Zero- and one-dimensional organic-inorganic hybrid compounds based on monovacant keggin polyoxotungstates

De Juan Li; Shou Tian Zheng; Guo Yu Yang

Zero- and one-dimensional organic-inorganic hybrid compounds based on monovacant keggin polyoxotungstates

De Juan Li, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Two new organic-inorganic hybrid mono-transition-metal-substituted polyoxometalates [Ni(2,2′-bipy)₃]₃[Ni(H ₂O)SiW₁₁H₂O 1 and [Cu(dien)(H ₂O)][Cu(dien)(H₂O)₂]₂-[CuSiW ₁₁O₃₉]-5.5H₂O 2 (2,2′-bipy = 2,2′-bipyridine, dien = diethylenetriamine) have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, magnetic properties, and IR spectrum. Crystal data for 1: monoclinic, space group P2₁/n, a = 17.492(3), b = 33.481(5), c = 20.493(3) Å, β = 101.894(3)°, D_c = 2.563 mg/Å, F(000) = 8440, μ -11.454 mm^-1 and Z = 4; and those for 2: monoclinic, space group P2₁\ln, a = 11.114(3), b = 22.803(7), c = 22.468(7) Å, β = 97.896(6)°, D_c = 4.036 mg/Å³, F(000) = 6140, mu; = 23.942 mm^-1 and Z = 4. The study on the magnetic susceptibility of 2 demonstrates the presence of ferromagnetic interaction.

Original language	English
Pages (from-to)	655-662
Number of pages	8
Journal	Jiegou Huaxue
Volume	28
Issue number	6
Publication status	Published - 2009
Externally published	Yes

Keywords

Inorganic-organic
Polyoxometalate
Substituted
Transition metal

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@article{9f425bf9c4ab432f9bec15035bcbce6b,

title = "Zero- and one-dimensional organic-inorganic hybrid compounds based on monovacant keggin polyoxotungstates",

abstract = "Two new organic-inorganic hybrid mono-transition-metal-substituted polyoxometalates [Ni(2,2′-bipy)3]3[Ni(H 2O)SiW11H2O 1 and [Cu(dien)(H 2O)][Cu(dien)(H2O)2]2-[CuSiW 11O39]-5.5H2O 2 (2,2′-bipy = 2,2′-bipyridine, dien = diethylenetriamine) have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, magnetic properties, and IR spectrum. Crystal data for 1: monoclinic, space group P21/n, a = 17.492(3), b = 33.481(5), c = 20.493(3) {\AA}, β = 101.894(3)°, Dc = 2.563 mg/{\AA}, F(000) = 8440, μ -11.454 mm-1 and Z = 4; and those for 2: monoclinic, space group P21\ln, a = 11.114(3), b = 22.803(7), c = 22.468(7) {\AA}, β = 97.896(6)°, Dc = 4.036 mg/{\AA}3, F(000) = 6140, mu; = 23.942 mm-1 and Z = 4. The study on the magnetic susceptibility of 2 demonstrates the presence of ferromagnetic interaction.",

keywords = "Inorganic-organic, Polyoxometalate, Substituted, Transition metal",

author = "Li, {De Juan} and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2009",

language = "English",

volume = "28",

pages = "655--662",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "6",

}

TY - JOUR

T1 - Zero- and one-dimensional organic-inorganic hybrid compounds based on monovacant keggin polyoxotungstates

AU - Li, De Juan

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2009

Y1 - 2009

N2 - Two new organic-inorganic hybrid mono-transition-metal-substituted polyoxometalates [Ni(2,2′-bipy)3]3[Ni(H 2O)SiW11H2O 1 and [Cu(dien)(H 2O)][Cu(dien)(H2O)2]2-[CuSiW 11O39]-5.5H2O 2 (2,2′-bipy = 2,2′-bipyridine, dien = diethylenetriamine) have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, magnetic properties, and IR spectrum. Crystal data for 1: monoclinic, space group P21/n, a = 17.492(3), b = 33.481(5), c = 20.493(3) Å, β = 101.894(3)°, Dc = 2.563 mg/Å, F(000) = 8440, μ -11.454 mm-1 and Z = 4; and those for 2: monoclinic, space group P21\ln, a = 11.114(3), b = 22.803(7), c = 22.468(7) Å, β = 97.896(6)°, Dc = 4.036 mg/Å3, F(000) = 6140, mu; = 23.942 mm-1 and Z = 4. The study on the magnetic susceptibility of 2 demonstrates the presence of ferromagnetic interaction.

AB - Two new organic-inorganic hybrid mono-transition-metal-substituted polyoxometalates [Ni(2,2′-bipy)3]3[Ni(H 2O)SiW11H2O 1 and [Cu(dien)(H 2O)][Cu(dien)(H2O)2]2-[CuSiW 11O39]-5.5H2O 2 (2,2′-bipy = 2,2′-bipyridine, dien = diethylenetriamine) have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, magnetic properties, and IR spectrum. Crystal data for 1: monoclinic, space group P21/n, a = 17.492(3), b = 33.481(5), c = 20.493(3) Å, β = 101.894(3)°, Dc = 2.563 mg/Å, F(000) = 8440, μ -11.454 mm-1 and Z = 4; and those for 2: monoclinic, space group P21\ln, a = 11.114(3), b = 22.803(7), c = 22.468(7) Å, β = 97.896(6)°, Dc = 4.036 mg/Å3, F(000) = 6140, mu; = 23.942 mm-1 and Z = 4. The study on the magnetic susceptibility of 2 demonstrates the presence of ferromagnetic interaction.

KW - Inorganic-organic

KW - Polyoxometalate

KW - Substituted

KW - Transition metal

UR - http://www.scopus.com/inward/record.url?scp=67650986303&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:67650986303

SN - 0254-5861

VL - 28

SP - 655

EP - 662

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 6

ER -

Zero- and one-dimensional organic-inorganic hybrid compounds based on monovacant keggin polyoxotungstates

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