Two additive-induced isomeric aluminoborates templated by methylamine

Gao Juan Cao; Jian Lin; Jin Yun Wang; Shou Tian Zheng; Wei Hui Fang; Guo Yu Yang

doi:10.1039/c0dt00303d

Two additive-induced isomeric aluminoborates templated by methylamine

Gao Juan Cao, Jian Lin, Jin Yun Wang, Shou Tian Zheng, Wei Hui Fang, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

Two additive-induced isomeric aluminoborates, (CH₃NH ₃)₂(H₂O)₂[Al(B₅O ₁₀)] (1) and (CH₃NH₃)(H₂O)[Al(B ₅O₁₀)] (2), have been obtained by using small methylamine molecules as structure directing agents (SDA) under solvothermal conditions and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, single-crystal X-ray diffraction, NLO determination, UV-vis spectral investigation, electronic structure calculation and ion exchange. Different arrangements of B₅O₁₀ units and AlO₄ tetrahedra results in two different structures with two pairs of helical channels along [100] and [010] directions, respectively. Interestingly, the two frameworks with noncentrosymmetric and chiral space groups separately exhibit the same diamond topologies and display good second harmonic generation efficiencies of about 2.0 times the value of KDP.

Original language	English
Pages (from-to)	8631-8636
Number of pages	6
Journal	Dalton Transactions
Volume	39
Issue number	37
DOIs	https://doi.org/10.1039/c0dt00303d
Publication status	Published - 7 Oct 2010

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title = "Two additive-induced isomeric aluminoborates templated by methylamine",

abstract = "Two additive-induced isomeric aluminoborates, (CH3NH 3)2(H2O)2[Al(B5O 10)] (1) and (CH3NH3)(H2O)[Al(B 5O10)] (2), have been obtained by using small methylamine molecules as structure directing agents (SDA) under solvothermal conditions and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, single-crystal X-ray diffraction, NLO determination, UV-vis spectral investigation, electronic structure calculation and ion exchange. Different arrangements of B5O10 units and AlO4 tetrahedra results in two different structures with two pairs of helical channels along [100] and [010] directions, respectively. Interestingly, the two frameworks with noncentrosymmetric and chiral space groups separately exhibit the same diamond topologies and display good second harmonic generation efficiencies of about 2.0 times the value of KDP.",

author = "Cao, {Gao Juan} and Jian Lin and Wang, {Jin Yun} and Zheng, {Shou Tian} and Fang, {Wei Hui} and Yang, {Guo Yu}",

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doi = "10.1039/c0dt00303d",

language = "English",

volume = "39",

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journal = "Dalton Transactions",

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TY - JOUR

T1 - Two additive-induced isomeric aluminoborates templated by methylamine

AU - Cao, Gao Juan

AU - Lin, Jian

AU - Wang, Jin Yun

AU - Zheng, Shou Tian

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2010/10/7

Y1 - 2010/10/7

N2 - Two additive-induced isomeric aluminoborates, (CH3NH 3)2(H2O)2[Al(B5O 10)] (1) and (CH3NH3)(H2O)[Al(B 5O10)] (2), have been obtained by using small methylamine molecules as structure directing agents (SDA) under solvothermal conditions and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, single-crystal X-ray diffraction, NLO determination, UV-vis spectral investigation, electronic structure calculation and ion exchange. Different arrangements of B5O10 units and AlO4 tetrahedra results in two different structures with two pairs of helical channels along [100] and [010] directions, respectively. Interestingly, the two frameworks with noncentrosymmetric and chiral space groups separately exhibit the same diamond topologies and display good second harmonic generation efficiencies of about 2.0 times the value of KDP.

AB - Two additive-induced isomeric aluminoborates, (CH3NH 3)2(H2O)2[Al(B5O 10)] (1) and (CH3NH3)(H2O)[Al(B 5O10)] (2), have been obtained by using small methylamine molecules as structure directing agents (SDA) under solvothermal conditions and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, single-crystal X-ray diffraction, NLO determination, UV-vis spectral investigation, electronic structure calculation and ion exchange. Different arrangements of B5O10 units and AlO4 tetrahedra results in two different structures with two pairs of helical channels along [100] and [010] directions, respectively. Interestingly, the two frameworks with noncentrosymmetric and chiral space groups separately exhibit the same diamond topologies and display good second harmonic generation efficiencies of about 2.0 times the value of KDP.

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U2 - 10.1039/c0dt00303d

DO - 10.1039/c0dt00303d

M3 - Article

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VL - 39

SP - 8631

EP - 8636

JO - Dalton Transactions

JF - Dalton Transactions

IS - 37

ER -

Two additive-induced isomeric aluminoborates templated by methylamine

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