Thermoregulated phase transfer ligand and its catalysis: IV. Study of styrene biphase hydroformylation catalyzed by ethoxylated tri-(-p-hydroxyphenyl-)-phosphine rhodium complex

Yanhua Wang; Jingyang Jiang; Fei He; Zilin Jin

Thermoregulated phase transfer ligand and its catalysis: IV. Study of styrene biphase hydroformylation catalyzed by ethoxylated tri-(-p-hydroxyphenyl-)-phosphine rhodium complex

Yanhua Wang^*
, Jingyang Jiang
, Fei He
, Zilin Jin

^*Corresponding author for this work

Dalian University of Technology
Tianjin University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Nonionic water-soluble phosphine rhodium complex was prepared in situ by the reaction of P-(-OCH₂CH₂)OH]₃ (TPPP) with RhCl₃ · 3H₂O. The catalytic activity and selectivity of TPPP/RhCl₃ · 3H₂O for styrene hydroformylation are studied in biphase catalytic system. In addition, effect of reaction temperature, pressure, organic solvent and V (water) /V (styrene) was investigated. The results showed that the reaction took place mainly in the organic phase at higher temperature (90°C). Under the condition of 90°C and 6. 0 MPa the reaction was carried out in toluene for 3. 5 h, the conversion of styrene is 98. 0% , aldehyde yield is 94. 4%, iso I normal molar ratio of aldehyde is 1. 4.

Original language	English
Pages (from-to)	335-337
Number of pages	3
Journal	Chinese Journal of Catalysis
Volume	18
Issue number	4
Publication status	Published - 1997
Externally published	Yes

Keywords

Hydroformylation
Phase transfer catalysis
Phosphine rhodium complex
Styrene

Cite this

@article{8d5cfb2f9e8047559322fab80071224f,

title = "Thermoregulated phase transfer ligand and its catalysis: IV. Study of styrene biphase hydroformylation catalyzed by ethoxylated tri-(-p-hydroxyphenyl-)-phosphine rhodium complex",

abstract = "Nonionic water-soluble phosphine rhodium complex was prepared in situ by the reaction of P-(-OCH2CH2)OH]3 (TPPP) with RhCl3 · 3H2O. The catalytic activity and selectivity of TPPP/RhCl3 · 3H2O for styrene hydroformylation are studied in biphase catalytic system. In addition, effect of reaction temperature, pressure, organic solvent and V (water) /V (styrene) was investigated. The results showed that the reaction took place mainly in the organic phase at higher temperature (90°C). Under the condition of 90°C and 6. 0 MPa the reaction was carried out in toluene for 3. 5 h, the conversion of styrene is 98. 0\% , aldehyde yield is 94. 4\%, iso I normal molar ratio of aldehyde is 1. 4.",

keywords = "Hydroformylation, Phase transfer catalysis, Phosphine rhodium complex, Styrene",

author = "Yanhua Wang and Jingyang Jiang and Fei He and Zilin Jin",

year = "1997",

language = "English",

volume = "18",

pages = "335--337",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

publisher = "Science Press",

number = "4",

}

TY - JOUR

T1 - Thermoregulated phase transfer ligand and its catalysis

T2 - IV. Study of styrene biphase hydroformylation catalyzed by ethoxylated tri-(-p-hydroxyphenyl-)-phosphine rhodium complex

AU - Wang, Yanhua

AU - Jiang, Jingyang

AU - He, Fei

AU - Jin, Zilin

PY - 1997

Y1 - 1997

N2 - Nonionic water-soluble phosphine rhodium complex was prepared in situ by the reaction of P-(-OCH2CH2)OH]3 (TPPP) with RhCl3 · 3H2O. The catalytic activity and selectivity of TPPP/RhCl3 · 3H2O for styrene hydroformylation are studied in biphase catalytic system. In addition, effect of reaction temperature, pressure, organic solvent and V (water) /V (styrene) was investigated. The results showed that the reaction took place mainly in the organic phase at higher temperature (90°C). Under the condition of 90°C and 6. 0 MPa the reaction was carried out in toluene for 3. 5 h, the conversion of styrene is 98. 0% , aldehyde yield is 94. 4%, iso I normal molar ratio of aldehyde is 1. 4.

AB - Nonionic water-soluble phosphine rhodium complex was prepared in situ by the reaction of P-(-OCH2CH2)OH]3 (TPPP) with RhCl3 · 3H2O. The catalytic activity and selectivity of TPPP/RhCl3 · 3H2O for styrene hydroformylation are studied in biphase catalytic system. In addition, effect of reaction temperature, pressure, organic solvent and V (water) /V (styrene) was investigated. The results showed that the reaction took place mainly in the organic phase at higher temperature (90°C). Under the condition of 90°C and 6. 0 MPa the reaction was carried out in toluene for 3. 5 h, the conversion of styrene is 98. 0% , aldehyde yield is 94. 4%, iso I normal molar ratio of aldehyde is 1. 4.

KW - Hydroformylation

KW - Phase transfer catalysis

KW - Phosphine rhodium complex

KW - Styrene

UR - https://www.scopus.com/pages/publications/0343161424

M3 - Article

AN - SCOPUS:0343161424

SN - 1872-2067

VL - 18

SP - 335

EP - 337

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 4

ER -

Thermoregulated phase transfer ligand and its catalysis: IV. Study of styrene biphase hydroformylation catalyzed by ethoxylated tri-(-p-hydroxyphenyl-)-phosphine rhodium complex

Abstract

Keywords

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