Vibronic coupling parameters and luminescent properties of Eu2+ doped complex alkaline earth thioaluminates

Dong Pu Zhang; Wei Xue; Zhi Nong Yu; Ting Zhang; Jian Leng; Xiang Jun Kong

doi:10.1117/12.869876

Vibronic coupling parameters and luminescent properties of Eu²⁺ doped complex alkaline earth thioaluminates

Dong Pu Zhang^*, Wei Xue, Zhi Nong Yu, Ting Zhang, Jian Leng, Xiang Jun Kong

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

3 Citations (Scopus)

Abstract

The luminescent properties of different M_x^IIM _1-x^IIAl₂S₄:Eu and M ^IIAl₂S₄:Eu are researched in this paper. A novel assessment method is used to evaluate these materials base on the configuration coordinates model. Vibronic coupling parameters of these phosphor materials can be calculated by the formula. With the calculation of characteristic energy and unitless factors, performances of M_x ^IIM_1-x^IIAl₂S₄:Eu and M^IIAl₂S₄:Eu are evaluated. We then concluded that BaAl₂S₄:Eu shows highest Φ value comparing with other single or complex thioaluminates. With increasing amounts of Ba and Ca ions in the Ba_xMg_1-xAl₂S₄:Eu and Ca_1-ySr_yAl₂S₄:Eu respectively, the complex thioaluminates gives better luminescent performance and a broad tunable emission color can be achieved.

Original language	English
Title of host publication	LED and Display Technologies
DOIs	https://doi.org/10.1117/12.869876
Publication status	Published - 2010
Externally published	Yes
Event	LED and Display Technologies - Beijing, China Duration: 18 Oct 2010 → 19 Oct 2010

Publication series

Name	Proceedings of SPIE - The International Society for Optical Engineering
Volume	7852
ISSN (Print)	0277-786X

Conference

Conference	LED and Display Technologies
Country/Territory	China
City	Beijing
Period	18/10/10 → 19/10/10

Keywords

Assessment
Crystal structure
Materials
PL spectrum
Thioaluminates

Access to Document

10.1117/12.869876

Cite this

@inproceedings{35ff2920c582482da1583e3dd7767a50,

title = "Vibronic coupling parameters and luminescent properties of Eu2+ doped complex alkaline earth thioaluminates",

abstract = "The luminescent properties of different MxIIM 1-xIIAl2S4:Eu and M IIAl2S4:Eu are researched in this paper. A novel assessment method is used to evaluate these materials base on the configuration coordinates model. Vibronic coupling parameters of these phosphor materials can be calculated by the formula. With the calculation of characteristic energy and unitless factors, performances of Mx IIM1-xIIAl2S4:Eu and MIIAl2S4:Eu are evaluated. We then concluded that BaAl2S4:Eu shows highest Φ value comparing with other single or complex thioaluminates. With increasing amounts of Ba and Ca ions in the BaxMg1-xAl2S4:Eu and Ca1-ySryAl2S4:Eu respectively, the complex thioaluminates gives better luminescent performance and a broad tunable emission color can be achieved.",

keywords = "Assessment, Crystal structure, Materials, PL spectrum, Thioaluminates",

author = "Zhang, \{Dong Pu\} and Wei Xue and Yu, \{Zhi Nong\} and Ting Zhang and Jian Leng and Kong, \{Xiang Jun\}",

year = "2010",

doi = "10.1117/12.869876",

language = "English",

isbn = "9780819483829",

series = "Proceedings of SPIE - The International Society for Optical Engineering",

booktitle = "LED and Display Technologies",

note = "LED and Display Technologies ; Conference date: 18-10-2010 Through 19-10-2010",

}

Zhang, DP, Xue, W, Yu, ZN, Zhang, T, Leng, J & Kong, XJ 2010, Vibronic coupling parameters and luminescent properties of Eu²⁺ doped complex alkaline earth thioaluminates. in LED and Display Technologies., 785210, Proceedings of SPIE - The International Society for Optical Engineering, vol. 7852, LED and Display Technologies, Beijing, China, 18/10/10. https://doi.org/10.1117/12.869876

Vibronic coupling parameters and luminescent properties of Eu²⁺ doped complex alkaline earth thioaluminates. / Zhang, Dong Pu; Xue, Wei; Yu, Zhi Nong et al.
LED and Display Technologies. 2010. 785210 (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 7852).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Vibronic coupling parameters and luminescent properties of Eu2+ doped complex alkaline earth thioaluminates

AU - Zhang, Dong Pu

AU - Xue, Wei

AU - Yu, Zhi Nong

AU - Zhang, Ting

AU - Leng, Jian

AU - Kong, Xiang Jun

PY - 2010

Y1 - 2010

N2 - The luminescent properties of different MxIIM 1-xIIAl2S4:Eu and M IIAl2S4:Eu are researched in this paper. A novel assessment method is used to evaluate these materials base on the configuration coordinates model. Vibronic coupling parameters of these phosphor materials can be calculated by the formula. With the calculation of characteristic energy and unitless factors, performances of Mx IIM1-xIIAl2S4:Eu and MIIAl2S4:Eu are evaluated. We then concluded that BaAl2S4:Eu shows highest Φ value comparing with other single or complex thioaluminates. With increasing amounts of Ba and Ca ions in the BaxMg1-xAl2S4:Eu and Ca1-ySryAl2S4:Eu respectively, the complex thioaluminates gives better luminescent performance and a broad tunable emission color can be achieved.

AB - The luminescent properties of different MxIIM 1-xIIAl2S4:Eu and M IIAl2S4:Eu are researched in this paper. A novel assessment method is used to evaluate these materials base on the configuration coordinates model. Vibronic coupling parameters of these phosphor materials can be calculated by the formula. With the calculation of characteristic energy and unitless factors, performances of Mx IIM1-xIIAl2S4:Eu and MIIAl2S4:Eu are evaluated. We then concluded that BaAl2S4:Eu shows highest Φ value comparing with other single or complex thioaluminates. With increasing amounts of Ba and Ca ions in the BaxMg1-xAl2S4:Eu and Ca1-ySryAl2S4:Eu respectively, the complex thioaluminates gives better luminescent performance and a broad tunable emission color can be achieved.

KW - Assessment

KW - Crystal structure

KW - Materials

KW - PL spectrum

KW - Thioaluminates

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M3 - Conference contribution

AN - SCOPUS:78751561910

SN - 9780819483829

T3 - Proceedings of SPIE - The International Society for Optical Engineering

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