The structure of cis-[chloro(dimethylsulfoxide)bis(1,10-phenanthroline) ruthenium(II)]-tetraphenylborate, [RuCl(DMSO)(1,10-phen)2][BPh 4]

Biao Wu; Christoph Janiak

doi:10.1002/zaac.200400387

The structure of cis-[chloro(dimethylsulfoxide)bis(1,10-phenanthroline) ruthenium(II)]-tetraphenylborate, [RuCl(DMSO)(1,10-phen)₂][BPh ₄]

Biao Wu
, Christoph Janiak^*

^*Corresponding author for this work

University of Freiburg

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The complex cis-[RuCl(DMSO)(phen)₂]BPh₄, where DMSO is dimethylsulfoxide and phen is 1,10-phenanthroline, crystallizes in the monoclinic space group P2₁/c with a = 19.505(4), b = 10.045(2), c = 21.199(4) Å, β = 90.137(4)°, V = 4153(2) Å³, Z = 4, D_calc = 1.430 g cm^-3. The ruthenium coordination geometry is that of a slightly distorted octahedron with a cis-RuN ₄ClS arrangement of the ligand donor atoms. The Ru-Cl distance is 2.421(1) Å and the Ru-S distance 2.250(2) Å. The four Ru-N distances are 2.057(6), 2.066(4), 2.073(4), and 2.086(4) Å with the Ru-N bond trans to Cl the second shortest and the Ru-N bond trans to S the longest one.

Original language	English
Pages (from-to)	17-18
Number of pages	2
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	631
Issue number	1
DOIs	https://doi.org/10.1002/zaac.200400387
Publication status	Published - 2005
Externally published	Yes

Keywords

1,10-Phenanthroline
Crystal Structure
Dimethylsulfoxide (DMSO)
Ruthenium(II)

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10.1002/zaac.200400387

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title = "The structure of cis-[chloro(dimethylsulfoxide)bis(1,10-phenanthroline) ruthenium(II)]-tetraphenylborate, [RuCl(DMSO)(1,10-phen)2][BPh 4]",

abstract = "The complex cis-[RuCl(DMSO)(phen)2]BPh4, where DMSO is dimethylsulfoxide and phen is 1,10-phenanthroline, crystallizes in the monoclinic space group P21/c with a = 19.505(4), b = 10.045(2), c = 21.199(4) {\AA}, β = 90.137(4)°, V = 4153(2) {\AA}3, Z = 4, Dcalc = 1.430 g cm-3. The ruthenium coordination geometry is that of a slightly distorted octahedron with a cis-RuN 4ClS arrangement of the ligand donor atoms. The Ru-Cl distance is 2.421(1) {\AA} and the Ru-S distance 2.250(2) {\AA}. The four Ru-N distances are 2.057(6), 2.066(4), 2.073(4), and 2.086(4) {\AA} with the Ru-N bond trans to Cl the second shortest and the Ru-N bond trans to S the longest one.",

keywords = "1,10-Phenanthroline, Crystal Structure, Dimethylsulfoxide (DMSO), Ruthenium(II)",

author = "Biao Wu and Christoph Janiak",

year = "2005",

doi = "10.1002/zaac.200400387",

language = "English",

volume = "631",

pages = "17--18",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "1",

}

TY - JOUR

T1 - The structure of cis-[chloro(dimethylsulfoxide)bis(1,10-phenanthroline) ruthenium(II)]-tetraphenylborate, [RuCl(DMSO)(1,10-phen)2][BPh 4]

AU - Wu, Biao

AU - Janiak, Christoph

PY - 2005

Y1 - 2005

N2 - The complex cis-[RuCl(DMSO)(phen)2]BPh4, where DMSO is dimethylsulfoxide and phen is 1,10-phenanthroline, crystallizes in the monoclinic space group P21/c with a = 19.505(4), b = 10.045(2), c = 21.199(4) Å, β = 90.137(4)°, V = 4153(2) Å3, Z = 4, Dcalc = 1.430 g cm-3. The ruthenium coordination geometry is that of a slightly distorted octahedron with a cis-RuN 4ClS arrangement of the ligand donor atoms. The Ru-Cl distance is 2.421(1) Å and the Ru-S distance 2.250(2) Å. The four Ru-N distances are 2.057(6), 2.066(4), 2.073(4), and 2.086(4) Å with the Ru-N bond trans to Cl the second shortest and the Ru-N bond trans to S the longest one.

AB - The complex cis-[RuCl(DMSO)(phen)2]BPh4, where DMSO is dimethylsulfoxide and phen is 1,10-phenanthroline, crystallizes in the monoclinic space group P21/c with a = 19.505(4), b = 10.045(2), c = 21.199(4) Å, β = 90.137(4)°, V = 4153(2) Å3, Z = 4, Dcalc = 1.430 g cm-3. The ruthenium coordination geometry is that of a slightly distorted octahedron with a cis-RuN 4ClS arrangement of the ligand donor atoms. The Ru-Cl distance is 2.421(1) Å and the Ru-S distance 2.250(2) Å. The four Ru-N distances are 2.057(6), 2.066(4), 2.073(4), and 2.086(4) Å with the Ru-N bond trans to Cl the second shortest and the Ru-N bond trans to S the longest one.

KW - 1,10-Phenanthroline

KW - Crystal Structure

KW - Dimethylsulfoxide (DMSO)

KW - Ruthenium(II)

UR - https://www.scopus.com/pages/publications/12344278051

U2 - 10.1002/zaac.200400387

DO - 10.1002/zaac.200400387

M3 - Article

AN - SCOPUS:12344278051

SN - 0044-2313

VL - 631

SP - 17

EP - 18

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 1

ER -

The structure of cis-[chloro(dimethylsulfoxide)bis(1,10-phenanthroline) ruthenium(II)]-tetraphenylborate, [RuCl(DMSO)(1,10-phen)₂][BPh ₄]

Abstract

Keywords

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