Thermal behavior and thermo-kinetic studies of 5,5′-bistetrazole-1,1′-diolate (1,1-BTO)

Chunyuan Zhang; Shaohua Jin; Shusen Chen; Lijie Li; Chang Zhou; Yan Zhang; Qinghai Shu

doi:10.1007/s10973-017-6228-1

Thermal behavior and thermo-kinetic studies of 5,5′-bistetrazole-1,1′-diolate (1,1-BTO)

Chunyuan Zhang
, Shaohua Jin
, Shusen Chen
, Lijie Li
, Chang Zhou
, Yan Zhang
, Qinghai Shu^*

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Thermogravimetric-differential scanning calorimeter and accelerating rate calorimeter (ARC) were performed to study the thermal characteristics and kinetics of energetic 5,5′-bistetrazole-1,1′-diolate (1,1-BTO). The DSC measurements showed one endothermic peak and one exothermic peak with decomposition occurring at 219.1, 227.2, 234.0 and 244.1 °C at different heating rates (2, 4, 8 and 15 °C min⁻¹). The value of critical temperature of thermal explosion (T_b) and kinetics parameters was calculated, suggesting that 1,1-BTO is stable below the temperature of 175.36 °C. The thermal behavior under adiabatic condition was studied by ARC, depicting that onset temperature was 176.61 °C and the thermal decomposition ended at 215.93 °C, within the time span of 49.04 min. In addition, the thermo-kinetic parameters such as the activation energy E_a and pre-exponential factor A under adiabatic condition were also obtained.

Original language	English
Pages (from-to)	1265-1270
Number of pages	6
Journal	Journal of Thermal Analysis and Calorimetry
Volume	129
Issue number	2
DOIs	https://doi.org/10.1007/s10973-017-6228-1
Publication status	Published - 1 Aug 2017

Keywords

5,5′-Bistetrazole-1,1′-diol (BTO)
ARC
Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate (TKX-50)
DSC
Thermal decomposition

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10.1007/s10973-017-6228-1

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title = "Thermal behavior and thermo-kinetic studies of 5,5′-bistetrazole-1,1′-diolate (1,1-BTO)",

abstract = "Thermogravimetric-differential scanning calorimeter and accelerating rate calorimeter (ARC) were performed to study the thermal characteristics and kinetics of energetic 5,5′-bistetrazole-1,1′-diolate (1,1-BTO). The DSC measurements showed one endothermic peak and one exothermic peak with decomposition occurring at 219.1, 227.2, 234.0 and 244.1 °C at different heating rates (2, 4, 8 and 15 °C min−1). The value of critical temperature of thermal explosion (Tb) and kinetics parameters was calculated, suggesting that 1,1-BTO is stable below the temperature of 175.36 °C. The thermal behavior under adiabatic condition was studied by ARC, depicting that onset temperature was 176.61 °C and the thermal decomposition ended at 215.93 °C, within the time span of 49.04 min. In addition, the thermo-kinetic parameters such as the activation energy Ea and pre-exponential factor A under adiabatic condition were also obtained.",

keywords = "5,5′-Bistetrazole-1,1′-diol (BTO), ARC, Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate (TKX-50), DSC, Thermal decomposition",

author = "Chunyuan Zhang and Shaohua Jin and Shusen Chen and Lijie Li and Chang Zhou and Yan Zhang and Qinghai Shu",

note = "Publisher Copyright: {\textcopyright} 2017, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2017",

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doi = "10.1007/s10973-017-6228-1",

language = "English",

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TY - JOUR

T1 - Thermal behavior and thermo-kinetic studies of 5,5′-bistetrazole-1,1′-diolate (1,1-BTO)

AU - Zhang, Chunyuan

AU - Jin, Shaohua

AU - Chen, Shusen

AU - Li, Lijie

AU - Zhou, Chang

AU - Zhang, Yan

AU - Shu, Qinghai

PY - 2017/8/1

Y1 - 2017/8/1

N2 - Thermogravimetric-differential scanning calorimeter and accelerating rate calorimeter (ARC) were performed to study the thermal characteristics and kinetics of energetic 5,5′-bistetrazole-1,1′-diolate (1,1-BTO). The DSC measurements showed one endothermic peak and one exothermic peak with decomposition occurring at 219.1, 227.2, 234.0 and 244.1 °C at different heating rates (2, 4, 8 and 15 °C min−1). The value of critical temperature of thermal explosion (Tb) and kinetics parameters was calculated, suggesting that 1,1-BTO is stable below the temperature of 175.36 °C. The thermal behavior under adiabatic condition was studied by ARC, depicting that onset temperature was 176.61 °C and the thermal decomposition ended at 215.93 °C, within the time span of 49.04 min. In addition, the thermo-kinetic parameters such as the activation energy Ea and pre-exponential factor A under adiabatic condition were also obtained.

AB - Thermogravimetric-differential scanning calorimeter and accelerating rate calorimeter (ARC) were performed to study the thermal characteristics and kinetics of energetic 5,5′-bistetrazole-1,1′-diolate (1,1-BTO). The DSC measurements showed one endothermic peak and one exothermic peak with decomposition occurring at 219.1, 227.2, 234.0 and 244.1 °C at different heating rates (2, 4, 8 and 15 °C min−1). The value of critical temperature of thermal explosion (Tb) and kinetics parameters was calculated, suggesting that 1,1-BTO is stable below the temperature of 175.36 °C. The thermal behavior under adiabatic condition was studied by ARC, depicting that onset temperature was 176.61 °C and the thermal decomposition ended at 215.93 °C, within the time span of 49.04 min. In addition, the thermo-kinetic parameters such as the activation energy Ea and pre-exponential factor A under adiabatic condition were also obtained.

KW - 5,5′-Bistetrazole-1,1′-diol (BTO)

KW - ARC

KW - Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate (TKX-50)

KW - DSC

KW - Thermal decomposition

UR - https://www.scopus.com/pages/publications/85014172222

U2 - 10.1007/s10973-017-6228-1

DO - 10.1007/s10973-017-6228-1

M3 - Article

AN - SCOPUS:85014172222

SN - 1388-6150

VL - 129

SP - 1265

EP - 1270

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 2

ER -

Thermal behavior and thermo-kinetic studies of 5,5′-bistetrazole-1,1′-diolate (1,1-BTO)

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Keywords

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