Two novel self-interpenetrating 3D iron(II) coordination frameworks: Synthesis, spectroscopic and structural characterizations with magnetic properties

Zouaoui Setifi; Abderazzak Addala; Jun Tao; Nanthawat Wannarit; Christopher Glidewell; Fatima Setifi; Sujittra Youngme

doi:10.1016/j.inoche.2016.04.005

Two novel self-interpenetrating 3D iron(II) coordination frameworks: Synthesis, spectroscopic and structural characterizations with magnetic properties

Zouaoui Setifi, Abderazzak Addala, Jun Tao, Nanthawat Wannarit^*, Christopher Glidewell, Fatima Setifi, Sujittra Youngme

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag₂(CN)₃]₂}_n (I) and {Fe(4,4′-bpy)[Ag(CN)₂]₂[AgCN]₂}_n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag₂(CN)₃]^- species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)₂]^- resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by Ag^I ⋯ Ag^I interactions. Their magnetic properties exhibit high spin behavior.

Original language	English
Pages (from-to)	80-84
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	68
DOIs	https://doi.org/10.1016/j.inoche.2016.04.005
Publication status	Published - Jun 2016
Externally published	Yes

Keywords

Ag ⋯ Ag
Fe(II) coordination frameworks
Magnetic properties
Self-interpenetrate

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10.1016/j.inoche.2016.04.005

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@article{71d429fede2748208cb5af39611af93b,

title = "Two novel self-interpenetrating 3D iron(II) coordination frameworks: Synthesis, spectroscopic and structural characterizations with magnetic properties",

abstract = "Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n (I) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]- species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]- resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.",

keywords = "Ag ⋯ Ag, Fe(II) coordination frameworks, Magnetic properties, Self-interpenetrate",

author = "Zouaoui Setifi and Abderazzak Addala and Jun Tao and Nanthawat Wannarit and Christopher Glidewell and Fatima Setifi and Sujittra Youngme",

year = "2016",

month = jun,

doi = "10.1016/j.inoche.2016.04.005",

language = "English",

volume = "68",

pages = "80--84",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

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T1 - Two novel self-interpenetrating 3D iron(II) coordination frameworks

T2 - Synthesis, spectroscopic and structural characterizations with magnetic properties

AU - Setifi, Zouaoui

AU - Addala, Abderazzak

AU - Tao, Jun

AU - Wannarit, Nanthawat

AU - Glidewell, Christopher

AU - Setifi, Fatima

AU - Youngme, Sujittra

PY - 2016/6

Y1 - 2016/6

N2 - Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n (I) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]- species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]- resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.

AB - Two novel self-interpenetrating 3D Fe(II) coordination frameworks namely {Fe(4,4′-bpy)[Ag2(CN)3]2}n (I) and {Fe(4,4′-bpy)[Ag(CN)2]2[AgCN]2}n (II) have been synthesized and fully characterized. The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species. The crystal structure of I presents 4-fold interpenetrating 3D framework with 4,4′-bpy and [Ag2(CN)3]- species. While, that of II constructed by 4,4′-bpy and two different silver(I) cyanide species, AgCN and [Ag(CN)2]- resulting to 2-fold interpenetrating 3D framework. The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions. Their magnetic properties exhibit high spin behavior.

KW - Ag ⋯ Ag

KW - Fe(II) coordination frameworks

KW - Magnetic properties

KW - Self-interpenetrate

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DO - 10.1016/j.inoche.2016.04.005

M3 - Article

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SN - 1387-7003

VL - 68

SP - 80

EP - 84

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Two novel self-interpenetrating 3D iron(II) coordination frameworks: Synthesis, spectroscopic and structural characterizations with magnetic properties

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Keywords

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