Two New Borates Containing [B5O6(OH)4] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH3COO− Group

Yuan Liu; Huan He; Bai Feng Yang; Qiang Zhang; Guo Yu Yang

doi:10.1007/s10876-015-0845-2

Two New Borates Containing [B₅O₆(OH)₄] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH₃COO⁻ Group

Yuan Liu, Huan He, Bai Feng Yang, Qiang Zhang^*, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Two new borate clusters, [C₄H₁₁N₂O][C₄H₉N₂][B₅O₆(OH)₄]₂ (1), [Cd(dien)₂][B₅O₆(OH)₄]₂ (2, dien = diethylenetriamine), have been obtained under solvothermal conditions and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray structural analysis, respectively. Crystal data for 1: monoclinic, P2₁/c, a = 18.6975(5) Å, b = 15.3413(8) Å, c = 9.6691(3) Å, β = 90.462(3)°, Z = 4. Crystal data for 2: triclinic, P-1, a = 8.6107(4) Å, b = 9.3504(4) Å, c = 18.9631(4) Å, α = 103.798(4), β = 91.940(4)°, γ = 94.134(4)°, Z = 2. They all consist of [B₅O₆(OH)₄]⁻ clusters and further extend to 3-D frameworks via extensive hydrogen-bonding interactions. Interestingly, a novel in situ organic reaction between ethylenediamine and CH₃COO⁻ group has been observed during the formation of compound 1.

Original language	English
Pages (from-to)	1537-1545
Number of pages	9
Journal	Journal of Cluster Science
Volume	26
Issue number	5
DOIs	https://doi.org/10.1007/s10876-015-0845-2
Publication status	Published - 24 Sept 2015

Keywords

Amine
Borates
Crystal structure
In situ reaction
Solvothermal synthesis

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10.1007/s10876-015-0845-2

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@article{be2004c94c1648b89f48729724c2ae0a,

title = "Two New Borates Containing [B5O6(OH)4] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH3COO− Group",

abstract = "Two new borate clusters, [C4H11N2O][C4H9N2][B5O6(OH)4]2 (1), [Cd(dien)2][B5O6(OH)4]2 (2, dien = diethylenetriamine), have been obtained under solvothermal conditions and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray structural analysis, respectively. Crystal data for 1: monoclinic, P21/c, a = 18.6975(5) {\AA}, b = 15.3413(8) {\AA}, c = 9.6691(3) {\AA}, β = 90.462(3)°, Z = 4. Crystal data for 2: triclinic, P-1, a = 8.6107(4) {\AA}, b = 9.3504(4) {\AA}, c = 18.9631(4) {\AA}, α = 103.798(4), β = 91.940(4)°, γ = 94.134(4)°, Z = 2. They all consist of [B5O6(OH)4]− clusters and further extend to 3-D frameworks via extensive hydrogen-bonding interactions. Interestingly, a novel in situ organic reaction between ethylenediamine and CH3COO− group has been observed during the formation of compound 1.",

keywords = "Amine, Borates, Crystal structure, In situ reaction, Solvothermal synthesis",

author = "Yuan Liu and Huan He and Yang, \{Bai Feng\} and Qiang Zhang and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2015, Springer Science+Business Media New York.",

year = "2015",

month = sep,

day = "24",

doi = "10.1007/s10876-015-0845-2",

language = "English",

volume = "26",

pages = "1537--1545",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "5",

}

TY - JOUR

T1 - Two New Borates Containing [B5O6(OH)4] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH3COO− Group

AU - Liu, Yuan

AU - He, Huan

AU - Yang, Bai Feng

AU - Zhang, Qiang

AU - Yang, Guo Yu

PY - 2015/9/24

Y1 - 2015/9/24

N2 - Two new borate clusters, [C4H11N2O][C4H9N2][B5O6(OH)4]2 (1), [Cd(dien)2][B5O6(OH)4]2 (2, dien = diethylenetriamine), have been obtained under solvothermal conditions and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray structural analysis, respectively. Crystal data for 1: monoclinic, P21/c, a = 18.6975(5) Å, b = 15.3413(8) Å, c = 9.6691(3) Å, β = 90.462(3)°, Z = 4. Crystal data for 2: triclinic, P-1, a = 8.6107(4) Å, b = 9.3504(4) Å, c = 18.9631(4) Å, α = 103.798(4), β = 91.940(4)°, γ = 94.134(4)°, Z = 2. They all consist of [B5O6(OH)4]− clusters and further extend to 3-D frameworks via extensive hydrogen-bonding interactions. Interestingly, a novel in situ organic reaction between ethylenediamine and CH3COO− group has been observed during the formation of compound 1.

AB - Two new borate clusters, [C4H11N2O][C4H9N2][B5O6(OH)4]2 (1), [Cd(dien)2][B5O6(OH)4]2 (2, dien = diethylenetriamine), have been obtained under solvothermal conditions and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray structural analysis, respectively. Crystal data for 1: monoclinic, P21/c, a = 18.6975(5) Å, b = 15.3413(8) Å, c = 9.6691(3) Å, β = 90.462(3)°, Z = 4. Crystal data for 2: triclinic, P-1, a = 8.6107(4) Å, b = 9.3504(4) Å, c = 18.9631(4) Å, α = 103.798(4), β = 91.940(4)°, γ = 94.134(4)°, Z = 2. They all consist of [B5O6(OH)4]− clusters and further extend to 3-D frameworks via extensive hydrogen-bonding interactions. Interestingly, a novel in situ organic reaction between ethylenediamine and CH3COO− group has been observed during the formation of compound 1.

KW - Amine

KW - Borates

KW - Crystal structure

KW - In situ reaction

KW - Solvothermal synthesis

UR - https://www.scopus.com/pages/publications/84939772148

U2 - 10.1007/s10876-015-0845-2

DO - 10.1007/s10876-015-0845-2

M3 - Article

AN - SCOPUS:84939772148

SN - 1040-7278

VL - 26

SP - 1537

EP - 1545

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 5

ER -

Two New Borates Containing [B₅O₆(OH)₄] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH₃COO⁻ Group

Abstract

Keywords

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