Two novel 2D lanthanide-organic frameworks based on different carboxylate-containing mixed ligands

Zhi Long Wang; Shou Tian Zheng; Guo Yua Yang

Two novel 2D lanthanide-organic frameworks based on different carboxylate-containing mixed ligands

Zhi Long Wang
, Shou Tian Zheng
, Guo Yua Yang

CAS - Fujian Institute of Research on the Structure of Matter
University of Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Two novel lanthanide-organic polymers [Er₂(pdc) ₂(o-bdc)(H₂O)₂(1, H₂O (1, H ₂pdc = 2,6-pyridinedicarboxylic acid, O-H₂bdc = 1,2-benzenedicarboxylic acid) and Er(Himdc)(m-bdc)0.5(H₂O) (2, H ₃imdc = 4,5-imidazoledicarboxylic acid, m-H₂bdc = 1,3-benzenedicarboxylic acid) have been synthesized and characterized by elemental analysis, IR, thermogravimetric analysis and X-ray single-crystal diffraction studies. 1 crystallizes in monoclinic, space group P2₁/c, while 2 in the orthorhombic space group Pbcn. Both compounds 1 and 2 display two-dimensional network structures. For 1, the tetranuclear parallelogram {Er₄} cluster as a building block is further assembled into a wonderful 2D grid, and the layers are interconnected via hydrogen bonds and nπ-π stacking interactions to yield a 3D supramolecular architecture; for 2, its configuration is a rare double-decker structure. These two complexes represent good examples for using mix-carboxylate-containing ligands to construct diverse 2D lanthanide coordination polymers.

Original language	English
Pages (from-to)	17-22
Number of pages	6
Journal	Jiegou Huaxue
Volume	29
Issue number	1
Publication status	Published - 2010
Externally published	Yes

Keywords

Carboxylate-containing
Hydrothermal synthesis
Lanthanide
Ligands

Cite this

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title = "Two novel 2D lanthanide-organic frameworks based on different carboxylate-containing mixed ligands",

abstract = "Two novel lanthanide-organic polymers [Er2(pdc) 2(o-bdc)(H2O)2(1, H2O (1, H 2pdc = 2,6-pyridinedicarboxylic acid, O-H2bdc = 1,2-benzenedicarboxylic acid) and Er(Himdc)(m-bdc)0.5(H2O) (2, H 3imdc = 4,5-imidazoledicarboxylic acid, m-H2bdc = 1,3-benzenedicarboxylic acid) have been synthesized and characterized by elemental analysis, IR, thermogravimetric analysis and X-ray single-crystal diffraction studies. 1 crystallizes in monoclinic, space group P21/c, while 2 in the orthorhombic space group Pbcn. Both compounds 1 and 2 display two-dimensional network structures. For 1, the tetranuclear parallelogram \{Er4\} cluster as a building block is further assembled into a wonderful 2D grid, and the layers are interconnected via hydrogen bonds and nπ-π stacking interactions to yield a 3D supramolecular architecture; for 2, its configuration is a rare double-decker structure. These two complexes represent good examples for using mix-carboxylate-containing ligands to construct diverse 2D lanthanide coordination polymers.",

keywords = "Carboxylate-containing, Hydrothermal synthesis, Lanthanide, Ligands",

author = "Wang, \{Zhi Long\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yua\}",

year = "2010",

language = "English",

volume = "29",

pages = "17--22",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "1",

}

TY - JOUR

T1 - Two novel 2D lanthanide-organic frameworks based on different carboxylate-containing mixed ligands

AU - Wang, Zhi Long

AU - Zheng, Shou Tian

AU - Yang, Guo Yua

PY - 2010

Y1 - 2010

N2 - Two novel lanthanide-organic polymers [Er2(pdc) 2(o-bdc)(H2O)2(1, H2O (1, H 2pdc = 2,6-pyridinedicarboxylic acid, O-H2bdc = 1,2-benzenedicarboxylic acid) and Er(Himdc)(m-bdc)0.5(H2O) (2, H 3imdc = 4,5-imidazoledicarboxylic acid, m-H2bdc = 1,3-benzenedicarboxylic acid) have been synthesized and characterized by elemental analysis, IR, thermogravimetric analysis and X-ray single-crystal diffraction studies. 1 crystallizes in monoclinic, space group P21/c, while 2 in the orthorhombic space group Pbcn. Both compounds 1 and 2 display two-dimensional network structures. For 1, the tetranuclear parallelogram {Er4} cluster as a building block is further assembled into a wonderful 2D grid, and the layers are interconnected via hydrogen bonds and nπ-π stacking interactions to yield a 3D supramolecular architecture; for 2, its configuration is a rare double-decker structure. These two complexes represent good examples for using mix-carboxylate-containing ligands to construct diverse 2D lanthanide coordination polymers.

AB - Two novel lanthanide-organic polymers [Er2(pdc) 2(o-bdc)(H2O)2(1, H2O (1, H 2pdc = 2,6-pyridinedicarboxylic acid, O-H2bdc = 1,2-benzenedicarboxylic acid) and Er(Himdc)(m-bdc)0.5(H2O) (2, H 3imdc = 4,5-imidazoledicarboxylic acid, m-H2bdc = 1,3-benzenedicarboxylic acid) have been synthesized and characterized by elemental analysis, IR, thermogravimetric analysis and X-ray single-crystal diffraction studies. 1 crystallizes in monoclinic, space group P21/c, while 2 in the orthorhombic space group Pbcn. Both compounds 1 and 2 display two-dimensional network structures. For 1, the tetranuclear parallelogram {Er4} cluster as a building block is further assembled into a wonderful 2D grid, and the layers are interconnected via hydrogen bonds and nπ-π stacking interactions to yield a 3D supramolecular architecture; for 2, its configuration is a rare double-decker structure. These two complexes represent good examples for using mix-carboxylate-containing ligands to construct diverse 2D lanthanide coordination polymers.

KW - Carboxylate-containing

KW - Hydrothermal synthesis

KW - Lanthanide

KW - Ligands

UR - https://www.scopus.com/pages/publications/77149169744

M3 - Article

AN - SCOPUS:77149169744

SN - 0254-5861

VL - 29

SP - 17

EP - 22

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 1

ER -

Two novel 2D lanthanide-organic frameworks based on different carboxylate-containing mixed ligands

Abstract

Keywords

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