Three new mixed-alkali- and alkaline-earth-metal borates: From 1D chain to 2D layer to 3D framework

Han Qing Wu; Ping Ju; Huan He; Bai Feng Yang; Guo Yu Yang

doi:10.1021/ic4015465

Three new mixed-alkali- and alkaline-earth-metal borates: From 1D chain to 2D layer to 3D framework

Han Qing Wu, Ping Ju, Huan He, Bai Feng Yang, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Three new mixed-metal borates, K₄Ba₂[B ₁₄O₂₀(OH)₁₀]·3H₂O (1), LiSr₂[B₁₀O₁₆(OH)₃] (2), and LiBa[B₉O₁₅] (3), have been made under hydro(solvo)thermal conditions and characterized by means of IR, UV-vis-near-IR, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray diffraction, respectively. 1 is a 1D chain constructed from B₁₄O ₂₁(OH)₁₀^10- cluster units, 2 is of a 2D layer with nine-membered-ring windows built up of B₁₀O₁₉(OH) ₃^9- cluster units, while 3 exhibits a 3D framework with 12-membered-ring channels composed of B₃O₇ cluster units.

Original language	English
Pages (from-to)	10566-10570
Number of pages	5
Journal	Inorganic Chemistry
Volume	52
Issue number	18
DOIs	https://doi.org/10.1021/ic4015465
Publication status	Published - 16 Sept 2013

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title = "Three new mixed-alkali- and alkaline-earth-metal borates: From 1D chain to 2D layer to 3D framework",

abstract = "Three new mixed-metal borates, K4Ba2[B 14O20(OH)10]·3H2O (1), LiSr2[B10O16(OH)3] (2), and LiBa[B9O15] (3), have been made under hydro(solvo)thermal conditions and characterized by means of IR, UV-vis-near-IR, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray diffraction, respectively. 1 is a 1D chain constructed from B14O 21(OH)1010- cluster units, 2 is of a 2D layer with nine-membered-ring windows built up of B10O19(OH) 39- cluster units, while 3 exhibits a 3D framework with 12-membered-ring channels composed of B3O7 cluster units.",

author = "Wu, \{Han Qing\} and Ping Ju and Huan He and Yang, \{Bai Feng\} and Yang, \{Guo Yu\}",

year = "2013",

month = sep,

day = "16",

doi = "10.1021/ic4015465",

language = "English",

volume = "52",

pages = "10566--10570",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Three new mixed-alkali- and alkaline-earth-metal borates

T2 - From 1D chain to 2D layer to 3D framework

AU - Wu, Han Qing

AU - Ju, Ping

AU - He, Huan

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2013/9/16

Y1 - 2013/9/16

N2 - Three new mixed-metal borates, K4Ba2[B 14O20(OH)10]·3H2O (1), LiSr2[B10O16(OH)3] (2), and LiBa[B9O15] (3), have been made under hydro(solvo)thermal conditions and characterized by means of IR, UV-vis-near-IR, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray diffraction, respectively. 1 is a 1D chain constructed from B14O 21(OH)1010- cluster units, 2 is of a 2D layer with nine-membered-ring windows built up of B10O19(OH) 39- cluster units, while 3 exhibits a 3D framework with 12-membered-ring channels composed of B3O7 cluster units.

AB - Three new mixed-metal borates, K4Ba2[B 14O20(OH)10]·3H2O (1), LiSr2[B10O16(OH)3] (2), and LiBa[B9O15] (3), have been made under hydro(solvo)thermal conditions and characterized by means of IR, UV-vis-near-IR, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray diffraction, respectively. 1 is a 1D chain constructed from B14O 21(OH)1010- cluster units, 2 is of a 2D layer with nine-membered-ring windows built up of B10O19(OH) 39- cluster units, while 3 exhibits a 3D framework with 12-membered-ring channels composed of B3O7 cluster units.

UR - https://www.scopus.com/pages/publications/84884267841

U2 - 10.1021/ic4015465

DO - 10.1021/ic4015465

M3 - Article

AN - SCOPUS:84884267841

SN - 0020-1669

VL - 52

SP - 10566

EP - 10570

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 18

ER -

Three new mixed-alkali- and alkaline-earth-metal borates: From 1D chain to 2D layer to 3D framework

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