The separation and concentration of titanium(IV) from sulfuric acid solution with trioctylamine

Qi Wang; Lin Jiang; Fan Ni; Tao Wang

doi:10.1021/ie2023756

The separation and concentration of titanium(IV) from sulfuric acid solution with trioctylamine

Qi Wang^*
, Lin Jiang
, Fan Ni
, Tao Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

This paper presents research on separating and concentrating titanium(IV) from aqueous sulfuric acid solution, using trioctylamine (TOA) as extractant and kerosene as a diluent. We investigated the effects of reaction time, temperature, sulfuric acid concentration, organic/aqueous phase ratio, TOA concentration, and titanium concentration on the removal efficiency of titanium(IV). The results show that it is possible to recover over 99% of titanium(IV) after 15 min reaction time by TOA from the sulfuric acid solution under the optimum operation conditions and the loading capacity of TOA for titanium(IV) is 30 g Ti(IV)/100 g TOA. We expect that results studied would be applicable to separate and concentrate titanium from secondary sources such as red mud produced in the aluminum/alumina industry.

Original language	English
Pages (from-to)	3430-3435
Number of pages	6
Journal	Industrial and Engineering Chemistry Research
Volume	51
Issue number	8
DOIs	https://doi.org/10.1021/ie2023756
Publication status	Published - 29 Feb 2012
Externally published	Yes

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title = "The separation and concentration of titanium(IV) from sulfuric acid solution with trioctylamine",

abstract = "This paper presents research on separating and concentrating titanium(IV) from aqueous sulfuric acid solution, using trioctylamine (TOA) as extractant and kerosene as a diluent. We investigated the effects of reaction time, temperature, sulfuric acid concentration, organic/aqueous phase ratio, TOA concentration, and titanium concentration on the removal efficiency of titanium(IV). The results show that it is possible to recover over 99\% of titanium(IV) after 15 min reaction time by TOA from the sulfuric acid solution under the optimum operation conditions and the loading capacity of TOA for titanium(IV) is 30 g Ti(IV)/100 g TOA. We expect that results studied would be applicable to separate and concentrate titanium from secondary sources such as red mud produced in the aluminum/alumina industry.",

author = "Qi Wang and Lin Jiang and Fan Ni and Tao Wang",

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T1 - The separation and concentration of titanium(IV) from sulfuric acid solution with trioctylamine

AU - Wang, Qi

AU - Jiang, Lin

AU - Ni, Fan

AU - Wang, Tao

PY - 2012/2/29

Y1 - 2012/2/29

N2 - This paper presents research on separating and concentrating titanium(IV) from aqueous sulfuric acid solution, using trioctylamine (TOA) as extractant and kerosene as a diluent. We investigated the effects of reaction time, temperature, sulfuric acid concentration, organic/aqueous phase ratio, TOA concentration, and titanium concentration on the removal efficiency of titanium(IV). The results show that it is possible to recover over 99% of titanium(IV) after 15 min reaction time by TOA from the sulfuric acid solution under the optimum operation conditions and the loading capacity of TOA for titanium(IV) is 30 g Ti(IV)/100 g TOA. We expect that results studied would be applicable to separate and concentrate titanium from secondary sources such as red mud produced in the aluminum/alumina industry.

AB - This paper presents research on separating and concentrating titanium(IV) from aqueous sulfuric acid solution, using trioctylamine (TOA) as extractant and kerosene as a diluent. We investigated the effects of reaction time, temperature, sulfuric acid concentration, organic/aqueous phase ratio, TOA concentration, and titanium concentration on the removal efficiency of titanium(IV). The results show that it is possible to recover over 99% of titanium(IV) after 15 min reaction time by TOA from the sulfuric acid solution under the optimum operation conditions and the loading capacity of TOA for titanium(IV) is 30 g Ti(IV)/100 g TOA. We expect that results studied would be applicable to separate and concentrate titanium from secondary sources such as red mud produced in the aluminum/alumina industry.

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SP - 3430

EP - 3435

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 8

ER -

The separation and concentration of titanium(IV) from sulfuric acid solution with trioctylamine

Abstract

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