Thermoregulated Phase-Transfer Pd Nanocatalyst for Selective Hydrogenation of 1,5-Cyclooctadiene at Atmospheric Hydrogen Pressure

Zhaohui Zhao; Yanhua Wang

doi:10.1007/s10562-020-03174-3

Thermoregulated Phase-Transfer Pd Nanocatalyst for Selective Hydrogenation of 1,5-Cyclooctadiene at Atmospheric Hydrogen Pressure

Zhaohui Zhao, Yanhua Wang^*

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Abstract: Thermoregulated phase-transfer Pd nanocatalyst was firstly employed in the selective hydrogenation of 1,5-cyclooctadiene (1,5-COD) at atmospheric hydrogen pressure. Under the optimal conditions, > 99% conversion and 95% selectivity to cyclooctene (COE) were obtained. The Pd nanocatalyst can be easily separated from products and directly reused. The turnover frequency (TOF) of 1411 h⁻¹ is the highest value ever reported among Pd nanocatalysts at atmospheric hydrogen pressure. Graphic Abstract: [Figure not available: see fulltext.].

Original language	English
Pages (from-to)	2703-2708
Number of pages	6
Journal	Catalysis Letters
Volume	150
Issue number	9
DOIs	https://doi.org/10.1007/s10562-020-03174-3
Publication status	Published - 1 Sept 2020
Externally published	Yes

Keywords

1,5-COD
Atmospheric hydrogen pressure
Pd nanocatalyst
Selective hydrogenation
Thermoregulated phase-transfer catalysis

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10.1007/s10562-020-03174-3

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title = "Thermoregulated Phase-Transfer Pd Nanocatalyst for Selective Hydrogenation of 1,5-Cyclooctadiene at Atmospheric Hydrogen Pressure",

abstract = "Abstract: Thermoregulated phase-transfer Pd nanocatalyst was firstly employed in the selective hydrogenation of 1,5-cyclooctadiene (1,5-COD) at atmospheric hydrogen pressure. Under the optimal conditions, > 99% conversion and 95% selectivity to cyclooctene (COE) were obtained. The Pd nanocatalyst can be easily separated from products and directly reused. The turnover frequency (TOF) of 1411 h−1 is the highest value ever reported among Pd nanocatalysts at atmospheric hydrogen pressure. Graphic Abstract: [Figure not available: see fulltext.].",

keywords = "1,5-COD, Atmospheric hydrogen pressure, Pd nanocatalyst, Selective hydrogenation, Thermoregulated phase-transfer catalysis",

author = "Zhaohui Zhao and Yanhua Wang",

note = "Publisher Copyright: {\textcopyright} 2020, Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2020",

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doi = "10.1007/s10562-020-03174-3",

language = "English",

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TY - JOUR

T1 - Thermoregulated Phase-Transfer Pd Nanocatalyst for Selective Hydrogenation of 1,5-Cyclooctadiene at Atmospheric Hydrogen Pressure

AU - Zhao, Zhaohui

AU - Wang, Yanhua

PY - 2020/9/1

Y1 - 2020/9/1

N2 - Abstract: Thermoregulated phase-transfer Pd nanocatalyst was firstly employed in the selective hydrogenation of 1,5-cyclooctadiene (1,5-COD) at atmospheric hydrogen pressure. Under the optimal conditions, > 99% conversion and 95% selectivity to cyclooctene (COE) were obtained. The Pd nanocatalyst can be easily separated from products and directly reused. The turnover frequency (TOF) of 1411 h−1 is the highest value ever reported among Pd nanocatalysts at atmospheric hydrogen pressure. Graphic Abstract: [Figure not available: see fulltext.].

AB - Abstract: Thermoregulated phase-transfer Pd nanocatalyst was firstly employed in the selective hydrogenation of 1,5-cyclooctadiene (1,5-COD) at atmospheric hydrogen pressure. Under the optimal conditions, > 99% conversion and 95% selectivity to cyclooctene (COE) were obtained. The Pd nanocatalyst can be easily separated from products and directly reused. The turnover frequency (TOF) of 1411 h−1 is the highest value ever reported among Pd nanocatalysts at atmospheric hydrogen pressure. Graphic Abstract: [Figure not available: see fulltext.].

KW - 1,5-COD

KW - Atmospheric hydrogen pressure

KW - Pd nanocatalyst

KW - Selective hydrogenation

KW - Thermoregulated phase-transfer catalysis

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U2 - 10.1007/s10562-020-03174-3

DO - 10.1007/s10562-020-03174-3

M3 - Article

AN - SCOPUS:85082740219

SN - 1011-372X

VL - 150

SP - 2703

EP - 2708

JO - Catalysis Letters

JF - Catalysis Letters

IS - 9

ER -

Thermoregulated Phase-Transfer Pd Nanocatalyst for Selective Hydrogenation of 1,5-Cyclooctadiene at Atmospheric Hydrogen Pressure

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