Abstract
Aim: To investigate the synthesis of new derivatives of resorcarene and their use as separation materials. Methods: Resorcinol reacted with aldehydes in the presence of hydrochloride acid, and resorcarenes were produced. The resorcarences were derivatived using pentyl bromide and 2-chloroacetic acid. The selectivities of perpentylated resorcarenes used as gas chromatographic stationary phases were tested. Results: Perpentylated resorcarenes show excellent selectivity for separation of positional isomers. Conclusion: Perpentylated resorcarenes can be used as gas chromatographic stationary phases.
Original language | English |
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Pages (from-to) | 359-363 |
Number of pages | 5 |
Journal | Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology |
Volume | 18 |
Issue number | 3 |
Publication status | Published - 1998 |
Keywords
- Gas chromatography
- Resorcarene
- Synthesis of stationary phases