Two noncentrosymmetric new crystals with high phase transition temperatures: [(parachloroanilinum+)(18-crown-6)][ClO4                             -](CH3COCH3) and [(parachloroanilinum+)(18-crown-6)][BF4                             -](CH3COCH3)

Tiantian Kang; Jing Wang; Fanghua Zhao; Duanliang Wang; Chuanying Shen; Yude Wang; Fan Meng; Zixiao Cui; Jiyang Wang

doi:10.35848/1882-0786/ab7483

Two noncentrosymmetric new crystals with high phase transition temperatures: [(parachloroanilinum⁺)(18-crown-6)][ClO₄ ^-](CH₃COCH₃) and [(parachloroanilinum⁺)(18-crown-6)][BF₄ ^-](CH₃COCH₃)

Tiantian Kang, Jing Wang, Fanghua Zhao, Duanliang Wang, Chuanying Shen, Yude Wang, Fan Meng, Zixiao Cui, Jiyang Wang

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Organic-inorganic hybrid new crystals, [(parachloroanilinum⁺)(18-crown-6)][ClO₄ ^-](CH₃COCH₃) and [(parachloroanilinum⁺)(18-crown-6)][BF₄ ^-](CH₃COCH₃), with high phase transition temperatures and noncentrosymmetric structures were grown. Their physical properties, including their structures, phase transitions, and dielectric, piezoelectric and photoluminescent properties, were systematically investigated. A phase transition at 71 °C was successively detected and confirmed by DSC and dielectric measurements. Piezoelectric features were clearly verified by piezoresponse force microscopy. Both compounds show strong and wide photoluminescent properties. All the results make the two compounds promising candidates for potential applications in the piezoelectric and optical fields.

Original language	English
Article number	035503
Journal	Applied Physics Express
Volume	13
Issue number	3
DOIs	https://doi.org/10.35848/1882-0786/ab7483
Publication status	Published - 1 Mar 2020
Externally published	Yes

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Kang, T., Wang, J., Zhao, F., Wang, D., Shen, C., Wang, Y., Meng, F., Cui, Z., & Wang, J. (2020). Two noncentrosymmetric new crystals with high phase transition temperatures: [(parachloroanilinum⁺)(18-crown-6)][ClO₄ ^-](CH₃COCH₃) and [(parachloroanilinum⁺)(18-crown-6)][BF₄ ^-](CH₃COCH₃). Applied Physics Express, 13(3), Article 035503. https://doi.org/10.35848/1882-0786/ab7483

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title = "Two noncentrosymmetric new crystals with high phase transition temperatures: [(parachloroanilinum+)(18-crown-6)][ClO4 -](CH3COCH3) and [(parachloroanilinum+)(18-crown-6)][BF4 -](CH3COCH3)",

abstract = "Organic-inorganic hybrid new crystals, [(parachloroanilinum+)(18-crown-6)][ClO4 -](CH3COCH3) and [(parachloroanilinum+)(18-crown-6)][BF4 -](CH3COCH3), with high phase transition temperatures and noncentrosymmetric structures were grown. Their physical properties, including their structures, phase transitions, and dielectric, piezoelectric and photoluminescent properties, were systematically investigated. A phase transition at 71 °C was successively detected and confirmed by DSC and dielectric measurements. Piezoelectric features were clearly verified by piezoresponse force microscopy. Both compounds show strong and wide photoluminescent properties. All the results make the two compounds promising candidates for potential applications in the piezoelectric and optical fields.",

author = "Tiantian Kang and Jing Wang and Fanghua Zhao and Duanliang Wang and Chuanying Shen and Yude Wang and Fan Meng and Zixiao Cui and Jiyang Wang",

note = "Publisher Copyright: {\textcopyright} 2020 The Japan Society of Applied Physics.",

year = "2020",

month = mar,

day = "1",

doi = "10.35848/1882-0786/ab7483",

language = "English",

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Kang, T, Wang, J, Zhao, F, Wang, D, Shen, C, Wang, Y, Meng, F, Cui, Z & Wang, J 2020, 'Two noncentrosymmetric new crystals with high phase transition temperatures: [(parachloroanilinum⁺)(18-crown-6)][ClO₄ ^-](CH₃COCH₃) and [(parachloroanilinum⁺)(18-crown-6)][BF₄ ^-](CH₃COCH₃)', Applied Physics Express, vol. 13, no. 3, 035503. https://doi.org/10.35848/1882-0786/ab7483

Two noncentrosymmetric new crystals with high phase transition temperatures: [(parachloroanilinum⁺)(18-crown-6)][ClO₄ ^-](CH₃COCH₃) and [(parachloroanilinum⁺)(18-crown-6)][BF₄ ^-](CH₃COCH₃). / Kang, Tiantian; Wang, Jing; Zhao, Fanghua et al.
In: Applied Physics Express, Vol. 13, No. 3, 035503, 01.03.2020.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Two noncentrosymmetric new crystals with high phase transition temperatures

T2 - [(parachloroanilinum+)(18-crown-6)][ClO4 -](CH3COCH3) and [(parachloroanilinum+)(18-crown-6)][BF4 -](CH3COCH3)

AU - Kang, Tiantian

AU - Wang, Jing

AU - Zhao, Fanghua

AU - Wang, Duanliang

AU - Shen, Chuanying

AU - Wang, Yude

AU - Meng, Fan

AU - Cui, Zixiao

AU - Wang, Jiyang

PY - 2020/3/1

Y1 - 2020/3/1

N2 - Organic-inorganic hybrid new crystals, [(parachloroanilinum+)(18-crown-6)][ClO4 -](CH3COCH3) and [(parachloroanilinum+)(18-crown-6)][BF4 -](CH3COCH3), with high phase transition temperatures and noncentrosymmetric structures were grown. Their physical properties, including their structures, phase transitions, and dielectric, piezoelectric and photoluminescent properties, were systematically investigated. A phase transition at 71 °C was successively detected and confirmed by DSC and dielectric measurements. Piezoelectric features were clearly verified by piezoresponse force microscopy. Both compounds show strong and wide photoluminescent properties. All the results make the two compounds promising candidates for potential applications in the piezoelectric and optical fields.

AB - Organic-inorganic hybrid new crystals, [(parachloroanilinum+)(18-crown-6)][ClO4 -](CH3COCH3) and [(parachloroanilinum+)(18-crown-6)][BF4 -](CH3COCH3), with high phase transition temperatures and noncentrosymmetric structures were grown. Their physical properties, including their structures, phase transitions, and dielectric, piezoelectric and photoluminescent properties, were systematically investigated. A phase transition at 71 °C was successively detected and confirmed by DSC and dielectric measurements. Piezoelectric features were clearly verified by piezoresponse force microscopy. Both compounds show strong and wide photoluminescent properties. All the results make the two compounds promising candidates for potential applications in the piezoelectric and optical fields.

UR - https://www.scopus.com/pages/publications/85082683204

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DO - 10.35848/1882-0786/ab7483

M3 - Article

AN - SCOPUS:85082683204

SN - 1882-0778

VL - 13

JO - Applied Physics Express

JF - Applied Physics Express

IS - 3

M1 - 035503

ER -

Kang T, Wang J, Zhao F, Wang D, Shen C, Wang Y et al. Two noncentrosymmetric new crystals with high phase transition temperatures: [(parachloroanilinum⁺)(18-crown-6)][ClO₄ ^-](CH₃COCH₃) and [(parachloroanilinum⁺)(18-crown-6)][BF₄ ^-](CH₃COCH₃). Applied Physics Express. 2020 Mar 1;13(3):035503. doi: 10.35848/1882-0786/ab7483

Two noncentrosymmetric new crystals with high phase transition temperatures: [(parachloroanilinum⁺)(18-crown-6)][ClO₄ ^-](CH₃COCH₃) and [(parachloroanilinum⁺)(18-crown-6)][BF₄ ^-](CH₃COCH₃)

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