Tuning the wavelength of electrochemiluminescence by anodic potential: A design using non-Kekulé-structured iridium-ruthenium luminophores

Michael Schmittel; Qinghai Shu; Mehmet Emin Cinar

doi:10.1039/c2dt30303e

Tuning the wavelength of electrochemiluminescence by anodic potential: A design using non-Kekulé-structured iridium-ruthenium luminophores

Michael Schmittel^*
, Qinghai Shu
, Mehmet Emin Cinar

^*Corresponding author for this work

University of Siegen

Research output: Contribution to journal › Article › peer-review

47 Citations (Scopus)

Abstract

Setting up spatially separated HOMO and LUMO regions in a non-Kekulé structured trinuclear Ir(iii)-Ru(ii)-Ir(iii) system and using oxidative-reduction electrochemiluminescence leads to emissions that are not detected in photoluminescence. Moreover, the new design allows tuning of the wavelength of emission in a stepless fashion as a function of the selected potential range.

Original language	English
Pages (from-to)	6064-6068
Number of pages	5
Journal	Dalton Transactions
Volume	41
Issue number	20
DOIs	https://doi.org/10.1039/c2dt30303e
Publication status	Published - 28 May 2012
Externally published	Yes

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abstract = "Setting up spatially separated HOMO and LUMO regions in a non-Kekul{\'e} structured trinuclear Ir(iii)-Ru(ii)-Ir(iii) system and using oxidative-reduction electrochemiluminescence leads to emissions that are not detected in photoluminescence. Moreover, the new design allows tuning of the wavelength of emission in a stepless fashion as a function of the selected potential range.",

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AU - Cinar, Mehmet Emin

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N2 - Setting up spatially separated HOMO and LUMO regions in a non-Kekulé structured trinuclear Ir(iii)-Ru(ii)-Ir(iii) system and using oxidative-reduction electrochemiluminescence leads to emissions that are not detected in photoluminescence. Moreover, the new design allows tuning of the wavelength of emission in a stepless fashion as a function of the selected potential range.

AB - Setting up spatially separated HOMO and LUMO regions in a non-Kekulé structured trinuclear Ir(iii)-Ru(ii)-Ir(iii) system and using oxidative-reduction electrochemiluminescence leads to emissions that are not detected in photoluminescence. Moreover, the new design allows tuning of the wavelength of emission in a stepless fashion as a function of the selected potential range.

UR - https://www.scopus.com/pages/publications/84860444282

U2 - 10.1039/c2dt30303e

DO - 10.1039/c2dt30303e

M3 - Article

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 20

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Tuning the wavelength of electrochemiluminescence by anodic potential: A design using non-Kekulé-structured iridium-ruthenium luminophores

Abstract

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