Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydrogenation in an aqueous/organic biphasic system

Kaoxue Li; Yanhua Wang; Jingyang Jiang; Zilin Jin

doi:10.1016/j.catcom.2009.12.015

Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydrogenation in an aqueous/organic biphasic system

Kaoxue Li, Yanhua Wang^*, Jingyang Jiang, Zilin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

A simple, effective and reversible aqueous/organic phase-transfer method for rhodium nanoparticles was developed on the basis of the cloud point (Cp) of thermoregulated ligand. The rhodium nanoparticles stabilized by thermoregulated ligand Ph₂P(CH₂CH₂O)_nCH₃ (n = 16) could transfer from aqueous phase to 1-butanol phase and vice versa by means of changing temperature. This thermoregulated phase-transfer rhodium nanoparticle catalyst evaluated in the hydrogenation of olefins in an aqueous/1-butanol biphasic system exhibited high activity and stability.

Original language	English
Pages (from-to)	542-546
Number of pages	5
Journal	Catalysis Communications
Volume	11
Issue number	6
DOIs	https://doi.org/10.1016/j.catcom.2009.12.015
Publication status	Published - 20 Feb 2010
Externally published	Yes

Keywords

Aqueous/organic biphasic catalysis
Hydrogenation
Olefin
Rhodium nanoparticles
Thermoregulated ligand

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10.1016/j.catcom.2009.12.015

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title = "Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydrogenation in an aqueous/organic biphasic system",

abstract = "A simple, effective and reversible aqueous/organic phase-transfer method for rhodium nanoparticles was developed on the basis of the cloud point (Cp) of thermoregulated ligand. The rhodium nanoparticles stabilized by thermoregulated ligand Ph2P(CH2CH2O)nCH3 (n = 16) could transfer from aqueous phase to 1-butanol phase and vice versa by means of changing temperature. This thermoregulated phase-transfer rhodium nanoparticle catalyst evaluated in the hydrogenation of olefins in an aqueous/1-butanol biphasic system exhibited high activity and stability.",

keywords = "Aqueous/organic biphasic catalysis, Hydrogenation, Olefin, Rhodium nanoparticles, Thermoregulated ligand",

author = "Kaoxue Li and Yanhua Wang and Jingyang Jiang and Zilin Jin",

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doi = "10.1016/j.catcom.2009.12.015",

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T1 - Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydrogenation in an aqueous/organic biphasic system

AU - Li, Kaoxue

AU - Wang, Yanhua

AU - Jiang, Jingyang

AU - Jin, Zilin

PY - 2010/2/20

Y1 - 2010/2/20

N2 - A simple, effective and reversible aqueous/organic phase-transfer method for rhodium nanoparticles was developed on the basis of the cloud point (Cp) of thermoregulated ligand. The rhodium nanoparticles stabilized by thermoregulated ligand Ph2P(CH2CH2O)nCH3 (n = 16) could transfer from aqueous phase to 1-butanol phase and vice versa by means of changing temperature. This thermoregulated phase-transfer rhodium nanoparticle catalyst evaluated in the hydrogenation of olefins in an aqueous/1-butanol biphasic system exhibited high activity and stability.

AB - A simple, effective and reversible aqueous/organic phase-transfer method for rhodium nanoparticles was developed on the basis of the cloud point (Cp) of thermoregulated ligand. The rhodium nanoparticles stabilized by thermoregulated ligand Ph2P(CH2CH2O)nCH3 (n = 16) could transfer from aqueous phase to 1-butanol phase and vice versa by means of changing temperature. This thermoregulated phase-transfer rhodium nanoparticle catalyst evaluated in the hydrogenation of olefins in an aqueous/1-butanol biphasic system exhibited high activity and stability.

KW - Aqueous/organic biphasic catalysis

KW - Hydrogenation

KW - Olefin

KW - Rhodium nanoparticles

KW - Thermoregulated ligand

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DO - 10.1016/j.catcom.2009.12.015

M3 - Article

AN - SCOPUS:74849138023

SN - 1566-7367

VL - 11

SP - 542

EP - 546

JO - Catalysis Communications

JF - Catalysis Communications

IS - 6

ER -

Thermoregulated phase-transfer rhodium nanoparticle catalyst for hydrogenation in an aqueous/organic biphasic system

Abstract

Keywords

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