Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters

Zichen Zhao; Mengyun Zhao; Lan Deng; Qing Li; Jing Zhang; Haifeng Su; Hongjin Lv; Guo Yu Yang

doi:10.1039/d4cc00681j

Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters

Zichen Zhao
, Mengyun Zhao
, Lan Deng^*
, Qing Li
, Jing Zhang
, Haifeng Su
, Hongjin Lv^*
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Xiamen University

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters, [Nb₆O₁₉@Ag₄₅(ⁱPrS)₂₃(CH₃COO)₁₄] (Ag₄₅) and (H₃O)₄[Nb₆O₁₉@Ag₄₁KS_2.5O₂(H₂O)_7.5(ⁱPrS)₂₄(CH₃COO)₅] (Ag₄₁), were synthesized using a facile one-pot solvothermal approach. Single crystal X-ray diffraction analyses revealed the presence of a classical Lindqvist-type [Nb₆O₁₉]⁸⁻ anion template, with ⁱPrS⁻ and CH₃COO⁻ surface-protecting ligands in both silver clusters, which can further form two-dimensional Ag₄₅ assembly and one-dimensional Ag₄₁ chain packing structures. Both Ag₄₅ and Ag₄₁ clusters exhibited intriguing photothermal conversion properties and temperature-dependent emission behavior.

Original language	English
Pages (from-to)	5415-5418
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	41
DOIs	https://doi.org/10.1039/d4cc00681j
Publication status	Published - 23 Apr 2024

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title = "Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters",

abstract = "Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters, [Nb6O19@Ag45(iPrS)23(CH3COO)14] (Ag45) and (H3O)4[Nb6O19@Ag41KS2.5O2(H2O)7.5(iPrS)24(CH3COO)5] (Ag41), were synthesized using a facile one-pot solvothermal approach. Single crystal X-ray diffraction analyses revealed the presence of a classical Lindqvist-type [Nb6O19]8− anion template, with iPrS− and CH3COO− surface-protecting ligands in both silver clusters, which can further form two-dimensional Ag45 assembly and one-dimensional Ag41 chain packing structures. Both Ag45 and Ag41 clusters exhibited intriguing photothermal conversion properties and temperature-dependent emission behavior.",

author = "Zichen Zhao and Mengyun Zhao and Lan Deng and Qing Li and Jing Zhang and Haifeng Su and Hongjin Lv and Yang, \{Guo Yu\}",

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year = "2024",

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doi = "10.1039/d4cc00681j",

language = "English",

volume = "60",

pages = "5415--5418",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters

AU - Zhao, Zichen

AU - Zhao, Mengyun

AU - Deng, Lan

AU - Li, Qing

AU - Zhang, Jing

AU - Su, Haifeng

AU - Lv, Hongjin

AU - Yang, Guo Yu

PY - 2024/4/23

Y1 - 2024/4/23

N2 - Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters, [Nb6O19@Ag45(iPrS)23(CH3COO)14] (Ag45) and (H3O)4[Nb6O19@Ag41KS2.5O2(H2O)7.5(iPrS)24(CH3COO)5] (Ag41), were synthesized using a facile one-pot solvothermal approach. Single crystal X-ray diffraction analyses revealed the presence of a classical Lindqvist-type [Nb6O19]8− anion template, with iPrS− and CH3COO− surface-protecting ligands in both silver clusters, which can further form two-dimensional Ag45 assembly and one-dimensional Ag41 chain packing structures. Both Ag45 and Ag41 clusters exhibited intriguing photothermal conversion properties and temperature-dependent emission behavior.

AB - Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters, [Nb6O19@Ag45(iPrS)23(CH3COO)14] (Ag45) and (H3O)4[Nb6O19@Ag41KS2.5O2(H2O)7.5(iPrS)24(CH3COO)5] (Ag41), were synthesized using a facile one-pot solvothermal approach. Single crystal X-ray diffraction analyses revealed the presence of a classical Lindqvist-type [Nb6O19]8− anion template, with iPrS− and CH3COO− surface-protecting ligands in both silver clusters, which can further form two-dimensional Ag45 assembly and one-dimensional Ag41 chain packing structures. Both Ag45 and Ag41 clusters exhibited intriguing photothermal conversion properties and temperature-dependent emission behavior.

UR - https://www.scopus.com/pages/publications/85191861577

U2 - 10.1039/d4cc00681j

DO - 10.1039/d4cc00681j

M3 - Article

AN - SCOPUS:85191861577

SN - 1359-7345

VL - 60

SP - 5415

EP - 5418

JO - Chemical Communications

JF - Chemical Communications

IS - 41

ER -

Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters

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