The first solid composed of {As4V16O 42(H2O)} clusters

Shou Tian Zheng; Jie Zhang; Bing Li; Guo Yu Yang

doi:10.1039/b806770h

The first solid composed of {As₄V₁₆O ₄₂(H₂O)} clusters

Shou Tian Zheng, Jie Zhang, Bing Li, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

A new polyoxovanadate [Zn₂(dien)₃]{[Zn(dien)] ₂As₄V₁₆O₄₂(H₂O)} •3H₂O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by EA, IR, TGA, magnetic measurement and single crystal X-ray diffraction. X-Ray diffraction analyses reveal that 1 exhibits the first {As₄V₁₆O₄₂(H ₂O)}-containing polyoxometalate. In 1, the adjacent {As ₄V₁₆O₄₂(H₂O)} clusters are linked to each other through dual mono-nuclear zinc complexes {Zn(dien)} to form one-dimensional anionic chains with isolated dinuclear zinc complexes {Zn ₂(dien)₃} occupying the interchain regions as charge compensation. The study of the magnetic susceptibility demonstrates the presence of antiferromagnetic interaction between V^IV cations in 1.

Original language	English
Pages (from-to)	5584-5587
Number of pages	4
Journal	Dalton Transactions
Issue number	41
DOIs	https://doi.org/10.1039/b806770h
Publication status	Published - 2008
Externally published	Yes

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title = "The first solid composed of {As4V16O 42(H2O)} clusters",

abstract = "A new polyoxovanadate [Zn2(dien)3]{[Zn(dien)] 2As4V16O42(H2O)} •3H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by EA, IR, TGA, magnetic measurement and single crystal X-ray diffraction. X-Ray diffraction analyses reveal that 1 exhibits the first {As4V16O42(H 2O)}-containing polyoxometalate. In 1, the adjacent {As 4V16O42(H2O)} clusters are linked to each other through dual mono-nuclear zinc complexes {Zn(dien)} to form one-dimensional anionic chains with isolated dinuclear zinc complexes {Zn 2(dien)3} occupying the interchain regions as charge compensation. The study of the magnetic susceptibility demonstrates the presence of antiferromagnetic interaction between VIV cations in 1.",

author = "Zheng, {Shou Tian} and Jie Zhang and Bing Li and Yang, {Guo Yu}",

year = "2008",

doi = "10.1039/b806770h",

language = "English",

pages = "5584--5587",

journal = "Dalton Transactions",

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T1 - The first solid composed of {As4V16O 42(H2O)} clusters

AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Li, Bing

AU - Yang, Guo Yu

PY - 2008

Y1 - 2008

N2 - A new polyoxovanadate [Zn2(dien)3]{[Zn(dien)] 2As4V16O42(H2O)} •3H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by EA, IR, TGA, magnetic measurement and single crystal X-ray diffraction. X-Ray diffraction analyses reveal that 1 exhibits the first {As4V16O42(H 2O)}-containing polyoxometalate. In 1, the adjacent {As 4V16O42(H2O)} clusters are linked to each other through dual mono-nuclear zinc complexes {Zn(dien)} to form one-dimensional anionic chains with isolated dinuclear zinc complexes {Zn 2(dien)3} occupying the interchain regions as charge compensation. The study of the magnetic susceptibility demonstrates the presence of antiferromagnetic interaction between VIV cations in 1.

AB - A new polyoxovanadate [Zn2(dien)3]{[Zn(dien)] 2As4V16O42(H2O)} •3H2O (1, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by EA, IR, TGA, magnetic measurement and single crystal X-ray diffraction. X-Ray diffraction analyses reveal that 1 exhibits the first {As4V16O42(H 2O)}-containing polyoxometalate. In 1, the adjacent {As 4V16O42(H2O)} clusters are linked to each other through dual mono-nuclear zinc complexes {Zn(dien)} to form one-dimensional anionic chains with isolated dinuclear zinc complexes {Zn 2(dien)3} occupying the interchain regions as charge compensation. The study of the magnetic susceptibility demonstrates the presence of antiferromagnetic interaction between VIV cations in 1.

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DO - 10.1039/b806770h

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EP - 5587

JO - Dalton Transactions

JF - Dalton Transactions

IS - 41

ER -

The first solid composed of {As₄V₁₆O ₄₂(H₂O)} clusters

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