Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

Lei Lei Li; Rui Pan; Jun Wei Zhao; Bai Feng Yang; Guo Yu Yang

doi:10.1039/c6dt01909a

Two novel pillared-layer lanthanide borates built by Ln@B₁₂O_28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

Lei Lei Li
, Rui Pan
, Jun Wei Zhao
, Bai Feng Yang
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Henan University
Shantou University

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln₂B₈O₁₂(bdc)₃(H₂O)]·H₂O (Ln = Pr, 1; Nd, 2; H₂bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B₁₂O₂₈/Ln@B₁₂O₂₉, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.

Original language	English
Pages (from-to)	11628-11632
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	29
DOIs	https://doi.org/10.1039/c6dt01909a
Publication status	Published - 2016

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title = "Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)",

abstract = "Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln2B8O12(bdc)3(H2O)]·H2O (Ln = Pr, 1; Nd, 2; H2bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B12O28/Ln@B12O29, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.",

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year = "2016",

doi = "10.1039/c6dt01909a",

language = "English",

volume = "45",

pages = "11628--11632",

journal = "Dalton Transactions",

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T1 - Two novel pillared-layer lanthanide borates built by Ln@B12O28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

AU - Li, Lei Lei

AU - Pan, Rui

AU - Zhao, Jun Wei

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2016

Y1 - 2016

N2 - Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln2B8O12(bdc)3(H2O)]·H2O (Ln = Pr, 1; Nd, 2; H2bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B12O28/Ln@B12O29, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.

AB - Two organic-inorganic hybrid pillared-layer lanthanide borates, [Ln2B8O12(bdc)3(H2O)]·H2O (Ln = Pr, 1; Nd, 2; H2bdc = 1,4-benzene dicarboxylic acid), have been made, in which inorganic layers are built by Ln-centred oxoboron ring clusters, Ln@B12O28/Ln@B12O29, while the pillars are organic bdc linkers. Interestingly, two types of linkages, Ln-O-C and B-O-C bonds, exist in the structures, showing firstly novel linking modes between inorganic polyborate and organic dicarboxylate.

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DO - 10.1039/c6dt01909a

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SN - 1477-9226

VL - 45

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JO - Dalton Transactions

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IS - 29

ER -

Two novel pillared-layer lanthanide borates built by Ln@B₁₂O_28/29 ring clusters and dicarboxylate linkers (Ln = Pr, Nd)

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