Ying Nan Chi^*, Chang Wen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Two isostructural decaniobate polymers {[Zn(2,2′-bipy)₂]₃[Nb₁₀O₂₈] · 3H₂O}_n (1) and {[Co(2,2′-bipy)₂]₃[Nb₁₀O₂₈] · 1.5H₂O}_n (2) have been assembled successfully based on [M(2,2′-bipy)₂] (M = Zn and Co) and metastable [Nb₁₀O₂₈]^6- clusters under mild hydrothermal condition. The two compounds have been characterized by IR, TG analysis and single-crystal X-ray diffraction. The decaniobate [Nb₁₀O₂₈]^6- linked by Zn(2,2′-bipy)₂ or Co(2,2′-bipy)₂ is first observed in polyoxoniobate chemistry as the first examples of decaniobate polymers.

Original language	English
Pages (from-to)	992-994
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	9
DOIs	https://doi.org/10.1016/j.inoche.2008.05.015
Publication status	Published - Sept 2008

Keywords

2,2′-Bipyridine
Cobalt
Decaniobate
Hydrothermal condition
Zinc

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10.1016/j.inoche.2008.05.015

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title = "Zn(2,2′-bipy)2/Co(2,2′-bipy)2 linked decaniobate [Nb10O28]6- clusters-zigzag neutral chains",

abstract = "Two isostructural decaniobate polymers {[Zn(2,2′-bipy)2]3[Nb10O28] · 3H2O}n (1) and {[Co(2,2′-bipy)2]3[Nb10O28] · 1.5H2O}n (2) have been assembled successfully based on [M(2,2′-bipy)2] (M = Zn and Co) and metastable [Nb10O28]6- clusters under mild hydrothermal condition. The two compounds have been characterized by IR, TG analysis and single-crystal X-ray diffraction. The decaniobate [Nb10O28]6- linked by Zn(2,2′-bipy)2 or Co(2,2′-bipy)2 is first observed in polyoxoniobate chemistry as the first examples of decaniobate polymers.",

keywords = "2,2′-Bipyridine, Cobalt, Decaniobate, Hydrothermal condition, Zinc",

author = "Long Shen and Li, {Chun Hong} and Chi, {Ying Nan} and Hu, {Chang Wen}",

year = "2008",

month = sep,

doi = "10.1016/j.inoche.2008.05.015",

language = "English",

volume = "11",

pages = "992--994",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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T1 - Zn(2,2′-bipy)2/Co(2,2′-bipy)2 linked decaniobate [Nb10O28]6- clusters-zigzag neutral chains

AU - Shen, Long

AU - Li, Chun Hong

AU - Chi, Ying Nan

AU - Hu, Chang Wen

PY - 2008/9

Y1 - 2008/9

N2 - Two isostructural decaniobate polymers {[Zn(2,2′-bipy)2]3[Nb10O28] · 3H2O}n (1) and {[Co(2,2′-bipy)2]3[Nb10O28] · 1.5H2O}n (2) have been assembled successfully based on [M(2,2′-bipy)2] (M = Zn and Co) and metastable [Nb10O28]6- clusters under mild hydrothermal condition. The two compounds have been characterized by IR, TG analysis and single-crystal X-ray diffraction. The decaniobate [Nb10O28]6- linked by Zn(2,2′-bipy)2 or Co(2,2′-bipy)2 is first observed in polyoxoniobate chemistry as the first examples of decaniobate polymers.

AB - Two isostructural decaniobate polymers {[Zn(2,2′-bipy)2]3[Nb10O28] · 3H2O}n (1) and {[Co(2,2′-bipy)2]3[Nb10O28] · 1.5H2O}n (2) have been assembled successfully based on [M(2,2′-bipy)2] (M = Zn and Co) and metastable [Nb10O28]6- clusters under mild hydrothermal condition. The two compounds have been characterized by IR, TG analysis and single-crystal X-ray diffraction. The decaniobate [Nb10O28]6- linked by Zn(2,2′-bipy)2 or Co(2,2′-bipy)2 is first observed in polyoxoniobate chemistry as the first examples of decaniobate polymers.

KW - 2,2′-Bipyridine

KW - Cobalt

KW - Decaniobate

KW - Hydrothermal condition

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=50249096698&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2008.05.015

DO - 10.1016/j.inoche.2008.05.015

M3 - Article

AN - SCOPUS:50249096698

SN - 1387-7003

VL - 11

SP - 992

EP - 994

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 9

ER -

Zn(2,2′-bipy)₂/Co(2,2′-bipy)₂ linked decaniobate [Nb₁₀O₂₈]^6- clusters-zigzag neutral chains

Abstract

Keywords

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