Unusual reaction of β-hydroxy α-diazo carbonyl compounds with Cl3CCN/NaH and Rh(II)-catalyzed reaction of β -trichloroacetylamino α-diazo carbonyl compounds

Weifeng Shi; Nan Jiang; Shiwei Zhang; Weiming Wu; Daming Du; Jianbo Wang

doi:10.1021/ol034550o

Unusual reaction of β-hydroxy α-diazo carbonyl compounds with Cl₃CCN/NaH and Rh(II)-catalyzed reaction of β -trichloroacetylamino α-diazo carbonyl compounds

Weifeng Shi, Nan Jiang, Shiwei Zhang, Weiming Wu, Daming Du, Jianbo Wang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

(Matrix presented) The hydroxyl group was directly converted into the trichloroacetylamino group by reacting β-hydroxy α-diazo carbonyl compounds with Cl₃CCN and NaH. Rh(II)-catalyzed reactions of the β-amino α-diazo carbonyl compounds were discussed.

Original language	English
Pages (from-to)	2243-2246
Number of pages	4
Journal	Organic Letters
Volume	5
Issue number	13
DOIs	https://doi.org/10.1021/ol034550o
Publication status	Published - 26 Jun 2003
Externally published	Yes

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10.1021/ol034550o

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title = "Unusual reaction of β-hydroxy α-diazo carbonyl compounds with Cl3CCN/NaH and Rh(II)-catalyzed reaction of β -trichloroacetylamino α-diazo carbonyl compounds",

abstract = "(Matrix presented) The hydroxyl group was directly converted into the trichloroacetylamino group by reacting β-hydroxy α-diazo carbonyl compounds with Cl3CCN and NaH. Rh(II)-catalyzed reactions of the β-amino α-diazo carbonyl compounds were discussed.",

author = "Weifeng Shi and Nan Jiang and Shiwei Zhang and Weiming Wu and Daming Du and Jianbo Wang",

year = "2003",

month = jun,

day = "26",

doi = "10.1021/ol034550o",

language = "English",

volume = "5",

pages = "2243--2246",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "13",

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TY - JOUR

T1 - Unusual reaction of β-hydroxy α-diazo carbonyl compounds with Cl3CCN/NaH and Rh(II)-catalyzed reaction of β -trichloroacetylamino α-diazo carbonyl compounds

AU - Shi, Weifeng

AU - Jiang, Nan

AU - Zhang, Shiwei

AU - Wu, Weiming

AU - Du, Daming

AU - Wang, Jianbo

PY - 2003/6/26

Y1 - 2003/6/26

N2 - (Matrix presented) The hydroxyl group was directly converted into the trichloroacetylamino group by reacting β-hydroxy α-diazo carbonyl compounds with Cl3CCN and NaH. Rh(II)-catalyzed reactions of the β-amino α-diazo carbonyl compounds were discussed.

AB - (Matrix presented) The hydroxyl group was directly converted into the trichloroacetylamino group by reacting β-hydroxy α-diazo carbonyl compounds with Cl3CCN and NaH. Rh(II)-catalyzed reactions of the β-amino α-diazo carbonyl compounds were discussed.

UR - http://www.scopus.com/inward/record.url?scp=0141853258&partnerID=8YFLogxK

U2 - 10.1021/ol034550o

DO - 10.1021/ol034550o

M3 - Article

AN - SCOPUS:0141853258

SN - 1523-7060

VL - 5

SP - 2243

EP - 2246

JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

Unusual reaction of β-hydroxy α-diazo carbonyl compounds with Cl₃CCN/NaH and Rh(II)-catalyzed reaction of β -trichloroacetylamino α-diazo carbonyl compounds

Abstract

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