Thermal Stability and Adiabatic Kinetics of Four Explosives

Changgen Feng; Li Liu; Xinming Qian; Huaqiao Zhu

Thermal Stability and Adiabatic Kinetics of Four Explosives

Changgen Feng^*
, Li Liu
, Xinming Qian
, Huaqiao Zhu

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to conference › Paper › peer-review

2 Citations (Scopus)

Abstract

Four kinds of explosives, RDX, HMX, TATB and ε-CL-20, are studied by using Accelerating Rate Calorimeter (ARC). Their exothermic behaviors are described. The mechanisms of the thermal decomposition are discussed briefly and their kinetic parameters are determined in the present paper. The values of the activation energies of RDX, HMX, TATB and ε-CL-20 are 267.40, 368.66, 387.76 and 592.96 kJ · mol^-1 respectively, and their equations of compensation effect are respectively ln A = 0.2741E - 7.7087, ln A = 0.2414E - 7.1786, ln A = 0.2063E - 9.7128 and ln A = 0.2497E - 6.7068.

Original language	English
Pages	177-182
Number of pages	6
Publication status	Published - 2003
Event	Proceedings of the 2003 International Autumn Seminar on Propellants, Explosives and Pyrotechnics (2003 IASPEP) - Theory and Practice of Energetic Materials - Guilin, China Duration: 15 Oct 2003 → 18 Oct 2003

Conference

Conference	Proceedings of the 2003 International Autumn Seminar on Propellants, Explosives and Pyrotechnics (2003 IASPEP) - Theory and Practice of Energetic Materials
Country/Territory	China
City	Guilin
Period	15/10/03 → 18/10/03

Keywords

ARC
Explosive
Kinetics
Thermal decomposition

Cite this

@conference{a0314f5ee0704e77ab0f3cdf9a990745,

title = "Thermal Stability and Adiabatic Kinetics of Four Explosives",

abstract = "Four kinds of explosives, RDX, HMX, TATB and ε-CL-20, are studied by using Accelerating Rate Calorimeter (ARC). Their exothermic behaviors are described. The mechanisms of the thermal decomposition are discussed briefly and their kinetic parameters are determined in the present paper. The values of the activation energies of RDX, HMX, TATB and ε-CL-20 are 267.40, 368.66, 387.76 and 592.96 kJ · mol-1 respectively, and their equations of compensation effect are respectively ln A = 0.2741E - 7.7087, ln A = 0.2414E - 7.1786, ln A = 0.2063E - 9.7128 and ln A = 0.2497E - 6.7068.",

keywords = "ARC, Explosive, Kinetics, Thermal decomposition",

author = "Changgen Feng and Li Liu and Xinming Qian and Huaqiao Zhu",

year = "2003",

language = "English",

pages = "177--182",

note = "Proceedings of the 2003 International Autumn Seminar on Propellants, Explosives and Pyrotechnics (2003 IASPEP) - Theory and Practice of Energetic Materials ; Conference date: 15-10-2003 Through 18-10-2003",

}

Thermal Stability and Adiabatic Kinetics of Four Explosives. / Feng, Changgen; Liu, Li; Qian, Xinming et al.
2003. 177-182 Paper presented at Proceedings of the 2003 International Autumn Seminar on Propellants, Explosives and Pyrotechnics (2003 IASPEP) - Theory and Practice of Energetic Materials, Guilin, China.

Research output: Contribution to conference › Paper › peer-review

TY - CONF

T1 - Thermal Stability and Adiabatic Kinetics of Four Explosives

AU - Feng, Changgen

AU - Liu, Li

AU - Qian, Xinming

AU - Zhu, Huaqiao

PY - 2003

Y1 - 2003

N2 - Four kinds of explosives, RDX, HMX, TATB and ε-CL-20, are studied by using Accelerating Rate Calorimeter (ARC). Their exothermic behaviors are described. The mechanisms of the thermal decomposition are discussed briefly and their kinetic parameters are determined in the present paper. The values of the activation energies of RDX, HMX, TATB and ε-CL-20 are 267.40, 368.66, 387.76 and 592.96 kJ · mol-1 respectively, and their equations of compensation effect are respectively ln A = 0.2741E - 7.7087, ln A = 0.2414E - 7.1786, ln A = 0.2063E - 9.7128 and ln A = 0.2497E - 6.7068.

AB - Four kinds of explosives, RDX, HMX, TATB and ε-CL-20, are studied by using Accelerating Rate Calorimeter (ARC). Their exothermic behaviors are described. The mechanisms of the thermal decomposition are discussed briefly and their kinetic parameters are determined in the present paper. The values of the activation energies of RDX, HMX, TATB and ε-CL-20 are 267.40, 368.66, 387.76 and 592.96 kJ · mol-1 respectively, and their equations of compensation effect are respectively ln A = 0.2741E - 7.7087, ln A = 0.2414E - 7.1786, ln A = 0.2063E - 9.7128 and ln A = 0.2497E - 6.7068.

KW - ARC

KW - Explosive

KW - Kinetics

KW - Thermal decomposition

UR - https://www.scopus.com/pages/publications/2342535820

M3 - Paper

AN - SCOPUS:2342535820

SP - 177

EP - 182

T2 - Proceedings of the 2003 International Autumn Seminar on Propellants, Explosives and Pyrotechnics (2003 IASPEP) - Theory and Practice of Energetic Materials

Y2 - 15 October 2003 through 18 October 2003

ER -

Thermal Stability and Adiabatic Kinetics of Four Explosives

Abstract

Conference

Keywords

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