Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

Zhengguo Lin; Baokuan Chen; Xiao Feng; Bo Wang; Yingnan Chi; Yanxuan Fan; Xinhang Yang; Xianqiang Huang; Changwen Hu

doi:10.1039/c3ce40773j

Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

Zhengguo Lin, Baokuan Chen, Xiao Feng, Bo Wang^*, Yingnan Chi, Yanxuan Fan, Xinhang Yang, Xianqiang Huang, Changwen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Two new chiral hexanuclear palladium(ii) complexes [Pd₆(Cys) ₄(CysH)₄][Pd₆(CysH)₈]Cl ₄·24H₂O (1) and [Pd₆(HCys) ₁₀](NO₃)₂·11H₂O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(ii) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of l-Cys ligands can be preserved to the multinuclear Pd complexes.

Original language	English
Pages (from-to)	6461-6464
Number of pages	4
Journal	CrystEngComm
Volume	15
Issue number	33
DOIs	https://doi.org/10.1039/c3ce40773j
Publication status	Published - 7 Sept 2013

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abstract = "Two new chiral hexanuclear palladium(ii) complexes [Pd6(Cys) 4(CysH)4][Pd6(CysH)8]Cl 4·24H2O (1) and [Pd6(HCys) 10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(ii) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of l-Cys ligands can be preserved to the multinuclear Pd complexes.",

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T1 - Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

AU - Lin, Zhengguo

AU - Chen, Baokuan

AU - Feng, Xiao

AU - Wang, Bo

AU - Chi, Yingnan

AU - Fan, Yanxuan

AU - Yang, Xinhang

AU - Huang, Xianqiang

AU - Hu, Changwen

PY - 2013/9/7

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N2 - Two new chiral hexanuclear palladium(ii) complexes [Pd6(Cys) 4(CysH)4][Pd6(CysH)8]Cl 4·24H2O (1) and [Pd6(HCys) 10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(ii) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of l-Cys ligands can be preserved to the multinuclear Pd complexes.

AB - Two new chiral hexanuclear palladium(ii) complexes [Pd6(Cys) 4(CysH)4][Pd6(CysH)8]Cl 4·24H2O (1) and [Pd6(HCys) 10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(ii) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of l-Cys ligands can be preserved to the multinuclear Pd complexes.

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Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

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