The photoelectric conversion and second harmonic generation properties of the transition metal-containing complexes [(CH3)2N C6H4-CH=CH-C5H4N-C 18H37 ]2M(dmit)2 (M=Cd, Ni)

Jin Zhai; Chunhui Huang; Tian Xin Wei; Liangbing Gan; Hong Cao

doi:10.1016/S0277-5387(99)00020-0

The photoelectric conversion and second harmonic generation properties of the transition metal-containing complexes [(CH₃)₂N C₆H₄-CH=CH-C₅H₄N-C ₁₈H₃₇ ]₂M(dmit)₂ (M=Cd, Ni)

Jin Zhai
, Chunhui Huang^*
, Tian Xin Wei
, Liangbing Gan
, Hong Cao

^*Corresponding author for this work

Peking University

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

The photoelectric conversion and second harmonic generation properties of the complex bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium}bis(2-thione-1,3-dithiol-4,5-dimercapt)M,N[D₂M(dmit) ₂ where M=Cd, Ni] have been investigated. The photoelectric conversion quantum yield of the complex of D₂Cd(dmit)₂ was evaluated to be 1.1% which is five-fold larger than that of bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium} iodide (DI) itself, while the second order nonlinear optical susceptibility χ_zzz² was measured as 149.8 pm V^-1 which is about the same as DI.

Original language	English
Pages (from-to)	1513-1518
Number of pages	6
Journal	Polyhedron
Volume	18
Issue number	10
DOIs	https://doi.org/10.1016/S0277-5387(99)00020-0
Publication status	Published - 26 Mar 1999
Externally published	Yes

Keywords

Hemicyanine cation
Photoelectric conversion
Second-harmonic generation
Single-crystal structure
Transition metal complex anions

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10.1016/S0277-5387(99)00020-0

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@article{51543f9db3154ee385d5ecb583c514ab,

title = "The photoelectric conversion and second harmonic generation properties of the transition metal-containing complexes [(CH3)2N C6H4-CH=CH-C5H4N-C 18H37 ]2M(dmit)2 (M=Cd, Ni)",

abstract = "The photoelectric conversion and second harmonic generation properties of the complex bis\{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium\}bis(2-thione-1,3-dithiol-4,5-dimercapt)M,N[D2M(dmit) 2 where M=Cd, Ni] have been investigated. The photoelectric conversion quantum yield of the complex of D2Cd(dmit)2 was evaluated to be 1.1\% which is five-fold larger than that of bis\{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium\} iodide (DI) itself, while the second order nonlinear optical susceptibility χzzz2 was measured as 149.8 pm V-1 which is about the same as DI.",

keywords = "Hemicyanine cation, Photoelectric conversion, Second-harmonic generation, Single-crystal structure, Transition metal complex anions",

author = "Jin Zhai and Chunhui Huang and Wei, \{Tian Xin\} and Liangbing Gan and Hong Cao",

year = "1999",

month = mar,

day = "26",

doi = "10.1016/S0277-5387(99)00020-0",

language = "English",

volume = "18",

pages = "1513--1518",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "10",

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TY - JOUR

T1 - The photoelectric conversion and second harmonic generation properties of the transition metal-containing complexes [(CH3)2N C6H4-CH=CH-C5H4N-C 18H37 ]2M(dmit)2 (M=Cd, Ni)

AU - Zhai, Jin

AU - Huang, Chunhui

AU - Wei, Tian Xin

AU - Gan, Liangbing

AU - Cao, Hong

PY - 1999/3/26

Y1 - 1999/3/26

N2 - The photoelectric conversion and second harmonic generation properties of the complex bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium}bis(2-thione-1,3-dithiol-4,5-dimercapt)M,N[D2M(dmit) 2 where M=Cd, Ni] have been investigated. The photoelectric conversion quantum yield of the complex of D2Cd(dmit)2 was evaluated to be 1.1% which is five-fold larger than that of bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium} iodide (DI) itself, while the second order nonlinear optical susceptibility χzzz2 was measured as 149.8 pm V-1 which is about the same as DI.

AB - The photoelectric conversion and second harmonic generation properties of the complex bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium}bis(2-thione-1,3-dithiol-4,5-dimercapt)M,N[D2M(dmit) 2 where M=Cd, Ni] have been investigated. The photoelectric conversion quantum yield of the complex of D2Cd(dmit)2 was evaluated to be 1.1% which is five-fold larger than that of bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium} iodide (DI) itself, while the second order nonlinear optical susceptibility χzzz2 was measured as 149.8 pm V-1 which is about the same as DI.

KW - Hemicyanine cation

KW - Photoelectric conversion

KW - Second-harmonic generation

KW - Single-crystal structure

KW - Transition metal complex anions

UR - https://www.scopus.com/pages/publications/0000761243

U2 - 10.1016/S0277-5387(99)00020-0

DO - 10.1016/S0277-5387(99)00020-0

M3 - Article

AN - SCOPUS:0000761243

SN - 0277-5387

VL - 18

SP - 1513

EP - 1518

JO - Polyhedron

JF - Polyhedron

IS - 10

ER -

The photoelectric conversion and second harmonic generation properties of the transition metal-containing complexes [(CH₃)₂N C₆H₄-CH=CH-C₅H₄N-C ₁₈H₃₇ ]₂M(dmit)₂ (M=Cd, Ni)

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Keywords

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