Two Hexa-Ni-Substituted AsW9O34 Clusters Functionalized by Organic Ligands

Bin Cai; Jun Wei Zhao; Bai Feng Yang; Huan He; Guo Yu Yang

doi:10.1007/s10876-014-0688-2

Two Hexa-Ni-Substituted AsW₉O₃₄ Clusters Functionalized by Organic Ligands

Bin Cai, Jun Wei Zhao^*, Bai Feng Yang, Huan He, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Hydrothermal reactions of trilacunary precursor A-α-AsW₉O₃₄ ^9- polyoxoanions and nickel ions in the presence of ethylenediamine (en = ethylenediamine) led to two new hexa-Ni-substituted Keggin-type tungstoarsenates [Ni₆(μ ₃-OH)₃(en)₃(H₂O)₆(B-α-AsW₉O₃₄)]·6H₂O (1) and [Ni₆(μ ₃-OH)₃(en)₃(H₂O)₆(B-α-AsW₉O₃₄)]·10H₂O (2), which have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction. Crystal data for 1: hexagonal, R3c, a = b = 20.4379(5) Å, c = 21.5062(6) Å, β = 120^o, V = 7779.8 (3) Å³ and Z = 6; for 2: momoclinic, P2₁/c, a = 13.4200(3) Å, b = 19.1428(5) Å, c = 22.8845(9) Å, β = 112.403(3)^o, V = 5435.2(3) Å³ and Z = 4. Structural analyses reveal that the [Ni₆(μ ₃-OH)₃(B-α-AsW₉O₃₄)] clusters in 1 and 2 are covalently functionalized by neutral en ligands, in which two similar {Ni₆(μ ₃-OH)₃(en)₃(H₂O)₆}⁹⁺ cores have been observed by our lab. Notably, 1 and 2 represent the highest number of substituted transition metal ions in all known lacunary Keggin-type polyoxotungstoarsenate monomers.

Original language	English
Pages (from-to)	1047-1059
Number of pages	13
Journal	Journal of Cluster Science
Volume	25
Issue number	4
DOIs	https://doi.org/10.1007/s10876-014-0688-2
Publication status	Published - Jul 2014

Keywords

Hydrothermal synthesis
Lacunary precursor
Organic functionalization
Substituted polyoxotungstoarsenate

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10.1007/s10876-014-0688-2

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@article{a97ae580637844e8acbdacd70edbf77b,

title = "Two Hexa-Ni-Substituted AsW9O34 Clusters Functionalized by Organic Ligands",

abstract = "Hydrothermal reactions of trilacunary precursor A-α-AsW9O34 9- polyoxoanions and nickel ions in the presence of ethylenediamine (en = ethylenediamine) led to two new hexa-Ni-substituted Keggin-type tungstoarsenates [Ni6(μ 3-OH)3(en)3(H2O)6(B-α-AsW9O34)]·6H2O (1) and [Ni6(μ 3-OH)3(en)3(H2O)6(B-α-AsW9O34)]·10H2O (2), which have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction. Crystal data for 1: hexagonal, R3c, a = b = 20.4379(5) {\AA}, c = 21.5062(6) {\AA}, β = 120o, V = 7779.8 (3) {\AA}3 and Z = 6; for 2: momoclinic, P21/c, a = 13.4200(3) {\AA}, b = 19.1428(5) {\AA}, c = 22.8845(9) {\AA}, β = 112.403(3)o, V = 5435.2(3) {\AA}3 and Z = 4. Structural analyses reveal that the [Ni6(μ 3-OH)3(B-α-AsW9O34)] clusters in 1 and 2 are covalently functionalized by neutral en ligands, in which two similar \{Ni6(μ 3-OH)3(en)3(H2O)6\}9+ cores have been observed by our lab. Notably, 1 and 2 represent the highest number of substituted transition metal ions in all known lacunary Keggin-type polyoxotungstoarsenate monomers.",

keywords = "Hydrothermal synthesis, Lacunary precursor, Organic functionalization, Substituted polyoxotungstoarsenate",

author = "Bin Cai and Zhao, \{Jun Wei\} and Yang, \{Bai Feng\} and Huan He and Yang, \{Guo Yu\}",

year = "2014",

month = jul,

doi = "10.1007/s10876-014-0688-2",

language = "English",

volume = "25",

pages = "1047--1059",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "4",

}

TY - JOUR

T1 - Two Hexa-Ni-Substituted AsW9O34 Clusters Functionalized by Organic Ligands

AU - Cai, Bin

AU - Zhao, Jun Wei

AU - Yang, Bai Feng

AU - He, Huan

AU - Yang, Guo Yu

PY - 2014/7

Y1 - 2014/7

N2 - Hydrothermal reactions of trilacunary precursor A-α-AsW9O34 9- polyoxoanions and nickel ions in the presence of ethylenediamine (en = ethylenediamine) led to two new hexa-Ni-substituted Keggin-type tungstoarsenates [Ni6(μ 3-OH)3(en)3(H2O)6(B-α-AsW9O34)]·6H2O (1) and [Ni6(μ 3-OH)3(en)3(H2O)6(B-α-AsW9O34)]·10H2O (2), which have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction. Crystal data for 1: hexagonal, R3c, a = b = 20.4379(5) Å, c = 21.5062(6) Å, β = 120o, V = 7779.8 (3) Å3 and Z = 6; for 2: momoclinic, P21/c, a = 13.4200(3) Å, b = 19.1428(5) Å, c = 22.8845(9) Å, β = 112.403(3)o, V = 5435.2(3) Å3 and Z = 4. Structural analyses reveal that the [Ni6(μ 3-OH)3(B-α-AsW9O34)] clusters in 1 and 2 are covalently functionalized by neutral en ligands, in which two similar {Ni6(μ 3-OH)3(en)3(H2O)6}9+ cores have been observed by our lab. Notably, 1 and 2 represent the highest number of substituted transition metal ions in all known lacunary Keggin-type polyoxotungstoarsenate monomers.

AB - Hydrothermal reactions of trilacunary precursor A-α-AsW9O34 9- polyoxoanions and nickel ions in the presence of ethylenediamine (en = ethylenediamine) led to two new hexa-Ni-substituted Keggin-type tungstoarsenates [Ni6(μ 3-OH)3(en)3(H2O)6(B-α-AsW9O34)]·6H2O (1) and [Ni6(μ 3-OH)3(en)3(H2O)6(B-α-AsW9O34)]·10H2O (2), which have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction. Crystal data for 1: hexagonal, R3c, a = b = 20.4379(5) Å, c = 21.5062(6) Å, β = 120o, V = 7779.8 (3) Å3 and Z = 6; for 2: momoclinic, P21/c, a = 13.4200(3) Å, b = 19.1428(5) Å, c = 22.8845(9) Å, β = 112.403(3)o, V = 5435.2(3) Å3 and Z = 4. Structural analyses reveal that the [Ni6(μ 3-OH)3(B-α-AsW9O34)] clusters in 1 and 2 are covalently functionalized by neutral en ligands, in which two similar {Ni6(μ 3-OH)3(en)3(H2O)6}9+ cores have been observed by our lab. Notably, 1 and 2 represent the highest number of substituted transition metal ions in all known lacunary Keggin-type polyoxotungstoarsenate monomers.

KW - Hydrothermal synthesis

KW - Lacunary precursor

KW - Organic functionalization

KW - Substituted polyoxotungstoarsenate

UR - https://www.scopus.com/pages/publications/84904179212

U2 - 10.1007/s10876-014-0688-2

DO - 10.1007/s10876-014-0688-2

M3 - Article

AN - SCOPUS:84904179212

SN - 1040-7278

VL - 25

SP - 1047

EP - 1059

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 4

ER -

Two Hexa-Ni-Substituted AsW₉O₃₄ Clusters Functionalized by Organic Ligands

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