Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20-

Kai Yao Wang; Bassem S. Bassil; Zheng Guo Lin; Ali Haider; Jie Cao; Holger Stephan; Katrin Viehweger; Ulrich Kortz

doi:10.1039/c4dt02494j

Ti₇-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti₆(TiO₆)(AsW₉O₃₃)₄]^20-

Kai Yao Wang, Bassem S. Bassil, Zheng Guo Lin, Ali Haider, Jie Cao, Holger Stephan, Katrin Viehweger, Ulrich Kortz^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

We have prepared the Ti₇-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti₆(TiO₆)(AsW₉O₃₃)₄]^20- (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti₇-core, comprising a central TiO₆ octahedron surrounded by six TiO₅ square-pyramids, and capped by four {As^IIIW₉} trilacunary fragments. The title polyanion is solution-stable, as shown by ¹⁸³W NMR and mass spectrometry, and exhibits interesting biological properties.

Original language	English
Pages (from-to)	16143-16146
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	43
DOIs	https://doi.org/10.1039/c4dt02494j
Publication status	Published - 21 Nov 2014
Externally published	Yes

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title = "Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20-",

abstract = "We have prepared the Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20- (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti7-core, comprising a central TiO6 octahedron surrounded by six TiO5 square-pyramids, and capped by four \{AsIIIW9\} trilacunary fragments. The title polyanion is solution-stable, as shown by 183W NMR and mass spectrometry, and exhibits interesting biological properties.",

author = "Wang, \{Kai Yao\} and Bassil, \{Bassem S.\} and Lin, \{Zheng Guo\} and Ali Haider and Jie Cao and Holger Stephan and Katrin Viehweger and Ulrich Kortz",

note = "Publisher Copyright: {\textcopyright} 2014 the Partner Organisations.",

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doi = "10.1039/c4dt02494j",

language = "English",

volume = "43",

pages = "16143--16146",

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T1 - Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20-

AU - Wang, Kai Yao

AU - Bassil, Bassem S.

AU - Lin, Zheng Guo

AU - Haider, Ali

AU - Cao, Jie

AU - Stephan, Holger

AU - Viehweger, Katrin

AU - Kortz, Ulrich

PY - 2014/11/21

Y1 - 2014/11/21

N2 - We have prepared the Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20- (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti7-core, comprising a central TiO6 octahedron surrounded by six TiO5 square-pyramids, and capped by four {AsIIIW9} trilacunary fragments. The title polyanion is solution-stable, as shown by 183W NMR and mass spectrometry, and exhibits interesting biological properties.

AB - We have prepared the Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20- (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti7-core, comprising a central TiO6 octahedron surrounded by six TiO5 square-pyramids, and capped by four {AsIIIW9} trilacunary fragments. The title polyanion is solution-stable, as shown by 183W NMR and mass spectrometry, and exhibits interesting biological properties.

UR - https://www.scopus.com/pages/publications/84908043052

U2 - 10.1039/c4dt02494j

DO - 10.1039/c4dt02494j

M3 - Article

AN - SCOPUS:84908043052

SN - 1477-9226

VL - 43

SP - 16143

EP - 16146

JO - Dalton Transactions

JF - Dalton Transactions

IS - 43

ER -

Ti₇-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti₆(TiO₆)(AsW₉O₃₃)₄]^20-

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