The lattice energy of [Mn(CHZ)3] (NO3)2 and [Mn(CHZ)3] (ClO4)2

Qiu Yu Zheng; Xiao Jing Qiao; Li Yang; Feng Lei Shao

The lattice energy of [Mn(CHZ)₃] (NO₃)₂ and [Mn(CHZ)₃] (ClO₄)₂

Qiu Yu Zheng^*
, Xiao Jing Qiao
, Li Yang
, Feng Lei Shao

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In order to study the relationship between the structures and sensitivities of energetic coordination compounds, the enthalpies of solution of [Mn(CHZ)₃] (NO₃)₂ and [Mn(CHZ)₃] (ClO₄)₂ in deionized water were measured by a Setaram C80 II micro-calorimeter at 298.15 K. The standard molar enthalpies of solution were obtained to be 91.13 kJ · mol^-1 for [Mn(CHZ)₃] (NO₃)₂ and 87.09 kJ · mol^-1 for [Mn(CHZ)₃] (ClO₄)₂. Their lattice energy were calculated farther as [Mn(CHZ)₃] (NO₃)₂ being 1737.36 kJ · mol^-1 and [Mn(CHZ)₃] (ClO₄)₂ being 1485.36 kJ · mol^-1 through Kapustinskii formula, and the thermochemistry radius of [Mn(CHZ)₃]²⁺ was obtained to be 2.12 A. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. The more the lattice energy is, the lower the sensitivity is. [Mn(CHZ)₃] (NO₃)₂ is more insensitive than [Mn(CHZ)₃](ClO₄)₂.

Original language	English
Pages (from-to)	666-669
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	15
Issue number	6
Publication status	Published - Dec 2007

Keywords

Enthalpy of solution
Lattice energy
Physical chemistry
Sensitivity
[Mn(CHZ)] (ClO)
[Mn(CHZ)] (NO)

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@article{1460066e15da4ae39baf1041c8d34090,

title = "The lattice energy of [Mn(CHZ)3] (NO3)2 and [Mn(CHZ)3] (ClO4)2",

abstract = "In order to study the relationship between the structures and sensitivities of energetic coordination compounds, the enthalpies of solution of [Mn(CHZ)3] (NO3)2 and [Mn(CHZ)3] (ClO4)2 in deionized water were measured by a Setaram C80 II micro-calorimeter at 298.15 K. The standard molar enthalpies of solution were obtained to be 91.13 kJ · mol-1 for [Mn(CHZ)3] (NO3)2 and 87.09 kJ · mol-1 for [Mn(CHZ)3] (ClO4)2. Their lattice energy were calculated farther as [Mn(CHZ)3] (NO3)2 being 1737.36 kJ · mol-1 and [Mn(CHZ)3] (ClO4)2 being 1485.36 kJ · mol-1 through Kapustinskii formula, and the thermochemistry radius of [Mn(CHZ)3]2+ was obtained to be 2.12 A. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. The more the lattice energy is, the lower the sensitivity is. [Mn(CHZ)3] (NO3)2 is more insensitive than [Mn(CHZ)3](ClO4)2.",

keywords = "Enthalpy of solution, Lattice energy, Physical chemistry, Sensitivity, [Mn(CHZ)] (ClO), [Mn(CHZ)] (NO)",

author = "Zheng, \{Qiu Yu\} and Qiao, \{Xiao Jing\} and Li Yang and Shao, \{Feng Lei\}",

year = "2007",

month = dec,

language = "English",

volume = "15",

pages = "666--669",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "6",

}

TY - JOUR

T1 - The lattice energy of [Mn(CHZ)3] (NO3)2 and [Mn(CHZ)3] (ClO4)2

AU - Zheng, Qiu Yu

AU - Qiao, Xiao Jing

AU - Yang, Li

AU - Shao, Feng Lei

PY - 2007/12

Y1 - 2007/12

N2 - In order to study the relationship between the structures and sensitivities of energetic coordination compounds, the enthalpies of solution of [Mn(CHZ)3] (NO3)2 and [Mn(CHZ)3] (ClO4)2 in deionized water were measured by a Setaram C80 II micro-calorimeter at 298.15 K. The standard molar enthalpies of solution were obtained to be 91.13 kJ · mol-1 for [Mn(CHZ)3] (NO3)2 and 87.09 kJ · mol-1 for [Mn(CHZ)3] (ClO4)2. Their lattice energy were calculated farther as [Mn(CHZ)3] (NO3)2 being 1737.36 kJ · mol-1 and [Mn(CHZ)3] (ClO4)2 being 1485.36 kJ · mol-1 through Kapustinskii formula, and the thermochemistry radius of [Mn(CHZ)3]2+ was obtained to be 2.12 A. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. The more the lattice energy is, the lower the sensitivity is. [Mn(CHZ)3] (NO3)2 is more insensitive than [Mn(CHZ)3](ClO4)2.

AB - In order to study the relationship between the structures and sensitivities of energetic coordination compounds, the enthalpies of solution of [Mn(CHZ)3] (NO3)2 and [Mn(CHZ)3] (ClO4)2 in deionized water were measured by a Setaram C80 II micro-calorimeter at 298.15 K. The standard molar enthalpies of solution were obtained to be 91.13 kJ · mol-1 for [Mn(CHZ)3] (NO3)2 and 87.09 kJ · mol-1 for [Mn(CHZ)3] (ClO4)2. Their lattice energy were calculated farther as [Mn(CHZ)3] (NO3)2 being 1737.36 kJ · mol-1 and [Mn(CHZ)3] (ClO4)2 being 1485.36 kJ · mol-1 through Kapustinskii formula, and the thermochemistry radius of [Mn(CHZ)3]2+ was obtained to be 2.12 A. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. The more the lattice energy is, the lower the sensitivity is. [Mn(CHZ)3] (NO3)2 is more insensitive than [Mn(CHZ)3](ClO4)2.

KW - Enthalpy of solution

KW - Lattice energy

KW - Physical chemistry

KW - Sensitivity

KW - [Mn(CHZ)] (ClO)

KW - [Mn(CHZ)] (NO)

UR - https://www.scopus.com/pages/publications/38349014269

M3 - Article

AN - SCOPUS:38349014269

SN - 1006-9941

VL - 15

SP - 666

EP - 669

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 6

ER -

The lattice energy of [Mn(CHZ)₃] (NO₃)₂ and [Mn(CHZ)₃] (ClO₄)₂

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