Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene

Zhijun Chen; Yanhua Wang; Wenjiang Li; Jingyang Jiang; Zilin Jin

doi:10.1016/S1872-2067(14)60216-3

Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene

Zhijun Chen
, Yanhua Wang^*
, Wenjiang Li
, Jingyang Jiang
, Zilin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The use of a thermoregulated phase-transfer Rh nanoparticle catalyst for the selective hydrogenation of ortho-chloronitrobenzene (o-CNB) to ortho-chloroaniline (o-CAN) in an aqueous/1-pentanol biphasic system was studied. Under the optimized reaction conditions, the conversion of o-CNB and the selectivity for o-CAN were 100% and 98%, respectively. The catalyst was easily separated from the product by phase separation and reused eight times without evident loss of activity and selectivity.

Original language	English
Pages (from-to)	1917-1920
Number of pages	4
Journal	Cuihua Xuebao/Chinese Journal of Catalysis
Volume	35
Issue number	12
DOIs	https://doi.org/10.1016/S1872-2067(14)60216-3
Publication status	Published - 20 Nov 2014
Externally published	Yes

Keywords

Aqueous/1-pentanol biphasic system
Ortho-chloronitrobenzene
Rhodium nanoparticle
Selective hydrogenation
Thermoregulated ligand

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10.1016/S1872-2067(14)60216-3

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title = "Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene",

abstract = "The use of a thermoregulated phase-transfer Rh nanoparticle catalyst for the selective hydrogenation of ortho-chloronitrobenzene (o-CNB) to ortho-chloroaniline (o-CAN) in an aqueous/1-pentanol biphasic system was studied. Under the optimized reaction conditions, the conversion of o-CNB and the selectivity for o-CAN were 100\% and 98\%, respectively. The catalyst was easily separated from the product by phase separation and reused eight times without evident loss of activity and selectivity.",

keywords = "Aqueous/1-pentanol biphasic system, Ortho-chloronitrobenzene, Rhodium nanoparticle, Selective hydrogenation, Thermoregulated ligand",

author = "Zhijun Chen and Yanhua Wang and Wenjiang Li and Jingyang Jiang and Zilin Jin",

note = "Publisher Copyright: {\textcopyright}, 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. Published by Elsevier B.V. All rights reserved.",

year = "2014",

month = nov,

day = "20",

doi = "10.1016/S1872-2067(14)60216-3",

language = "English",

volume = "35",

pages = "1917--1920",

journal = "Cuihua Xuebao/Chinese Journal of Catalysis",

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TY - JOUR

T1 - Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene

AU - Chen, Zhijun

AU - Wang, Yanhua

AU - Li, Wenjiang

AU - Jiang, Jingyang

AU - Jin, Zilin

PY - 2014/11/20

Y1 - 2014/11/20

N2 - The use of a thermoregulated phase-transfer Rh nanoparticle catalyst for the selective hydrogenation of ortho-chloronitrobenzene (o-CNB) to ortho-chloroaniline (o-CAN) in an aqueous/1-pentanol biphasic system was studied. Under the optimized reaction conditions, the conversion of o-CNB and the selectivity for o-CAN were 100% and 98%, respectively. The catalyst was easily separated from the product by phase separation and reused eight times without evident loss of activity and selectivity.

AB - The use of a thermoregulated phase-transfer Rh nanoparticle catalyst for the selective hydrogenation of ortho-chloronitrobenzene (o-CNB) to ortho-chloroaniline (o-CAN) in an aqueous/1-pentanol biphasic system was studied. Under the optimized reaction conditions, the conversion of o-CNB and the selectivity for o-CAN were 100% and 98%, respectively. The catalyst was easily separated from the product by phase separation and reused eight times without evident loss of activity and selectivity.

KW - Aqueous/1-pentanol biphasic system

KW - Ortho-chloronitrobenzene

KW - Rhodium nanoparticle

KW - Selective hydrogenation

KW - Thermoregulated ligand

UR - https://www.scopus.com/pages/publications/84919470408

U2 - 10.1016/S1872-2067(14)60216-3

DO - 10.1016/S1872-2067(14)60216-3

M3 - Article

AN - SCOPUS:84919470408

SN - 0253-9837

VL - 35

SP - 1917

EP - 1920

JO - Cuihua Xuebao/Chinese Journal of Catalysis

JF - Cuihua Xuebao/Chinese Journal of Catalysis

IS - 12

ER -

Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene

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