Type-III Weyl semi-half-metal in an ultralight monolayer Li₂N

The interplay between magnetic ordering and band topology has emerged as a fertile ground for discovering novel quantum states with profound implications for fundamental physics and next-generation electronics. Here, we theoretically predict a different type-III Weyl semi-half-metal (SHM) state in monolayer Li₂N, uniquely combining magnetic half-metallicity and type-III Weyl semimetal characteristics. First-principles calculations reveal a fully spin polarized and critically tilted Weyl cone around the Fermi level in monolayer Li₂N, driven by p-orbital ferromagnetism. This arises from the symmetry-protected band crossing between a partially flat valence band and a highly dispersive conduction band, leading to type-III Weyl fermions with strong transport anisotropy. A low-energy k·p Hamiltonian is constructed and corresponding nontrivial edge states are uncovered to capture the topological nature of Li₂N. Notably, this Weyl SHM phase remains robust under biaxial strain ranging from −2% to 4%, with an ideal type-III Weyl fermion emerging alongside a linelike ergodic surface emerging at 3.7% strain, offering a promising platform for exploring correlated electronic phenomena. Our results establish Li₂N as a viable candidate for realizing exotic type-III Weyl SHM states and open an avenue for exploring the intricate interplay among magnetism, topology, and flat-band physics.