Two porous-layered borates built by B7O13(OH) clusters and AlO4/GaO4 tetrahedra

Ya Zhuo Dong; Chong An Chen; Juan Chen; Jian Wen Cheng; Jin Hua Li; Guo Yu Yang

doi:10.1039/d2ce01336c

Two porous-layered borates built by B₇O₁₃(OH) clusters and AlO₄/GaO₄ tetrahedra

Ya Zhuo Dong
, Chong An Chen
, Juan Chen
, Jian Wen Cheng^*
, Jin Hua Li^*
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Zhejiang Normal University
Qingdao University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Two three-dimensional (3D) porous-layered borates, Na_0.5K_2.5[AlB₇O₁₃(OH)]·H₂O (1) and NaKCs[GaB₇O₁₃(OH)]·1.5H₂O (2), have been obtained under solvothermal conditions. Compound 1 crystallizes in the triclinic space group P1̄, while 2 crystallizes in the monoclinic space group P2₁/n. Compounds 1 and 2 contain similar units of B₇O₁₃(OH) and AlO₄/GaO₄; the strict alternations of B₇O₁₃(OH) clusters and AlO₄/GaO₄ resulted in 3D open-framework layers with 8-R and 13-R channels along different directions. The shapes and orientations of the channels of 1 and 2 are different due to their different space groups. It's interesting to note that three different alkali metal ions (Na⁺, K⁺, and Cs⁺) are found in different positions in 2. UV-vis diffuse reflectance analysis indicates that both compounds show a wide transparency range with a short-wavelength absorption edge below 190 nm.

Original language	English
Pages (from-to)	8027-8033
Number of pages	7
Journal	CrystEngComm
Volume	24
Issue number	45
DOIs	https://doi.org/10.1039/d2ce01336c
Publication status	Published - 4 Nov 2022

Access to Document

10.1039/d2ce01336c

Cite this

@article{8aa84b00a9a644318696d5562eb2ff60,

title = "Two porous-layered borates built by B7O13(OH) clusters and AlO4/GaO4 tetrahedra",

abstract = "Two three-dimensional (3D) porous-layered borates, Na0.5K2.5[AlB7O13(OH)]·H2O (1) and NaKCs[GaB7O13(OH)]·1.5H2O (2), have been obtained under solvothermal conditions. Compound 1 crystallizes in the triclinic space group P{\=1}, while 2 crystallizes in the monoclinic space group P21/n. Compounds 1 and 2 contain similar units of B7O13(OH) and AlO4/GaO4; the strict alternations of B7O13(OH) clusters and AlO4/GaO4 resulted in 3D open-framework layers with 8-R and 13-R channels along different directions. The shapes and orientations of the channels of 1 and 2 are different due to their different space groups. It's interesting to note that three different alkali metal ions (Na+, K+, and Cs+) are found in different positions in 2. UV-vis diffuse reflectance analysis indicates that both compounds show a wide transparency range with a short-wavelength absorption edge below 190 nm.",

author = "Dong, \{Ya Zhuo\} and Chen, \{Chong An\} and Juan Chen and Cheng, \{Jian Wen\} and Li, \{Jin Hua\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = nov,

day = "4",

doi = "10.1039/d2ce01336c",

language = "English",

volume = "24",

pages = "8027--8033",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "45",

}

TY - JOUR

T1 - Two porous-layered borates built by B7O13(OH) clusters and AlO4/GaO4 tetrahedra

AU - Dong, Ya Zhuo

AU - Chen, Chong An

AU - Chen, Juan

AU - Cheng, Jian Wen

AU - Li, Jin Hua

AU - Yang, Guo Yu

PY - 2022/11/4

Y1 - 2022/11/4

N2 - Two three-dimensional (3D) porous-layered borates, Na0.5K2.5[AlB7O13(OH)]·H2O (1) and NaKCs[GaB7O13(OH)]·1.5H2O (2), have been obtained under solvothermal conditions. Compound 1 crystallizes in the triclinic space group P1̄, while 2 crystallizes in the monoclinic space group P21/n. Compounds 1 and 2 contain similar units of B7O13(OH) and AlO4/GaO4; the strict alternations of B7O13(OH) clusters and AlO4/GaO4 resulted in 3D open-framework layers with 8-R and 13-R channels along different directions. The shapes and orientations of the channels of 1 and 2 are different due to their different space groups. It's interesting to note that three different alkali metal ions (Na+, K+, and Cs+) are found in different positions in 2. UV-vis diffuse reflectance analysis indicates that both compounds show a wide transparency range with a short-wavelength absorption edge below 190 nm.

AB - Two three-dimensional (3D) porous-layered borates, Na0.5K2.5[AlB7O13(OH)]·H2O (1) and NaKCs[GaB7O13(OH)]·1.5H2O (2), have been obtained under solvothermal conditions. Compound 1 crystallizes in the triclinic space group P1̄, while 2 crystallizes in the monoclinic space group P21/n. Compounds 1 and 2 contain similar units of B7O13(OH) and AlO4/GaO4; the strict alternations of B7O13(OH) clusters and AlO4/GaO4 resulted in 3D open-framework layers with 8-R and 13-R channels along different directions. The shapes and orientations of the channels of 1 and 2 are different due to their different space groups. It's interesting to note that three different alkali metal ions (Na+, K+, and Cs+) are found in different positions in 2. UV-vis diffuse reflectance analysis indicates that both compounds show a wide transparency range with a short-wavelength absorption edge below 190 nm.

UR - https://www.scopus.com/pages/publications/85141966838

U2 - 10.1039/d2ce01336c

DO - 10.1039/d2ce01336c

M3 - Article

AN - SCOPUS:85141966838

SN - 1466-8033

VL - 24

SP - 8027

EP - 8033

JO - CrystEngComm

JF - CrystEngComm

IS - 45

ER -

Two porous-layered borates built by B₇O₁₃(OH) clusters and AlO₄/GaO₄ tetrahedra

Abstract

Access to Document

Other files and links

Fingerprint

Cite this