Two organically templated niobium and zinconiobium fluorophosphates: Low temperature hydrothermal syntheses of NbOF(PO4)2(C 2H10N2)2 and Zn3(NbOF) (PO4)4(C2H10N2) 2

Guang Zhen Liu; Shou Tian Zheng; Guo Yu Yang

doi:10.1021/ic061752i

Two organically templated niobium and zinconiobium fluorophosphates: Low temperature hydrothermal syntheses of NbOF(PO₄)₂(C ₂H₁₀N₂)₂ and Zn₃(NbOF) (PO₄)₄(C₂H₁₀N₂) ₂

Guang Zhen Liu
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Two new niobium and zinconiobium fluorophosphates, NbOF(PO ₄)₂(C₂H₁₀N₂)₂ (1) and Zn₃(NbOF)(PO₄)₄-(C₂H ₁₀N₂)₂ (2), have been prepared under hydrothermal conditions using ethylenediamine as a template. The structures were determined by single crystal diffraction to be triclinic, space group P1 (No. 2), a = 8.1075 (6) Å, b = 9.8961 (7) Å, c = 10.1420(8) Å, α = 111.655(1)°, β = 111.51(1)°, γ = 93.206(1)°, V = 686.19(9) Å³, and Z = 2 for 1 and orthorhombic, space group Fddd (No. 70), a = 9.1928(2) Å, b = 14.2090(10) Å, c = 32.2971 (6) Å, V = 4218.66(12) Å³, and Z = 8 for 2, respectively. Compound 1 is an infinite linear chain consisting of corner-sharing [Nb ₂P₂] 4-MRs bridged at the Nb centers with organic amines situated between chains, and compound 2, containing the chains similar to that in 1, forms a zeotype framework with organic amines situated in the gismondine-type [4⁶8⁴] cavities. The topology of 2 was previously unknown with vertex symbol 4·4·4·4· 8·8 (vertex 1), 4·4·4·8₂·8· 8 (vertex 2), 4·4·8·8·8₂·8 ₂ (vertex 3), and 4·4·4·8 ₂·8·8 (vertex 4). The topological relationships between the 4-connected network of 2 and several reported (3,4)-connected networks were discussed.

Original language	English
Pages (from-to)	231-237
Number of pages	7
Journal	Inorganic Chemistry
Volume	46
Issue number	1
DOIs	https://doi.org/10.1021/ic061752i
Publication status	Published - 8 Jan 2007
Externally published	Yes

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@article{4abfb6e53f224bdd8121db63a6c7f734,

title = "Two organically templated niobium and zinconiobium fluorophosphates: Low temperature hydrothermal syntheses of NbOF(PO4)2(C 2H10N2)2 and Zn3(NbOF) (PO4)4(C2H10N2) 2",

abstract = "Two new niobium and zinconiobium fluorophosphates, NbOF(PO 4)2(C2H10N2)2 (1) and Zn3(NbOF)(PO4)4-(C2H 10N2)2 (2), have been prepared under hydrothermal conditions using ethylenediamine as a template. The structures were determined by single crystal diffraction to be triclinic, space group P1 (No. 2), a = 8.1075 (6) {\AA}, b = 9.8961 (7) {\AA}, c = 10.1420(8) {\AA}, α = 111.655(1)°, β = 111.51(1)°, γ = 93.206(1)°, V = 686.19(9) {\AA}3, and Z = 2 for 1 and orthorhombic, space group Fddd (No. 70), a = 9.1928(2) {\AA}, b = 14.2090(10) {\AA}, c = 32.2971 (6) {\AA}, V = 4218.66(12) {\AA}3, and Z = 8 for 2, respectively. Compound 1 is an infinite linear chain consisting of corner-sharing [Nb 2P2] 4-MRs bridged at the Nb centers with organic amines situated between chains, and compound 2, containing the chains similar to that in 1, forms a zeotype framework with organic amines situated in the gismondine-type [4684] cavities. The topology of 2 was previously unknown with vertex symbol 4·4·4·4· 8·8 (vertex 1), 4·4·4·82·8· 8 (vertex 2), 4·4·8·8·82·8 2 (vertex 3), and 4·4·4·8 2·8·8 (vertex 4). The topological relationships between the 4-connected network of 2 and several reported (3,4)-connected networks were discussed.",

author = "Liu, \{Guang Zhen\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2007",

month = jan,

day = "8",

doi = "10.1021/ic061752i",

language = "English",

volume = "46",

pages = "231--237",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "1",

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TY - JOUR

T1 - Two organically templated niobium and zinconiobium fluorophosphates

T2 - Low temperature hydrothermal syntheses of NbOF(PO4)2(C 2H10N2)2 and Zn3(NbOF) (PO4)4(C2H10N2) 2

AU - Liu, Guang Zhen

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2007/1/8

Y1 - 2007/1/8

N2 - Two new niobium and zinconiobium fluorophosphates, NbOF(PO 4)2(C2H10N2)2 (1) and Zn3(NbOF)(PO4)4-(C2H 10N2)2 (2), have been prepared under hydrothermal conditions using ethylenediamine as a template. The structures were determined by single crystal diffraction to be triclinic, space group P1 (No. 2), a = 8.1075 (6) Å, b = 9.8961 (7) Å, c = 10.1420(8) Å, α = 111.655(1)°, β = 111.51(1)°, γ = 93.206(1)°, V = 686.19(9) Å3, and Z = 2 for 1 and orthorhombic, space group Fddd (No. 70), a = 9.1928(2) Å, b = 14.2090(10) Å, c = 32.2971 (6) Å, V = 4218.66(12) Å3, and Z = 8 for 2, respectively. Compound 1 is an infinite linear chain consisting of corner-sharing [Nb 2P2] 4-MRs bridged at the Nb centers with organic amines situated between chains, and compound 2, containing the chains similar to that in 1, forms a zeotype framework with organic amines situated in the gismondine-type [4684] cavities. The topology of 2 was previously unknown with vertex symbol 4·4·4·4· 8·8 (vertex 1), 4·4·4·82·8· 8 (vertex 2), 4·4·8·8·82·8 2 (vertex 3), and 4·4·4·8 2·8·8 (vertex 4). The topological relationships between the 4-connected network of 2 and several reported (3,4)-connected networks were discussed.

AB - Two new niobium and zinconiobium fluorophosphates, NbOF(PO 4)2(C2H10N2)2 (1) and Zn3(NbOF)(PO4)4-(C2H 10N2)2 (2), have been prepared under hydrothermal conditions using ethylenediamine as a template. The structures were determined by single crystal diffraction to be triclinic, space group P1 (No. 2), a = 8.1075 (6) Å, b = 9.8961 (7) Å, c = 10.1420(8) Å, α = 111.655(1)°, β = 111.51(1)°, γ = 93.206(1)°, V = 686.19(9) Å3, and Z = 2 for 1 and orthorhombic, space group Fddd (No. 70), a = 9.1928(2) Å, b = 14.2090(10) Å, c = 32.2971 (6) Å, V = 4218.66(12) Å3, and Z = 8 for 2, respectively. Compound 1 is an infinite linear chain consisting of corner-sharing [Nb 2P2] 4-MRs bridged at the Nb centers with organic amines situated between chains, and compound 2, containing the chains similar to that in 1, forms a zeotype framework with organic amines situated in the gismondine-type [4684] cavities. The topology of 2 was previously unknown with vertex symbol 4·4·4·4· 8·8 (vertex 1), 4·4·4·82·8· 8 (vertex 2), 4·4·8·8·82·8 2 (vertex 3), and 4·4·4·8 2·8·8 (vertex 4). The topological relationships between the 4-connected network of 2 and several reported (3,4)-connected networks were discussed.

UR - https://www.scopus.com/pages/publications/33846455060

U2 - 10.1021/ic061752i

DO - 10.1021/ic061752i

M3 - Article

AN - SCOPUS:33846455060

SN - 0020-1669

VL - 46

SP - 231

EP - 237

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 1

ER -

Two organically templated niobium and zinconiobium fluorophosphates: Low temperature hydrothermal syntheses of NbOF(PO₄)₂(C ₂H₁₀N₂)₂ and Zn₃(NbOF) (PO₄)₄(C₂H₁₀N₂) ₂

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