The synthesis and crystallographic characterization of heterotrimetallic linear complex of [Et 4N] [(Ph 3P) 2 {CuS 2 WS 2Fe}Br 2]

Ping Lin; Xin Tao Wu; Quan Ming Wang; Tian Lu Sheng; Biao Wu; Heng Yu; Ling Chen

The synthesis and crystallographic characterization of heterotrimetallic linear complex of [Et ₄N] [(Ph ₃P) ₂ {CuS ₂ WS ₂Fe}Br ₂]

Ping Lin, Xin Tao Wu, Quan Ming Wang, Tian Lu Sheng, Biao Wu, Heng Yu, Ling Chen

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The complex [Et ₄N] [(Ph ₃P) ₂ {CuS ₂WS ₂Fe} Br ₂] (1), C ₄₄H ₅₀-NBr ₂CuFeP ₂S ₄W, M _r=1246.13, has been obtained by reaction of [Et ₄N] ₂[WS ₂] and FeBr ₂ with Cu (Ph ₃P) ₃I in MeCN/CH ₂Cl ₂. Crystal data for [Et ₄N] [(Ph ₃P) ₂-{CuS ₂WS ₂Fe}Br ₂] (1) : triclinic, P1, Z = 2, a=13. 495 (7), 6 = 15. 322 (5), c = 12.361 (4) Å, α=105. 32 (3), β=93. 19 (4), γ=101.35(4) and V=2401. 2 Å ³. The bond lengths of W - Fe bond and the W - Cu distance are 2. 793(2) Å and 2. 823 (2) Å , respectively. Three kind metal atoms of the title structure [Et ₄ND [(Ph ₃P) ₂ {CuS ₂WS ₂Fe}Br ₂(1) are nearly distributed along a line, and along which three metal atoms (W, Cu, Fe) are approximately tetrahedral coordination.

Original language	English
Pages (from-to)	361-364
Number of pages	4
Journal	Jiegou Huaxue
Volume	17
Issue number	5
Publication status	Published - 1998
Externally published	Yes

Keywords

Crystal structure
Heterotrimetallic sulfido cluster
Linear
Synthesis

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@article{e2f22a41e66846548fcb4c197b0f5de6,

title = "The synthesis and crystallographic characterization of heterotrimetallic linear complex of [Et 4N] [(Ph 3P) 2 {CuS 2 WS 2Fe}Br 2]",

abstract = "The complex [Et 4N] [(Ph 3P) 2 {CuS 2WS 2Fe} Br 2] (1), C 44H 50-NBr 2CuFeP 2S 4W, M r=1246.13, has been obtained by reaction of [Et 4N] 2[WS 2] and FeBr 2 with Cu (Ph 3P) 3I in MeCN/CH 2Cl 2. Crystal data for [Et 4N] [(Ph 3P) 2-{CuS 2WS 2Fe}Br 2] (1) : triclinic, P1, Z = 2, a=13. 495 (7), 6 = 15. 322 (5), c = 12.361 (4) {\AA}, α=105. 32 (3), β=93. 19 (4), γ=101.35(4) and V=2401. 2 {\AA} 3. The bond lengths of W - Fe bond and the W - Cu distance are 2. 793(2) {\AA} and 2. 823 (2) {\AA} , respectively. Three kind metal atoms of the title structure [Et 4ND [(Ph 3P) 2 {CuS 2WS 2Fe}Br 2(1) are nearly distributed along a line, and along which three metal atoms (W, Cu, Fe) are approximately tetrahedral coordination.",

keywords = "Crystal structure, Heterotrimetallic sulfido cluster, Linear, Synthesis",

author = "Ping Lin and Wu, {Xin Tao} and Wang, {Quan Ming} and Sheng, {Tian Lu} and Biao Wu and Heng Yu and Ling Chen",

year = "1998",

language = "English",

volume = "17",

pages = "361--364",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "5",

}

TY - JOUR

T1 - The synthesis and crystallographic characterization of heterotrimetallic linear complex of [Et 4N] [(Ph 3P) 2 {CuS 2 WS 2Fe}Br 2]

AU - Lin, Ping

AU - Wu, Xin Tao

AU - Wang, Quan Ming

AU - Sheng, Tian Lu

AU - Wu, Biao

AU - Yu, Heng

AU - Chen, Ling

PY - 1998

Y1 - 1998

N2 - The complex [Et 4N] [(Ph 3P) 2 {CuS 2WS 2Fe} Br 2] (1), C 44H 50-NBr 2CuFeP 2S 4W, M r=1246.13, has been obtained by reaction of [Et 4N] 2[WS 2] and FeBr 2 with Cu (Ph 3P) 3I in MeCN/CH 2Cl 2. Crystal data for [Et 4N] [(Ph 3P) 2-{CuS 2WS 2Fe}Br 2] (1) : triclinic, P1, Z = 2, a=13. 495 (7), 6 = 15. 322 (5), c = 12.361 (4) Å, α=105. 32 (3), β=93. 19 (4), γ=101.35(4) and V=2401. 2 Å 3. The bond lengths of W - Fe bond and the W - Cu distance are 2. 793(2) Å and 2. 823 (2) Å , respectively. Three kind metal atoms of the title structure [Et 4ND [(Ph 3P) 2 {CuS 2WS 2Fe}Br 2(1) are nearly distributed along a line, and along which three metal atoms (W, Cu, Fe) are approximately tetrahedral coordination.

AB - The complex [Et 4N] [(Ph 3P) 2 {CuS 2WS 2Fe} Br 2] (1), C 44H 50-NBr 2CuFeP 2S 4W, M r=1246.13, has been obtained by reaction of [Et 4N] 2[WS 2] and FeBr 2 with Cu (Ph 3P) 3I in MeCN/CH 2Cl 2. Crystal data for [Et 4N] [(Ph 3P) 2-{CuS 2WS 2Fe}Br 2] (1) : triclinic, P1, Z = 2, a=13. 495 (7), 6 = 15. 322 (5), c = 12.361 (4) Å, α=105. 32 (3), β=93. 19 (4), γ=101.35(4) and V=2401. 2 Å 3. The bond lengths of W - Fe bond and the W - Cu distance are 2. 793(2) Å and 2. 823 (2) Å , respectively. Three kind metal atoms of the title structure [Et 4ND [(Ph 3P) 2 {CuS 2WS 2Fe}Br 2(1) are nearly distributed along a line, and along which three metal atoms (W, Cu, Fe) are approximately tetrahedral coordination.

KW - Crystal structure

KW - Heterotrimetallic sulfido cluster

KW - Linear

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=2842577409&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:2842577409

SN - 0254-5861

VL - 17

SP - 361

EP - 364

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 5

ER -

The synthesis and crystallographic characterization of heterotrimetallic linear complex of [Et ₄N] [(Ph ₃P) ₂ {CuS ₂ WS ₂Fe}Br ₂]

Abstract

Keywords

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