The selective reduction of 4-propylthio-2-nitroaniline with CO using Ru3(CO)12/PEDPA complex as catalyst

Jing Yang Jiang; Qiang Miao; Yan Hua Wang; Zi Lin Jin

The selective reduction of 4-propylthio-2-nitroaniline with CO using Ru₃(CO)₁₂/PEDPA complex as catalyst

Jing Yang Jiang^*, Qiang Miao, Yan Hua Wang, Zi Lin Jin

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The Ru₃(CO)₁₂/PEDPA complex was firstly applied in the CO selective reduction of 4-propylthio-2-nitroaniline. The effects of reaction temperature, the pressure of CO and concentration of catalyst on the reduction were investigated. Under the optimum conditions of T=140°C, P _CO=5.0MPa and substrate/catalyst = 300 (molar ratio), the conversion and selectivity were 70% and 98%, respectively. After simple phase separation, the catalyst could be recycled.

Original language	English
Pages (from-to)	394-396
Number of pages	3
Journal	Chinese Chemical Letters
Volume	15
Issue number	4
Publication status	Published - Apr 2004
Externally published	Yes

Keywords

4-Propylthio-2-nitroaniline
CO selective reduction
Phosphine
Ru(CO)

Cite this

@article{a82ea0fb1ace4965b5d46f86609c7226,

title = "The selective reduction of 4-propylthio-2-nitroaniline with CO using Ru3(CO)12/PEDPA complex as catalyst",

abstract = "The Ru3(CO)12/PEDPA complex was firstly applied in the CO selective reduction of 4-propylthio-2-nitroaniline. The effects of reaction temperature, the pressure of CO and concentration of catalyst on the reduction were investigated. Under the optimum conditions of T=140°C, P CO=5.0MPa and substrate/catalyst = 300 (molar ratio), the conversion and selectivity were 70% and 98%, respectively. After simple phase separation, the catalyst could be recycled.",

keywords = "4-Propylthio-2-nitroaniline, CO selective reduction, Phosphine, Ru(CO)",

author = "Jiang, {Jing Yang} and Qiang Miao and Wang, {Yan Hua} and Jin, {Zi Lin}",

year = "2004",

month = apr,

language = "English",

volume = "15",

pages = "394--396",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "4",

}

TY - JOUR

T1 - The selective reduction of 4-propylthio-2-nitroaniline with CO using Ru3(CO)12/PEDPA complex as catalyst

AU - Jiang, Jing Yang

AU - Miao, Qiang

AU - Wang, Yan Hua

AU - Jin, Zi Lin

PY - 2004/4

Y1 - 2004/4

N2 - The Ru3(CO)12/PEDPA complex was firstly applied in the CO selective reduction of 4-propylthio-2-nitroaniline. The effects of reaction temperature, the pressure of CO and concentration of catalyst on the reduction were investigated. Under the optimum conditions of T=140°C, P CO=5.0MPa and substrate/catalyst = 300 (molar ratio), the conversion and selectivity were 70% and 98%, respectively. After simple phase separation, the catalyst could be recycled.

AB - The Ru3(CO)12/PEDPA complex was firstly applied in the CO selective reduction of 4-propylthio-2-nitroaniline. The effects of reaction temperature, the pressure of CO and concentration of catalyst on the reduction were investigated. Under the optimum conditions of T=140°C, P CO=5.0MPa and substrate/catalyst = 300 (molar ratio), the conversion and selectivity were 70% and 98%, respectively. After simple phase separation, the catalyst could be recycled.

KW - 4-Propylthio-2-nitroaniline

KW - CO selective reduction

KW - Phosphine

KW - Ru(CO)

UR - http://www.scopus.com/inward/record.url?scp=2342640787&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:2342640787

SN - 1001-8417

VL - 15

SP - 394

EP - 396

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 4

ER -

The selective reduction of 4-propylthio-2-nitroaniline with CO using Ru₃(CO)₁₂/PEDPA complex as catalyst

Abstract

Keywords

Other files and links

Fingerprint

Cite this