Three complexes based on ligands 1-hydroxybenzotriazole and 1,4-benzenedicarboxylic acid: Synthesis, structures and luminescence properties

Zhong Qiang Zhang; Ru Dan Huang; Yan Qing Xu; Li Qiong Yu; Zhi Wei Jiao; Qin Lei Zhu; Chang Wen Hu

doi:10.1016/j.ica.2009.09.031

Three complexes based on ligands 1-hydroxybenzotriazole and 1,4-benzenedicarboxylic acid: Synthesis, structures and luminescence properties

Zhong Qiang Zhang
, Ru Dan Huang^*
, Yan Qing Xu
, Li Qiong Yu
, Zhi Wei Jiao
, Qin Lei Zhu
, Chang Wen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Three new complexes, [Mn(OBt)₂(H₂O)₄]·3H₂O (1) (OBt = 1-hydroxybenzotriazole ion), [Zn₂(OBt)₂(BDC)(H₂O)·H₂O]_n (2) (H₂BDC = 1,4-benzenedicarboxylic acid), and [Cu₃(OBt)₂(BDC)(μ₃-OH)₂(H₂O)₂·2H₂O]_n (3) were synthesized by hydrothermal method and were characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1, 2 and 3 are zero-dimensional (0D), two-dimensional (2D) and two-dimensional (2D) frameworks, respectively. In particular, there are all two crystallographically unique metal ions in the structures of complexes 2 and 3. Complex 2 possesses two helical chains in its structure. In the structure of 3, the chains that are built from tri-copper clusters and μ₃-O atoms are connected with BDC^2- to construct 2D grid structure. The luminescence properties of the three complexes were investigated.

Original language	English
Pages (from-to)	5183-5189
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	362
Issue number	15
DOIs	https://doi.org/10.1016/j.ica.2009.09.031
Publication status	Published - 1 Dec 2009

Keywords

1,4-Benzenedicarboxylic acid
1-Hydroxybenzotriazole
Chemical synthesis
Crystal structure
Luminescence properties

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10.1016/j.ica.2009.09.031

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title = "Three complexes based on ligands 1-hydroxybenzotriazole and 1,4-benzenedicarboxylic acid: Synthesis, structures and luminescence properties",

abstract = "Three new complexes, [Mn(OBt)2(H2O)4]·3H2O (1) (OBt = 1-hydroxybenzotriazole ion), [Zn2(OBt)2(BDC)(H2O)·H2O]n (2) (H2BDC = 1,4-benzenedicarboxylic acid), and [Cu3(OBt)2(BDC)(μ3-OH)2(H2O)2·2H2O]n (3) were synthesized by hydrothermal method and were characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1, 2 and 3 are zero-dimensional (0D), two-dimensional (2D) and two-dimensional (2D) frameworks, respectively. In particular, there are all two crystallographically unique metal ions in the structures of complexes 2 and 3. Complex 2 possesses two helical chains in its structure. In the structure of 3, the chains that are built from tri-copper clusters and μ3-O atoms are connected with BDC2- to construct 2D grid structure. The luminescence properties of the three complexes were investigated.",

keywords = "1,4-Benzenedicarboxylic acid, 1-Hydroxybenzotriazole, Chemical synthesis, Crystal structure, Luminescence properties",

author = "Zhang, \{Zhong Qiang\} and Huang, \{Ru Dan\} and Xu, \{Yan Qing\} and Yu, \{Li Qiong\} and Jiao, \{Zhi Wei\} and Zhu, \{Qin Lei\} and Hu, \{Chang Wen\}",

year = "2009",

month = dec,

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doi = "10.1016/j.ica.2009.09.031",

language = "English",

volume = "362",

pages = "5183--5189",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Three complexes based on ligands 1-hydroxybenzotriazole and 1,4-benzenedicarboxylic acid

T2 - Synthesis, structures and luminescence properties

AU - Zhang, Zhong Qiang

AU - Huang, Ru Dan

AU - Xu, Yan Qing

AU - Yu, Li Qiong

AU - Jiao, Zhi Wei

AU - Zhu, Qin Lei

AU - Hu, Chang Wen

PY - 2009/12/1

Y1 - 2009/12/1

N2 - Three new complexes, [Mn(OBt)2(H2O)4]·3H2O (1) (OBt = 1-hydroxybenzotriazole ion), [Zn2(OBt)2(BDC)(H2O)·H2O]n (2) (H2BDC = 1,4-benzenedicarboxylic acid), and [Cu3(OBt)2(BDC)(μ3-OH)2(H2O)2·2H2O]n (3) were synthesized by hydrothermal method and were characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1, 2 and 3 are zero-dimensional (0D), two-dimensional (2D) and two-dimensional (2D) frameworks, respectively. In particular, there are all two crystallographically unique metal ions in the structures of complexes 2 and 3. Complex 2 possesses two helical chains in its structure. In the structure of 3, the chains that are built from tri-copper clusters and μ3-O atoms are connected with BDC2- to construct 2D grid structure. The luminescence properties of the three complexes were investigated.

AB - Three new complexes, [Mn(OBt)2(H2O)4]·3H2O (1) (OBt = 1-hydroxybenzotriazole ion), [Zn2(OBt)2(BDC)(H2O)·H2O]n (2) (H2BDC = 1,4-benzenedicarboxylic acid), and [Cu3(OBt)2(BDC)(μ3-OH)2(H2O)2·2H2O]n (3) were synthesized by hydrothermal method and were characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1, 2 and 3 are zero-dimensional (0D), two-dimensional (2D) and two-dimensional (2D) frameworks, respectively. In particular, there are all two crystallographically unique metal ions in the structures of complexes 2 and 3. Complex 2 possesses two helical chains in its structure. In the structure of 3, the chains that are built from tri-copper clusters and μ3-O atoms are connected with BDC2- to construct 2D grid structure. The luminescence properties of the three complexes were investigated.

KW - 1,4-Benzenedicarboxylic acid

KW - 1-Hydroxybenzotriazole

KW - Chemical synthesis

KW - Crystal structure

KW - Luminescence properties

UR - https://www.scopus.com/pages/publications/71749118742

U2 - 10.1016/j.ica.2009.09.031

DO - 10.1016/j.ica.2009.09.031

M3 - Article

AN - SCOPUS:71749118742

SN - 0020-1693

VL - 362

SP - 5183

EP - 5189

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 15

ER -

Three complexes based on ligands 1-hydroxybenzotriazole and 1,4-benzenedicarboxylic acid: Synthesis, structures and luminescence properties

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