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Two novel coordination polymers with different molecular tectonics based on cobalt-succinate-organoamine systems

  • Yun Gong
  • , Changwen Hu*
  • , Hui Li
  • , Wang Tang
  • *Corresponding author for this work
  • Beijing Institute of Technology

Research output: Contribution to journalArticlepeer-review

Abstract

Two novel coordination polymers with different N-donors, [Co(suc)(im)] n (1) and [Co(suc)(phen)]n (2) (suc = succinic dianion, im = imidazole, phen = 1,10-phenanthroline) were synthesized by solvothermal technique and structurally characterized by elemental analysis, IR and single crystal X-ray diffraction. Compound 1 exhibits a novel molecular tectonics like fourfold entangled catenane. Compound 2 shows a two-dimensional structure with two types of rings observed. They exhibit different photoluminescence properties.

Original languageEnglish
Pages (from-to)273-276
Number of pages4
JournalInorganic Chemistry Communications
Volume9
Issue number3
DOIs
Publication statusPublished - Mar 2006

Keywords

  • N-donor
  • Photoluminescence
  • Succinic anion
  • Tectonics

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