[{Za(enMe)2}2(enMe)2{Zn2As 8V12O40(H2O}]·4H 2O: A hybrid molecular material based on covalently linked inorganic Zn-As-V clusters and transition metal complexes via enMe ligands

Shou Tian Zheng; Jie Zhang; Guo Yu Yang

doi:10.1002/ejic.200400019

[{Za(enMe)₂}₂(enMe)₂{Zn₂As ₈V₁₂O₄₀(H₂O}]·4H ₂O: A hybrid molecular material based on covalently linked inorganic Zn-As-V clusters and transition metal complexes via enMe ligands

Shou Tian Zheng
, Jie Zhang
, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

A novel zinc-substituted polyoxovanadate, [{Zn(enMe)₂} ₂-(enMe)₂{Zn₂As₈V₁₂O ₄₀(H₂O)}]·4H₂O 1 (enMe = 1,2-diaminopropane), which is built up from Zn₂As₈V ₁₂O₄₀(H₂O) clusters and Zn(enMe)₂ complexes, and further connected together by trans-enMe ligands, has been hydrothermally prepared and characterized by X-ray crystallography. The study of the magnetic susceptibility of 1 demonstrates the presence of antiferromagnetic interaction between V^IV cations in 1.

Original language	English
Pages (from-to)	2004-2007
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	10
DOIs	https://doi.org/10.1002/ejic.200400019
Publication status	Published - 17 May 2004
Externally published	Yes

Keywords

Arsenic
Inorganic-organic hybrids
Polyoxometalate
Vanadium
Zinc

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10.1002/ejic.200400019

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@article{34fb6c1f2ccb4172bcf072869b6ffacc,

title = "[\{Za(enMe)2\}2(enMe)2\{Zn2As 8V12O40(H2O\}]·4H 2O: A hybrid molecular material based on covalently linked inorganic Zn-As-V clusters and transition metal complexes via enMe ligands",

abstract = "A novel zinc-substituted polyoxovanadate, [\{Zn(enMe)2\} 2-(enMe)2\{Zn2As8V12O 40(H2O)\}]·4H2O 1 (enMe = 1,2-diaminopropane), which is built up from Zn2As8V 12O40(H2O) clusters and Zn(enMe)2 complexes, and further connected together by trans-enMe ligands, has been hydrothermally prepared and characterized by X-ray crystallography. The study of the magnetic susceptibility of 1 demonstrates the presence of antiferromagnetic interaction between VIV cations in 1.",

keywords = "Arsenic, Inorganic-organic hybrids, Polyoxometalate, Vanadium, Zinc",

author = "Zheng, \{Shou Tian\} and Jie Zhang and Yang, \{Guo Yu\}",

year = "2004",

month = may,

day = "17",

doi = "10.1002/ejic.200400019",

language = "English",

pages = "2004--2007",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "10",

}

[{Za(enMe)₂}₂(enMe)₂{Zn₂As ₈V₁₂O₄₀(H₂O}]·4H ₂O: A hybrid molecular material based on covalently linked inorganic Zn-As-V clusters and transition metal complexes via enMe ligands. / Zheng, Shou Tian; Zhang, Jie ; Yang, Guo Yu.
In: European Journal of Inorganic Chemistry, No. 10, 17.05.2004, p. 2004-2007.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - [{Za(enMe)2}2(enMe)2{Zn2As 8V12O40(H2O}]·4H 2O

T2 - A hybrid molecular material based on covalently linked inorganic Zn-As-V clusters and transition metal complexes via enMe ligands

AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2004/5/17

Y1 - 2004/5/17

N2 - A novel zinc-substituted polyoxovanadate, [{Zn(enMe)2} 2-(enMe)2{Zn2As8V12O 40(H2O)}]·4H2O 1 (enMe = 1,2-diaminopropane), which is built up from Zn2As8V 12O40(H2O) clusters and Zn(enMe)2 complexes, and further connected together by trans-enMe ligands, has been hydrothermally prepared and characterized by X-ray crystallography. The study of the magnetic susceptibility of 1 demonstrates the presence of antiferromagnetic interaction between VIV cations in 1.

AB - A novel zinc-substituted polyoxovanadate, [{Zn(enMe)2} 2-(enMe)2{Zn2As8V12O 40(H2O)}]·4H2O 1 (enMe = 1,2-diaminopropane), which is built up from Zn2As8V 12O40(H2O) clusters and Zn(enMe)2 complexes, and further connected together by trans-enMe ligands, has been hydrothermally prepared and characterized by X-ray crystallography. The study of the magnetic susceptibility of 1 demonstrates the presence of antiferromagnetic interaction between VIV cations in 1.

KW - Arsenic

KW - Inorganic-organic hybrids

KW - Polyoxometalate

KW - Vanadium

KW - Zinc

UR - https://www.scopus.com/pages/publications/4544243276

U2 - 10.1002/ejic.200400019

DO - 10.1002/ejic.200400019

M3 - Article

AN - SCOPUS:4544243276

SN - 1434-1948

SP - 2004

EP - 2007

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 10

ER -

[{Za(enMe)₂}₂(enMe)₂{Zn₂As ₈V₁₂O₄₀(H₂O}]·4H ₂O: A hybrid molecular material based on covalently linked inorganic Zn-As-V clusters and transition metal complexes via enMe ligands

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Keywords

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