The first one-dimensional coordination polymer containing O-H···F-Ni hydrogen bonding: Crystal structure of [Ni3(dpa)4F2] [Ni3(dpa)4(H2 O)2](BF4)2 · 2CH3OH

Hui Li; Gene Hsiang Lee; Shie Ming Peng

doi:10.1016/S1387-7003(02)00668-8

The first one-dimensional coordination polymer containing O-H···F-Ni hydrogen bonding: Crystal structure of [Ni₃(dpa)₄F₂] [Ni₃(dpa)₄(H₂ O)₂](BF₄)₂ · 2CH₃OH

Hui Li
, Gene Hsiang Lee
, Shie Ming Peng^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The one-dimensional coordination polymer, [Ni₃(dpa)₄F₂][Ni₃ (dpa)₄(H₂O)₂](BF₄)₂ · 2CH₃OH (dpa^- = bis(2-pyridyl)amido ligand), has been constructed. The title complex crystallizes in the triclinic system, space group P, with a= 11.5966(1), b = 19.5609(2), c = 20.1509(2) Å, α = 79.5672(4), β = 75.4196(4), γ = 76.2199(5)°, Z = 2. The rare type hydrogen bonding of O-H⋯F-Ni links the two kinds of the trinickel metal string complexes as building blocks.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	1
DOIs	https://doi.org/10.1016/S1387-7003(02)00668-8
Publication status	Published - 1 Jan 2003
Externally published	Yes

Keywords

Coordination polymer
Hydrogen bonding
Metal string complexes
Supramolecular chemistry

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10.1016/S1387-7003(02)00668-8

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title = "The first one-dimensional coordination polymer containing O-H···F-Ni hydrogen bonding: Crystal structure of [Ni3(dpa)4F2] [Ni3(dpa)4(H2 O)2](BF4)2 · 2CH3OH",

abstract = "The one-dimensional coordination polymer, [Ni3(dpa)4F2][Ni3 (dpa)4(H2O)2](BF4)2 · 2CH3OH (dpa- = bis(2-pyridyl)amido ligand), has been constructed. The title complex crystallizes in the triclinic system, space group P, with a= 11.5966(1), b = 19.5609(2), c = 20.1509(2) {\AA}, α = 79.5672(4), β = 75.4196(4), γ = 76.2199(5)°, Z = 2. The rare type hydrogen bonding of O-H⋯F-Ni links the two kinds of the trinickel metal string complexes as building blocks.",

keywords = "Coordination polymer, Hydrogen bonding, Metal string complexes, Supramolecular chemistry",

author = "Hui Li and Lee, \{Gene Hsiang\} and Peng, \{Shie Ming\}",

year = "2003",

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doi = "10.1016/S1387-7003(02)00668-8",

language = "English",

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T1 - The first one-dimensional coordination polymer containing O-H···F-Ni hydrogen bonding

T2 - Crystal structure of [Ni3(dpa)4F2] [Ni3(dpa)4(H2 O)2](BF4)2 · 2CH3OH

AU - Li, Hui

AU - Lee, Gene Hsiang

AU - Peng, Shie Ming

PY - 2003/1/1

Y1 - 2003/1/1

N2 - The one-dimensional coordination polymer, [Ni3(dpa)4F2][Ni3 (dpa)4(H2O)2](BF4)2 · 2CH3OH (dpa- = bis(2-pyridyl)amido ligand), has been constructed. The title complex crystallizes in the triclinic system, space group P, with a= 11.5966(1), b = 19.5609(2), c = 20.1509(2) Å, α = 79.5672(4), β = 75.4196(4), γ = 76.2199(5)°, Z = 2. The rare type hydrogen bonding of O-H⋯F-Ni links the two kinds of the trinickel metal string complexes as building blocks.

AB - The one-dimensional coordination polymer, [Ni3(dpa)4F2][Ni3 (dpa)4(H2O)2](BF4)2 · 2CH3OH (dpa- = bis(2-pyridyl)amido ligand), has been constructed. The title complex crystallizes in the triclinic system, space group P, with a= 11.5966(1), b = 19.5609(2), c = 20.1509(2) Å, α = 79.5672(4), β = 75.4196(4), γ = 76.2199(5)°, Z = 2. The rare type hydrogen bonding of O-H⋯F-Ni links the two kinds of the trinickel metal string complexes as building blocks.

KW - Coordination polymer

KW - Hydrogen bonding

KW - Metal string complexes

KW - Supramolecular chemistry

UR - https://www.scopus.com/pages/publications/0037224199

U2 - 10.1016/S1387-7003(02)00668-8

DO - 10.1016/S1387-7003(02)00668-8

M3 - Article

AN - SCOPUS:0037224199

SN - 1387-7003

VL - 6

SP - 1

EP - 4

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

The first one-dimensional coordination polymer containing O-H···F-Ni hydrogen bonding: Crystal structure of [Ni₃(dpa)₄F₂] [Ni₃(dpa)₄(H₂ O)₂](BF₄)₂ · 2CH₃OH

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Keywords

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