Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

Xianqiang Huang; Yifa Chen; Zhengguo Lin; Xiaoqian Ren; Yuna Song; Zhenzhu Xu; Xinmei Dong; Xingguo Li; Changwen Hu; Bo Wang

doi:10.1039/c3cc49187k

Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

Xianqiang Huang
, Yifa Chen
, Zhengguo Lin
, Xiaoqian Ren
, Yuna Song
, Zhenzhu Xu
, Xinmei Dong
, Xingguo Li
, Changwen Hu
, Bo Wang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

127 Citations (Scopus)

Abstract

Three zinc-trimesic acid (Zn-BTC) MOFs, BIT-101, BIT-102 and BIT-103, have been synthesized via a structure-directing strategy. Interestingly, BIT-102 and -103 exhibit extraordinary catalytic performance (up to Conv. 100% and Sele. 95.2%) in the cycloaddition of CO₂ under solvent- and halogen-free conditions without any additives or co-catalysts.

Original language	English
Pages (from-to)	2624-2627
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	20
DOIs	https://doi.org/10.1039/c3cc49187k
Publication status	Published - 11 Feb 2014

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title = "Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion",

abstract = "Three zinc-trimesic acid (Zn-BTC) MOFs, BIT-101, BIT-102 and BIT-103, have been synthesized via a structure-directing strategy. Interestingly, BIT-102 and -103 exhibit extraordinary catalytic performance (up to Conv. 100\% and Sele. 95.2\%) in the cycloaddition of CO2 under solvent- and halogen-free conditions without any additives or co-catalysts.",

author = "Xianqiang Huang and Yifa Chen and Zhengguo Lin and Xiaoqian Ren and Yuna Song and Zhenzhu Xu and Xinmei Dong and Xingguo Li and Changwen Hu and Bo Wang",

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doi = "10.1039/c3cc49187k",

language = "English",

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TY - JOUR

T1 - Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

AU - Huang, Xianqiang

AU - Chen, Yifa

AU - Lin, Zhengguo

AU - Ren, Xiaoqian

AU - Song, Yuna

AU - Xu, Zhenzhu

AU - Dong, Xinmei

AU - Li, Xingguo

AU - Hu, Changwen

AU - Wang, Bo

PY - 2014/2/11

Y1 - 2014/2/11

N2 - Three zinc-trimesic acid (Zn-BTC) MOFs, BIT-101, BIT-102 and BIT-103, have been synthesized via a structure-directing strategy. Interestingly, BIT-102 and -103 exhibit extraordinary catalytic performance (up to Conv. 100% and Sele. 95.2%) in the cycloaddition of CO2 under solvent- and halogen-free conditions without any additives or co-catalysts.

AB - Three zinc-trimesic acid (Zn-BTC) MOFs, BIT-101, BIT-102 and BIT-103, have been synthesized via a structure-directing strategy. Interestingly, BIT-102 and -103 exhibit extraordinary catalytic performance (up to Conv. 100% and Sele. 95.2%) in the cycloaddition of CO2 under solvent- and halogen-free conditions without any additives or co-catalysts.

UR - https://www.scopus.com/pages/publications/84893899926

U2 - 10.1039/c3cc49187k

DO - 10.1039/c3cc49187k

M3 - Article

AN - SCOPUS:84893899926

SN - 1359-7345

VL - 50

SP - 2624

EP - 2627

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

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